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Oxidation Practice PCC How HOVOH to ma CH,CI2 он PCC (B. Banks, E1 2019) OH -...
1) + NaOH J) OH PCC CH,C1, K) H СН,ОН L) 1. Mg, ether -Br o...
1) + NaOH J) OH PCC CH,C1, K) H СН,ОН L) 1. Mg, ether -Br o 2. 3. H,0 M) OH Na Cr 0 H2SO4 4. Propose Mechanism (Show your work) (14 pts) A) CH,CH,CH,OH CHỊCH CHỊCHCHỊCOH
List in Order (a) 0 EtNH, (excess) ОН H2SO4 (cat.) OCH3 + CH,OH (excess) + H2O...
List in Order
(a) 0 EtNH, (excess) ОН H2SO4 (cat.) OCH3 + CH,OH (excess) + H2O CI NH -02 S- HÓ: OH Hd 0–CH OCH CI LOH Hac +N-H H NH A HON A HO OH H ---CH ام وی ام H 0 CH Step #1 Step #2 Step #3 D E H2O, H2SO4 (cat.) ОН Step #1 Step #2 Step #3 Step #4 Step #5 Step #6 N ОН 0 H S- HO HO NH 0 H sos-0 B...
COLUMNA 0 NO2 19 COLUMN B O + OH OH A) HAN AICI: 1) ch 2...
COLUMNA 0 NO2 19 COLUMN B O + OH OH A) HAN AICI: 1) ch 2 BHA 3) H,09 B) YN B 1) My C) ОН 2) 2)CO2 3) H30 4) CH3OH D) 3) E) 0 OH H 1)DBAL-H 2)Ph PCH2 3) mCPBA 1) SOCI2 2CH.NH. pyridine 3) excess LAHA 4)H,0* F) 0 O 4) OH o G) excess HB H) 5) 1) 6) H30* Δ. Mglk J) 7) OH 0 2 1,0 hp question completion Status: Н. 6) Н...
HO A) -CH OH PCC, excess CH2Cl2 B) 1) O 2) (CH3), 15) Rank the following...
HO A) -CH OH PCC, excess CH2Cl2 B) 1) O 2) (CH3), 15) Rank the following compounds in the decreasing order of reactivity towards nucleophilic addition reaction? 3 Pt ! H Most Reactive: Least Reactive 16) Write the reagents for the following transformations? 6 Pt مر 8 B) 0 OH C)
Question 20 15 pts OH A) HBO K) Cl2, hv B) NaOH, H2O L) SOCI2 C)...
Question 20 15 pts OH A) HBO K) Cl2, hv B) NaOH, H2O L) SOCI2 C) CH3COONa, DMF M) LIAIHA, THE D) CH3CH2CH2CH2MgBr, ether N) NaBH4, CH3CH2OH E) CH3CH2MgBr, ether O) CH3CH2OH, H2SO4 F) CH3CH2Li, ether P) CH3CH2ON, CH3OH G) Croz, H2SO4, H20 Q) H3O+ H) PCC, CH2Cl2 R) PBr3 1) Brą, hv S) H2, Pd J) heat T) CH3CH2CH2CH2OH, heat U) H20, H2SO4 Look at the given synthesis and the provided reagents. Fill in the blanks with the single...
Hас CH-O Haс H2SO4 Heat Hас 2 CH-OH O-CH3 CHз O-CH CH3 + 2 Hзс-он Hас...
Hас CH-O Haс H2SO4 Heat Hас 2 CH-OH O-CH3 CHз O-CH CH3 + 2 Hзс-он Hас Hас-о D с В A diisopropyl terephthalate 250.29 g/mol d 1.076 g/ml (est.) bp 300 C (est.) dimethyl terephthal ate 194.19 g/mol d 1.075 g/mL bp 288°C methanol isopropanol 60.10 g/mol 0.7855 g/mL 32.04 g/mol Bde lind 0.7914 g/mL 64.6 °C bp 82.3 °C O C Problem Two. Start over. This time assume A is a solid and 423.6 mg of A was measured...
нс Br СН,ОН HC CH a. Write the rate law for this reaction. How does this...
нс Br СН,ОН HC CH a. Write the rate law for this reaction. How does this compare to the rate law for an SN1 reaction? b. Do you think that both E1 and Sn1 reactions will have similar reaction energy diagrams? Why or why not? 2. Show the mechanism and product or products for an E2 reaction. (Mechanism 9.5 in your text walks you through this example). -CH3 + Hope НАС Сн, CH,CH-OH Br a. What is the rate law...
practice questions ③ show the product on products Expected for the reactions below a) + CH₃OH...
practice questions
③ show the product on products Expected for the reactions below a) + CH₃OH alcohol c-c-c aldehyde c-c-c acid C b) 014 + CH3 CH alcohol ÖH c) -10 kmnog LOH heat (Excess) cox - Bonus! 0: CEN: d) -10- H₂ Pd/c. (Excess H2) (Red) H -Bones! e) ÖH ć. + -10 alcohol он acid croch Grid x + CH₃ CH₂ 0 4 (drohol) -10 NH₂ 3 continued - show prodoct (s) رخ دن 2) 15 PH:10 NaOH...
LAB VII. PRACTICE PROBLEMS - CHAPTER 4 NAME: SECTION: b) How many grams of strontium nitrate,...
LAB VII. PRACTICE PROBLEMS - CHAPTER 4 NAME: SECTION: b) How many grams of strontium nitrate, Sr(NO), are needed to prepare 3.40x10 ml. of a 0.925 M solution? c) To what volume should 50.0mL of a 6.00M HCI stock solution be diluted to obtain a 1.50M HCl solution? How much water should be used? d) A 38.5ml sample of 0.875M AgNO, solution is mixed with 51.0mL sample of 0.744M NaCl solution. The AgCl precipitated has a mass of 2.06g. Calculate...
practice complely the follow, + NaOH following (Fill in the Blanks (ose wnds carboxylic Acid +...
practice
complely the follow, + NaOH following (Fill in the Blanks (ose wnds carboxylic Acid + Amine water carboxylic Aad & Alcohol Carboxylic Acid water Esten + H₂O + tre hydrolysis? Amide + H₂O titre hydedlysis Show the reagent / reagents needed to make the following molecolar conversions. Show reagent (s) to the right. Seach=40 HC=CH₂ HC-CH₃ 4 ة= SH please note: the is an aromated ring. It does not atlect the chemistry Hocao 0 ÖzçēH (oxidation? bacco in there...
1) + NaOH J) OH PCC CH,C1, K) H СН,ОН L) 1. Mg, ether -Br o 2. 3. H,0 M) OH Na Cr 0 H2SO4 4. Propose Mechanism (Show your work) (14 pts) A) CH,CH,CH,OH CHỊCH CHỊCHCHỊCOH
List in Order
(a) 0 EtNH, (excess) ОН H2SO4 (cat.) OCH3 + CH,OH (excess) + H2O CI NH -02 S- HÓ: OH Hd 0–CH OCH CI LOH Hac +N-H H NH A HON A HO OH H ---CH ام وی ام H 0 CH Step #1 Step #2 Step #3 D E H2O, H2SO4 (cat.) ОН Step #1 Step #2 Step #3 Step #4 Step #5 Step #6 N ОН 0 H S- HO HO NH 0 H sos-0 B...
COLUMNA 0 NO2 19 COLUMN B O + OH OH A) HAN AICI: 1) ch 2 BHA 3) H,09 B) YN B 1) My C) ОН 2) 2)CO2 3) H30 4) CH3OH D) 3) E) 0 OH H 1)DBAL-H 2)Ph PCH2 3) mCPBA 1) SOCI2 2CH.NH. pyridine 3) excess LAHA 4)H,0* F) 0 O 4) OH o G) excess HB H) 5) 1) 6) H30* Δ. Mglk J) 7) OH 0 2 1,0 hp question completion Status: Н. 6) Н...
HO A) -CH OH PCC, excess CH2Cl2 B) 1) O 2) (CH3), 15) Rank the following compounds in the decreasing order of reactivity towards nucleophilic addition reaction? 3 Pt ! H Most Reactive: Least Reactive 16) Write the reagents for the following transformations? 6 Pt مر 8 B) 0 OH C)
Question 20 15 pts OH A) HBO K) Cl2, hv B) NaOH, H2O L) SOCI2 C) CH3COONa, DMF M) LIAIHA, THE D) CH3CH2CH2CH2MgBr, ether N) NaBH4, CH3CH2OH E) CH3CH2MgBr, ether O) CH3CH2OH, H2SO4 F) CH3CH2Li, ether P) CH3CH2ON, CH3OH G) Croz, H2SO4, H20 Q) H3O+ H) PCC, CH2Cl2 R) PBr3 1) Brą, hv S) H2, Pd J) heat T) CH3CH2CH2CH2OH, heat U) H20, H2SO4 Look at the given synthesis and the provided reagents. Fill in the blanks with the single...
Hас CH-O Haс H2SO4 Heat Hас 2 CH-OH O-CH3 CHз O-CH CH3 + 2 Hзс-он Hас Hас-о D с В A diisopropyl terephthalate 250.29 g/mol d 1.076 g/ml (est.) bp 300 C (est.) dimethyl terephthal ate 194.19 g/mol d 1.075 g/mL bp 288°C methanol isopropanol 60.10 g/mol 0.7855 g/mL 32.04 g/mol Bde lind 0.7914 g/mL 64.6 °C bp 82.3 °C O C Problem Two. Start over. This time assume A is a solid and 423.6 mg of A was measured...
нс Br СН,ОН HC CH a. Write the rate law for this reaction. How does this compare to the rate law for an SN1 reaction? b. Do you think that both E1 and Sn1 reactions will have similar reaction energy diagrams? Why or why not? 2. Show the mechanism and product or products for an E2 reaction. (Mechanism 9.5 in your text walks you through this example). -CH3 + Hope НАС Сн, CH,CH-OH Br a. What is the rate law...
practice questions
③ show the product on products Expected for the reactions below a) + CH₃OH alcohol c-c-c aldehyde c-c-c acid C b) 014 + CH3 CH alcohol ÖH c) -10 kmnog LOH heat (Excess) cox - Bonus! 0: CEN: d) -10- H₂ Pd/c. (Excess H2) (Red) H -Bones! e) ÖH ć. + -10 alcohol он acid croch Grid x + CH₃ CH₂ 0 4 (drohol) -10 NH₂ 3 continued - show prodoct (s) رخ دن 2) 15 PH:10 NaOH...
LAB VII. PRACTICE PROBLEMS - CHAPTER 4 NAME: SECTION: b) How many grams of strontium nitrate, Sr(NO), are needed to prepare 3.40x10 ml. of a 0.925 M solution? c) To what volume should 50.0mL of a 6.00M HCI stock solution be diluted to obtain a 1.50M HCl solution? How much water should be used? d) A 38.5ml sample of 0.875M AgNO, solution is mixed with 51.0mL sample of 0.744M NaCl solution. The AgCl precipitated has a mass of 2.06g. Calculate...
practice
complely the follow, + NaOH following (Fill in the Blanks (ose wnds carboxylic Acid + Amine water carboxylic Aad & Alcohol Carboxylic Acid water Esten + H₂O + tre hydrolysis? Amide + H₂O titre hydedlysis Show the reagent / reagents needed to make the following molecolar conversions. Show reagent (s) to the right. Seach=40 HC=CH₂ HC-CH₃ 4 ة= SH please note: the is an aromated ring. It does not atlect the chemistry Hocao 0 ÖzçēH (oxidation? bacco in there...
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