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#4 and #5
4. Diesel fuel if made of hydrocarbons with an average of 13 carbon atoms per molecule, and gasoline is made of hydrocarbons with an average of 7 carbon atoms per molecule. Which fuel has the higher vapor pressure at room temperature? Explain why (be specific). 5. The difference between the molar concentration and the molal concentration of any dilute aqueous solution is small. Why?
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ans 5.above fig when solution is dilute aqueous the amount of solvent is approxmately equal to the amount of solution in mass the densty is 1 for water hence solvent volume is equal to total solution and molarity and molality become equal

ans4 .The vapour pressure of a liquid depend on how volatile the liquid and it depend on the force of attraction between the molecules (may be ions dipole ) of a substance .In hydrocarbons van der waals forces which depends on molar mass substance and surface area molecule .If no of carbon is high both molar mass and surface are increase so the higher carbon compounds have low vapour pressure.Hence diseal fuel has low vapour pressure.

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