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What ketone would you isolate after treatment of [a] with NaOEt and allyl bromide, followed by...
Show the product of reaction of the indicated ester with LDA, followed by butyl iodide. CHÚCH...
Show the product of reaction of the indicated ester with LDA,
followed by butyl iodide.
CHÚCH 0 1. Provide a correct name for the indicated ester. 2. How many signals would we expect to see in the 13C NMR spectrum? 3. Show the combination of reagents required to synthesize the indicated structure using a Fischer esterification reaction. 4. a. The indicated ester is submitted to Claisen condensation conditions, using the appropriate alkoxide base and a second acidification step. The product...
Draw a structural formula for the product of the aldol reaction of the compound shown above,...
Draw a structural formula for the product of the aldol reaction of the compound shown above, as well as the a.B-unsaturated aldehyde or ketone formed from dehydration of the aldol product. You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right comer. Separate structures using the sign from the drop-down menu. . o 1. Og 2. (CH3)2...
3. When 2-ethylcyclohexanone is treated with LDA (in the solvent THF), followed by ethyl bromide, two...
3. When 2-ethylcyclohexanone is treated with LDA (in the solvent THF), followed by ethyl bromide, two different alkylated products are formed. Answer the following questions about this reaction. 1) LDA THE two products 2) CH CH Br 3. a. What is LDA and what is its purpose? 3. b. Draw mechanisms for the reactions and show how the two different products are formed. Product A Mechanism Product B Mechanism 3. c. Draw an energy diagram for the formation of both...
Thank you！ 9. What would be the product of the following conversion? 1. NaOEt, EIOH OEt...
Thank you！
9. What would be the product of the following conversion? 1. NaOEt, EIOH OEt 2. H,о- OEt ОН О OEt OEt OEt OE OEt e. d. 10. What is the product of the Dieckmann condensation of the following diester? 1.NaOCH, CH,Oн HgCOoc coOCHs 2. H,0* осн, COOCH COOCH b. d. both a) and b) e. a), b), and c) a. C. 11. Consider the synthesis below. What is compound X? COOEt COOH 1. КОВи 1. NAOH, H2O, heat...
1. Provide the products of the reaction below and a detailed reaction mechanism using curved arrows...
1. Provide the products of the reaction below and a detailed reaction mechanism using curved arrows to indicate the movement of electrons. (a) (b) КОН (c) Note that formation of 4- or 7-membered rings is disfavored. Hiyo KOH acidie workup 2. An interesting problem that involves a bit of review (imines and Grignard chemistry) and application of what you previously learned to a new reaction: The Carbon of an imine functional group (i.e. R.C-NR) is sufficiently electron deficient to be...
please answer b) and question 3 b) An uknown ketone F reacted with CH,CH MgBr, followed...
please answer b) and question 3
b) An uknown ketone F reacted with CH,CH MgBr, followed by acidic hydrolysis to produce alcohol G, CHO. Reaction of F with sodium borohydride in methanol gives compound J, a chiral compound that undergoes dehydration with concentrated sulphuric acid to give 2-pentene as the major product. Write the reaction scheme involved and deduce the structure of F, Gand K Ketone F yang tidak diketahui bertindak balas dengan CH,CH MgBr, dikut dengan hidrolisis berasid menghasilkan...
a. Provide the major product(s) of its reaction with BH3-THF followed by H2O2 in basic aqueous solution. Include stereo...
a. Provide the major product(s) of its reaction with BH3-THF followed by H2O2 in basic aqueous solution. Include stereochemistry. In addition, draw the arrow(s) that leads to the initial interaction between alkene and BH3. Draw the structure of that intermediate and label atoms with d+ and d- to show partial charges, Give a BRIEF explanation for the regioselectivity of the step that follows. b. Provide the curved arrow mechanism and the major product(s) of its reaction with Hg(OAc)2 in 1-propanol...
or esterfication for D Which method would give this ketone? CH,CHE 1. PhMgBr 2. H307 1....
or
esterfication for D
Which method would give this ketone? CH,CHE 1. PhMgBr 2. H307 1. CH3CH MgBr 2. Hz0+ 1. CH2CHCN 2. PHCN CH3CH,COCI, AICI: TOLONIA O2 and 3 only 1 and 3 only 1. NaCN 2. H30, Heat CONH2 COH со,Н NH2 Question 14 (1 point) Which structure is consistent with the following proton NMR data: 1.2 (3H, triplet, J = 8Hz), 3.7 (2H, quartet, J = 8Hz), 4.1 (2H, singlet), 11.1 (1H, singlet) CH2CH3 och Por o...
(C) Protonation of alkene to form a carbocation followed by addition of bromide ion (D) Addition...
(C) Protonation of alkene to form a carbocation followed by addition of bromide ion (D) Addition of the proton to one face of the alkene with simultaneous delivery of a bromide ion from a different molecule of H-Br. 11. Which compound is the strongest nmucleophile for reaction of methane methanesulfonate (CHOS0.CH) in methanol at room temperature? (You may assume that everything is soluble in methanol) (A) potassium bromide (B) cesium iodide (C) sodiam chloride (D) lithium flaoride 12. Which proton...
Can you help me identify reagent (i), Compound 8 and Compound 12 in the reaction scheme?...
Can you help me identify reagent (i), Compound 8 and
Compound 12 in the reaction scheme?
You have laboratory data on all the compounds in the
synthesis, however the amount of data available to you varies. Some
have the entirety of the spectral data, others have as little as
the elemental analysis. Use the laboratory data to help you
discover which reaction has been performed.
The lab data for Compound 8 and 12 is as
follows:
You can use any...
Show the product of reaction of the indicated ester with LDA,
followed by butyl iodide.
CHÚCH 0 1. Provide a correct name for the indicated ester. 2. How many signals would we expect to see in the 13C NMR spectrum? 3. Show the combination of reagents required to synthesize the indicated structure using a Fischer esterification reaction. 4. a. The indicated ester is submitted to Claisen condensation conditions, using the appropriate alkoxide base and a second acidification step. The product...
Draw a structural formula for the product of the aldol reaction of the compound shown above, as well as the a.B-unsaturated aldehyde or ketone formed from dehydration of the aldol product. You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. • Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right comer. Separate structures using the sign from the drop-down menu. . o 1. Og 2. (CH3)2...
3. When 2-ethylcyclohexanone is treated with LDA (in the solvent THF), followed by ethyl bromide, two different alkylated products are formed. Answer the following questions about this reaction. 1) LDA THE two products 2) CH CH Br 3. a. What is LDA and what is its purpose? 3. b. Draw mechanisms for the reactions and show how the two different products are formed. Product A Mechanism Product B Mechanism 3. c. Draw an energy diagram for the formation of both...
Thank you！
9. What would be the product of the following conversion? 1. NaOEt, EIOH OEt 2. H,о- OEt ОН О OEt OEt OEt OE OEt e. d. 10. What is the product of the Dieckmann condensation of the following diester? 1.NaOCH, CH,Oн HgCOoc coOCHs 2. H,0* осн, COOCH COOCH b. d. both a) and b) e. a), b), and c) a. C. 11. Consider the synthesis below. What is compound X? COOEt COOH 1. КОВи 1. NAOH, H2O, heat...
1. Provide the products of the reaction below and a detailed reaction mechanism using curved arrows to indicate the movement of electrons. (a) (b) КОН (c) Note that formation of 4- or 7-membered rings is disfavored. Hiyo KOH acidie workup 2. An interesting problem that involves a bit of review (imines and Grignard chemistry) and application of what you previously learned to a new reaction: The Carbon of an imine functional group (i.e. R.C-NR) is sufficiently electron deficient to be...
please answer b) and question 3
b) An uknown ketone F reacted with CH,CH MgBr, followed by acidic hydrolysis to produce alcohol G, CHO. Reaction of F with sodium borohydride in methanol gives compound J, a chiral compound that undergoes dehydration with concentrated sulphuric acid to give 2-pentene as the major product. Write the reaction scheme involved and deduce the structure of F, Gand K Ketone F yang tidak diketahui bertindak balas dengan CH,CH MgBr, dikut dengan hidrolisis berasid menghasilkan...
a. Provide the major product(s) of its reaction with BH3-THF followed by H2O2 in basic aqueous solution. Include stereochemistry. In addition, draw the arrow(s) that leads to the initial interaction between alkene and BH3. Draw the structure of that intermediate and label atoms with d+ and d- to show partial charges, Give a BRIEF explanation for the regioselectivity of the step that follows. b. Provide the curved arrow mechanism and the major product(s) of its reaction with Hg(OAc)2 in 1-propanol...
or
esterfication for D
Which method would give this ketone? CH,CHE 1. PhMgBr 2. H307 1. CH3CH MgBr 2. Hz0+ 1. CH2CHCN 2. PHCN CH3CH,COCI, AICI: TOLONIA O2 and 3 only 1 and 3 only 1. NaCN 2. H30, Heat CONH2 COH со,Н NH2 Question 14 (1 point) Which structure is consistent with the following proton NMR data: 1.2 (3H, triplet, J = 8Hz), 3.7 (2H, quartet, J = 8Hz), 4.1 (2H, singlet), 11.1 (1H, singlet) CH2CH3 och Por o...
(C) Protonation of alkene to form a carbocation followed by addition of bromide ion (D) Addition of the proton to one face of the alkene with simultaneous delivery of a bromide ion from a different molecule of H-Br. 11. Which compound is the strongest nmucleophile for reaction of methane methanesulfonate (CHOS0.CH) in methanol at room temperature? (You may assume that everything is soluble in methanol) (A) potassium bromide (B) cesium iodide (C) sodiam chloride (D) lithium flaoride 12. Which proton...
Can you help me identify reagent (i), Compound 8 and
Compound 12 in the reaction scheme?
You have laboratory data on all the compounds in the
synthesis, however the amount of data available to you varies. Some
have the entirety of the spectral data, others have as little as
the elemental analysis. Use the laboratory data to help you
discover which reaction has been performed.
The lab data for Compound 8 and 12 is as
follows:
You can use any...
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