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The electrons within the confined 1,3-diene, C4Hs. observed in the uv region of the spectrum at a wavelength of 210 nm. Estimate the effective π system of conjugated hydrocarbons may be treated a s particles Within a one-dimensional box. The lowest energy transition in the spectrum of buta- ene, CaH6, corresponds to excitation of an electron from the HOMO to LUMO and is chain length of buta-1,3-diene in Angstrom.
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LUMO 8m 간 c. 첬 X 9.LO9 X lo-. 최 X 3x10

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