Draw the reaction equation for the Sodium Iodide/Acetone test (SN2 mechanism) for each of the substances:...
Draw the reaction equation for the Sodium Iodide/Acetone test (SN2 mechanism) for each of the substances:
1. 1-chlorobutane
2. 2-chlorobutane
3. 2-chloro-2-methylpropane
4. 1-bromobutane
5. 2-bromobutane
6. benzyl chloride
7. bromocyclohexane
8. bromocyclopentane
Homework Answers
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Draw the reaction equation for the Sodium Iodide/Acetone test
(SN2 mechanism) for each of the substances:...
For each compound listed below, predict the dominant mechanism for each reactant (SN1 and/or SN2). The...
For each compound listed below, predict the dominant mechanism for each reactant (SN1 and/or SN2). The two test reagent mixtures you will be using are sodium iodide in acetone and silver nitrate in ethanol.Note: a compound may not react at all or react under both mechanisms. If both mechanisms are possible, one is usually dominant. Indicate that where applicable. Reactant KI/acetone AgNO3/ethanol 1 bromobenzene 2 bromocyclopentane 3 bromocyclohexane 4 2-bromobutane 5 2-chlorobutane 6 1-chloropropan-2-one 7 1-chlorobutane 8 2-chloro-2-methylpropane 9 1-chloromethylbenzene
Product Structure in NaI, acetone of the following (Note: it should follow an SN2 mechanism). Dont...
Product Structure in NaI, acetone of the following (Note: it should follow an SN2 mechanism). Dont need the entire mechanism just the final product structure please. Thank you. 2-chlorobutane 2-bromobutane 1-chlorobutane 1-bromobutane 2-chloro-2-methyl propane Crotyl chloride Benzyl chloride Bromobenzene Bromocyclohexane Bromocyclopentane
Nucleophilic substitutions, mainly just need the arrangements, and the drawn out reaction equations CHEM 220L Laboratory...
Nucleophilic substitutions, mainly just need the arrangements,
and the drawn out reaction equations
CHEM 220L Laboratory Manual (S.A. Cummings & J.K. Mahoney) CHEM 220L Data Sheet: Nucleophilic Substitutions (SN1 and SN2) (6 points) Part 1. Enter the results of each test into the table below: Alkyl Halides 10, 2 or 3? SN2 (Nal/acetone) 1-chlorobutane 1-bromobutane 2-chlorobutane 2-bromobutane bromocyclohexane 2-chloro-2-methylpropane (t-butyl chloride) Crotyl chloride Benzyl chloride (a-chlorotoluene) Arrange the alkyl halides in order of reactivity (from most to least reactive) with...
Product structure in AgNO3 EtOH of the following (Note: it should follow an SN2 mechanism). Dont...
Product structure in AgNO3 EtOH of the following (Note: it should follow an SN2 mechanism). Dont need the entire mechanism just the final product structure please. Thank you. 2-chlorobutane 2-bromobutane 1-chlorobutane 1-bromobutane 2-chloro-2-methyl propane Crotyl chloride Benzyl chloride Bromobenzene Bromocyclohexane Bromocyclopentane
For the Reactions that formed precipitates, what are the drawn out reaction equations with stereochemistry if...
For the Reactions that formed precipitates, what are the drawn
out reaction equations with stereochemistry if applicable?
Part 1. Enter the results of each test into the table below: 1°, 2° or 3°? Alkyl Halides 1-chlorobutane Sn2 (Nal/acetone) Precipitate formed 1-bromobutane Precipitate formed 2-chlorobutane No precipitate formed 2-bromobutane No precipitate formed bromocyclohexane No precipitate formed 2-chloro-2-methylpropane (t-butyl chloride) No precipitate formed Crotyl chloride No precipitate formed Benzyl chloride (a-chlorotoluene) No precipitate formed Arrange the alkyl halides in order of reactivity...
. . . . 2.Write the chemical reaction of the following: Sodium Iodide in acetone with...
. . . . 2.Write the chemical reaction of the following: Sodium Iodide in acetone with 1-Bromobutane Sodium Iodide in acetone with 1- Chlorobutane Sodium Iodide in acetone with 2-Bromobutane Sodium Iodide in acetone with 2-Chlorobutane Sodium Iodide in acetone with 1-Chloro-2-methyl pentane Silver Nitrate in alcohol with 1-Bromobutane Silver Nitrate in alcohol with 1- Chlorobutane Silver Nitrate in alcohol with 2-Bromobutane SIlver Nitrate in alcohol with 2-Chlorobutane Silver Nitrate in alcohol with 1-Chloro-2-methyl pentane . . . . .
Mechanism for each reaction SN2 reaction conditions: To create reaction conditions suitable for an SN2 reaction,...
Mechanism for each reaction
SN2 reaction conditions: To create reaction conditions suitable for an SN2 reaction, sodium iodide will be employed. Iodide is a great nucleophile, given its highly polarizable nature. Since SN2 reactions work best in an aprotic solvent, acetone will be utilized for these reactions. As a side product, the sodium cation will form an ionic compound with the leaving halides. Since sodium chloride and sodium bromide is not soluble in acetone, thus the successful substitution reaction of...
1. In both the sodium iodide test and the silver nitrate test, why does 2-bromobutane react faster...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
Mechanism for each reaction SN2 reaction conditions: To create reaction conditions suitable for an SN2 reaction,...
Mechanism for each reaction
SN2 reaction conditions: To create reaction conditions suitable for an SN2 reaction, sodium iodide will be employed. lodide is a great nucleophile, given its highly polarizable nature. Since SN2 reactions work best in an aprotic solvent, acetone will be utilized for these reactions. As a side product, the sodium cation will form an ionic compound with the leaving halides. Since sodium chloride and sodium bromide is not soluble in acetone, thus the successful substitution reaction of...
In this exercise, you will use two reagent mixtures to test a variety of organic halides....
In this exercise, you will use two reagent mixtures to test a variety of organic halides. The distinct differences in the factors affecting the SN2 and SN1 mechanisms make it possible to determine which mechanism is favored by a given compound. One reagent and solvent favors SN2 reactivity, the other SN1 reactivity. From the results of your tests, you will determine which mechanism, if either, is favored by a given compound. In your post-lab assignment, you will be required to...
Nucleophilic substitutions, mainly just need the arrangements,
and the drawn out reaction equations
CHEM 220L Laboratory Manual (S.A. Cummings & J.K. Mahoney) CHEM 220L Data Sheet: Nucleophilic Substitutions (SN1 and SN2) (6 points) Part 1. Enter the results of each test into the table below: Alkyl Halides 10, 2 or 3? SN2 (Nal/acetone) 1-chlorobutane 1-bromobutane 2-chlorobutane 2-bromobutane bromocyclohexane 2-chloro-2-methylpropane (t-butyl chloride) Crotyl chloride Benzyl chloride (a-chlorotoluene) Arrange the alkyl halides in order of reactivity (from most to least reactive) with...
For the Reactions that formed precipitates, what are the drawn
out reaction equations with stereochemistry if applicable?
Part 1. Enter the results of each test into the table below: 1°, 2° or 3°? Alkyl Halides 1-chlorobutane Sn2 (Nal/acetone) Precipitate formed 1-bromobutane Precipitate formed 2-chlorobutane No precipitate formed 2-bromobutane No precipitate formed bromocyclohexane No precipitate formed 2-chloro-2-methylpropane (t-butyl chloride) No precipitate formed Crotyl chloride No precipitate formed Benzyl chloride (a-chlorotoluene) No precipitate formed Arrange the alkyl halides in order of reactivity...
. . . . 2.Write the chemical reaction of the following: Sodium Iodide in acetone with 1-Bromobutane Sodium Iodide in acetone with 1- Chlorobutane Sodium Iodide in acetone with 2-Bromobutane Sodium Iodide in acetone with 2-Chlorobutane Sodium Iodide in acetone with 1-Chloro-2-methyl pentane Silver Nitrate in alcohol with 1-Bromobutane Silver Nitrate in alcohol with 1- Chlorobutane Silver Nitrate in alcohol with 2-Bromobutane SIlver Nitrate in alcohol with 2-Chlorobutane Silver Nitrate in alcohol with 1-Chloro-2-methyl pentane . . . . .
Mechanism for each reaction
SN2 reaction conditions: To create reaction conditions suitable for an SN2 reaction, sodium iodide will be employed. Iodide is a great nucleophile, given its highly polarizable nature. Since SN2 reactions work best in an aprotic solvent, acetone will be utilized for these reactions. As a side product, the sodium cation will form an ionic compound with the leaving halides. Since sodium chloride and sodium bromide is not soluble in acetone, thus the successful substitution reaction of...
1. In both the sodium iodide
test and the silver nitrate test, why does 2-bromobutane react
faster than 2-chlorobutane?
Bromine is a better leaving group since it is a weaker base than
chlorine is.
2. a. Why does benzyl chloride react under both
SN1 and SN2 conditions?
Benzyl
chloride is a primary alkyl halide, hence reactive under SN2
conditions.
The
primary carbocation formed due to the departure of Cl- is
stabilized by the pi electrons in the benzene ring.
b. Why is...
Mechanism for each reaction
SN2 reaction conditions: To create reaction conditions suitable for an SN2 reaction, sodium iodide will be employed. lodide is a great nucleophile, given its highly polarizable nature. Since SN2 reactions work best in an aprotic solvent, acetone will be utilized for these reactions. As a side product, the sodium cation will form an ionic compound with the leaving halides. Since sodium chloride and sodium bromide is not soluble in acetone, thus the successful substitution reaction of...
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