Assuming equilibrium considerations, calculate the relative proportions (percentages) of sulfur in the H2S, HS−, and S= forms at a pH of 7.5. The pKa1 =
7.0 and pKa2 = 12.9.
Assuming equilibrium considerations, calculate the relative proportions (percentages) of sulfur in the H2S, HS−, and S=...
Consider the following mechanism: H2S <--> H+ + HS- (fast equilibrium) Cl2 + HS --> 2Cl- + H+ + S (slow) An intermediate is And the best rate law is
The equilibrium constant, Kc, for the following reaction is 1.80x10 at 298 K. NH HS(S)N)+HSg) Calculate the equilibrium concentration of HS when 0.529 moles of NH,HS() are introduced into a 1.00 L vessel at 298 K H2S
need help with both questions
7. Consider the following equilibrium, HS- + HC204- 5 H2S + C202-For oxalic acid the first and second acid dissociation constants are 5.6 x 102 and 5.4 x 10, respectively, and for hydrosulfuric acid the first and second acid dissociation constants are 9.5 x 108 and 1.0 x 10-19, respectively. Calculate the equilibrium constant, Keq. 12. A buffer with pH = 10.15 is to be prepared by addition solid sodium hydrogen carbonate to 1.00 L...
34. At volcanic sites, sulfur is formed via the following reaction. 2 H2S(g) +SO2(g) = 3S(s) +2 H20(g) a. Calculate the equilibrium constant, K, for this reaction at 25°C. 4 Gº (kJ/mol H2S (8) SO2) H20 (8) -33.0 -300.4 -228.6 s, b. Predict whether sulfur formation becomes more or less favorable as temperature increases. Explain. C Sulfur dioxide is a pollutant released by power plants. Would this reaction be suitable for removing SO2 from power plant waste?
3.(12pts) The reaction Cl(aq) + HS(a) determined DRL S)+(aq) +2 Cl(aq) has the experimentally rate k[Cl2][H2S] Which of the following mechanisms is(are) consistent with the experimental results. Mech I Mech 11, Mech III Cl2 +H2S >H CI CI+HS (slow) CI+ + HS. …>H+ + Cl. + S H2S = HS. + H+ HSCl2 2CI +S+H (fast) (fast equil) (slow) H2S HS+H (fast equil) (fast equil) (slow) 4. (10 pts) Write the equilibrium constant Ke expression for the following 4 KO:(s)...
Find the calculations for the data of this
population?
a) Calculate the relative fitness for each of the
three genotypes?
b) What is the mean fitness of this population, and
how do you expect it to change in response to selection?
c) Based on the calculations in a), calculate the
values of h and s. What type of selection has occured?
d) If the surviving individuals mate at random, what
will be the genotype frequencies in the next generation (...
7. A low concentration of NTA has equilibrated with
PbCO3(s) at pH 7.00 in a medium having a final
HCO3- concentration of 7.50x10-4
M.
a. Determine [Pb2+].
b. Write out KT and the overall reaction for
KT.
c. What is the ratio of [Pb(NTA)- ] to
[H(NTA)2-] in this solution?
Potentially useful data: Reaction Hg 2 +2e = Hgº(s) Feste = Fe2 Cu 2 +2e = Cuº(s) 2H + 2e = H2(g) Pb2 +2e=Pbº(s) Ca*2 + 2e = Cdº(s) 1/4...
6. Given a total dissolved lead concentration of
2.0x10-5 M, a total dissolved NTA concentration of
2.0x10-2 M, and a pH of 12.3 (note extreme pH)
a. Under these conditions, what is the dominant form of NTA?
b. Write an equation for total dissolved NTA and for total
dissolved Pb. What assumptions can you make?
c. Calculate the predicted [Pb2+], considering NTA
complexation only?
d. What is the [Pb2+] as predicted by the solubility
of Pb(OH)2(s) at pH 12.3?
e....
Calculate the standard free-energy change and the equilibrium constant Kc for the following reaction at 25°C. See Appendix C for data. Fe(s) + Cu2+ (aq) = Fe2+ (aq) + Cu(s) Find equilibrium constan + K at 25°C Appendix C Thermodynamic Quantities for Substances and Ions at 25°C Substance or lon AH; (kJ/mol) AG; (kJ/mol (J/mol-K) 20.87 Substance or lon Ba(OH),(s) ΔΗ: (kJ/mol) -946.3 --3342.2 AG (kJ/mol) -859.3 -2793 (J/mol K) 107.1 427 Ba(OH), 8H,O(s) BaSO (8) - 1473.2 -1362.3 132.2...
10. Write a one-page summary of the attached paper? INTRODUCTION Many problems can develop in activated sludge operation that adversely affect effluent quality with origins in the engineering, hydraulic and microbiological components of the process. The real "heart" of the activated sludge system is the development and maintenance of a mixed microbial culture (activated sludge) that treats wastewater and which can be managed. One definition of a wastewater treatment plant operator is a "bug farmer", one who controls the aeration...