A sample of \(\mathrm{N}_{2} \mathrm{O}_{3}\) contains 1 moles of nitrogen. Use the following atomic masses: \(\mathrm{N}=14, \mathrm{O}=16\).
$$ \begin{array}{|l|l|l|} \hline \text { The number of moles of } \mathrm{N}_{2} \mathrm{O}_{3} \text { present }= & \mathrm{mol} \mathrm{N}_{2} \mathrm{O}_{3} \\ \hline \text { The mass of the sample }= & \mathrm{g} \mathrm{N}_{2} \mathrm{O}_{3} \\ \hline \text { The number of moles of oxygen in the sample }= & & \mathrm{mol} \mathrm{O} \\ \hline \text { The mass of oxygen in the sample }= & \mathrm{g} \mathrm{O} \\ \hline \end{array} $$
Balance the following equation using the smallest integer coefficients.
a)
$$ \mathrm{H}_{3} \mathrm{PO}_{4}+\mathrm{KOH} \rightarrow \quad \mathrm{K}_{3} \mathrm{PO}_{4}+\mathrm{H}_{2} \mathrm{O} $$
b)
$$ \mathrm{N}_{2} \mathrm{O}_{5}+\quad \mathrm{H}_{2} \mathrm{O} \rightarrow \quad \mathrm{HNO}_{3} $$
c)
$$ \begin{array}{llll} \mathrm{Al}+ & \mathrm{H}_{2} \mathrm{O} \rightarrow & \mathrm{Al}(\mathrm{OH})_{3}+ & \mathrm{H}_{2} \end{array} $$
1. A river contains a relatively low concentration of dissolved salts, so that the ideal assumption applies. The river has the same \(\mathrm{pH}(8.1)\) and total carbonate concentration \(\left(2 \times 10^{-3} \mathrm{M}\right)\) as bulk seawater. The work of Garrels and Thompson (1962) indicates that the total ion activity coefficients of \(\mathrm{H}^{+}, \mathrm{OH}^{-}\), and various carbonate-containing species in seawater are as follows:$$ \begin{array}{|c|c|} \hline & \begin{array}{c} \text { activity } \\ \text { coefficient } \\ \text { lon } \end{array} &...
Which of the following reactions are redox reactions?Check all that apply.$$ \begin{array}{l} \mathrm{Mg}(\mathrm{s})+\mathrm{Br}_{2}(\mathrm{l}) \rightarrow \mathrm{MgBr}_{2}(\mathrm{~s}) \\ \mathrm{Al}(\mathrm{s})+3 \mathrm{Ag}^{+}(\mathrm{aq}) \rightarrow \mathrm{Al}^{3+}(\mathrm{aq})+3 \mathrm{Ag}(\mathrm{s}) \\ 4 \mathrm{~K}(\mathrm{~s})+\mathrm{O}_{2}(\mathrm{~g}) \rightarrow 2 \mathrm{~K}_{2} \mathrm{O}(\mathrm{s}) \\ \mathrm{SO}_{3}(\mathrm{~g})+\mathrm{H}_{2} \mathrm{O}(\mathrm{l}) \rightarrow \mathrm{H}_{2} \mathrm{SO}_{4}(\mathrm{aq}) \end{array} $$
A sample of N2O3 contains 2.26 moles of nitrogen. Use the following atomic masses: N =14, O=16. The number of moles of N2O3 present = mol N2O3 The mass of the sample = g N2O3 The number of moles of oxygen in the sample = mol O The mass of oxygen in the sample = g O
Gases are different from solids and liquids. In a sample of gas, the molecules are far apart. The gas molecules also move around and collide with each other as well as with the walls of the container. These collisions generate pressure. The pressure of a gas can be measured in different units. One convenient unit of measure is called the atmosphere (atm) because it is based on atmospheric pressure. At sea level, the average pressure is 1 atm. As you...
1. Calculate the current, voltage potential, and power for each resistor, and fill out Table \(1 .\) Assume \(V_{i n}=24 V\)$$ \begin{array}{|c|c|c|c|c|} \hline \text { Resistor } & \text { Resistance }(\Omega) & \text { Voltage (V) } & \text { Current (mA) } & \text { Power (W) } \\ \hline R_{1} & 1 \mathrm{k} & & & \\ \hline R_{2} & 10 & & & \\ \hline R_{3} & 2 \mathrm{k} & & & \\ \hline R_{4} &...
Calculate \(\Delta \mathrm{H}^{\circ}\) and \(\Delta \mathrm{G}^{\circ}\), using data in Appendix C. Determine whether each reaction is endothermic or exothermic, and spontaneous or nonspontaneous.a) \(\quad 2 P b O(s)+N_{2}(g) \rightarrow 2 P b(s)+2 N O(g)\)b) \(\mathrm{CS}_{2}(l)+2 \mathrm{H}_{2} \mathrm{O}(l) \rightarrow \mathrm{CO}_{2}(g)+2 \mathrm{H}_{2} \mathrm{~S}(g)\)
2. a) Balance the equation below and use it to calculate the moles of Fe formed from \(0.50\) moles of \(\mathrm{Fe}_{2} \mathrm{O}_{3}:\)$$ \mathrm{Fe}_{2} \mathrm{O}_{3}(\mathrm{~s})+\mathrm{CO}(\mathrm{g}) \stackrel{\Delta}{\rightarrow} \mathrm{Fe}(\mathrm{s})+\mathrm{CO}_{2}(\mathrm{~g}) $$3. Balance the equation below then calculate the mass of \(\mathrm{ZnCl}_{2}\) by obtained by reacting \(10.0 \mathrm{~g}\) of zinc metal with an excess (more than is required) of hydrochloric acid$$ \mathrm{Zn}(\mathrm{s})+\mathrm{HCl}(\mathrm{aq}) \rightarrow \mathrm{ZnCl}_{2}(\mathrm{aq})+\mathrm{H}_{2}(\mathrm{~g}) $$
23. Place the following in order of increasing IE1.\(\begin{array}{lll}\mathrm{N} & \mathrm{F} & \text { As }\end{array}\)A) \(\mathrm{N}<\mathrm{As}<\mathrm{F}\)B) \(A s<N<F\)C) \(\mathrm{F}<\mathrm{N}<\mathrm{As}\)D) As \(<F<N\)E) \(\mathrm{F}<\mathrm{AS}<\mathrm{N}\)24. Place the following in order of decreasing metallic character.\(\mathrm{P} \quad\) As \(\quad \mathrm{K}\)A) \(\mathrm{P}>\mathrm{As}>\mathrm{K}\)B) \(\mathrm{As}>\mathrm{P}>\mathrm{K}\)C) \(\mathrm{K}>\mathrm{P}>\mathrm{As}\)D) \(\mathrm{As}>\mathrm{K}>\mathrm{P}\)E) \(K>A s>P\)25. Choose the paramagnetic species from below.A) Ti4+B) \(\mathrm{O}\)C) \(\mathrm{Ar}\)26. Give the set of four quantum numbers that could represent the electron gained to form the Br- ion from the \(\mathrm{Br}\) atom.A) \(n=4, l=2, m l=1, m s=-\frac{1}{2}\)B) \(n=4,...
Calculate \(E_{\text {cell }}^{\circ}\) for a iron-cadmium cell in which the cell reaction is$$ 2 \mathrm{Fe}^{2+}(\mathrm{aq})+\mathrm{Cd}^{2+}(\mathrm{aq}) \rightarrow 2 \mathrm{Fe}^{3+}(\mathrm{aq})+\mathrm{Cd}(\mathrm{s}) $$$$ \begin{array}{ll} \mathrm{Fe}^{3+}+e^{-} \rightarrow \mathrm{Fe}^{2+} & E^{\mathrm{O}}=0.77 \mathrm{~V} \\ \mathrm{Cd}^{2+}+2 e^{-} \rightarrow \mathrm{Cd} & E^{\mathrm{O}}=-0.40 \mathrm{~V} \end{array} $$is oxidized in the reaction: \(2 \mathrm{Fe}^{2+}(\mathrm{aq})+\mathrm{Cd}^{2+}(\mathrm{aq}) \rightarrow 2 \mathrm{Fe}^{3+}(\mathrm{aq})+\mathrm{Cd}(\mathrm{s})\)Select one:A. -0.37 VB. 0.37 VC. -1.17 VD. 1.17 VE. none of these
Given the standard enthalpy changes for the following two reactions:(1) \(2 \mathrm{C}(\mathrm{s})+2 \mathrm{H}_{2}(\mathrm{~g}) \longrightarrow \mathrm{C}_{2} \mathrm{H}_{4}(\mathrm{~g}) \quad \Delta \mathrm{H}^{\circ}=\mathbf{5 2 . 3} \mathrm{kJ}\)(2) \(2 \mathbf{C}(\mathbf{s})+\mathbf{3 H}_{\mathbf{2}}(\mathbf{g}) \longrightarrow \mathbf{C}_{\mathbf{2}} \mathbf{H}_{\mathbf{6}}(\mathbf{g}) \quad \Delta \mathrm{H}^{\circ}=-\mathbf{8 4 . 7} \mathrm{kJ}\)what is the standard enthalpy change for the reaction:(3) \(\mathbf{C}_{\mathbf{2}} \mathbf{H}_{\mathbf{4}}(\mathbf{g})+\mathbf{H}_{\mathbf{2}}(\mathbf{g}) \longrightarrow \mathbf{C}_{\mathbf{2}} \mathbf{H}_{\mathbf{6}}(\mathbf{g}) \quad \Delta \mathrm{H}^{\circ}=?\)Given the standard enthalpy changes for the following two reactions:(1) \(\mathrm{N}_{2}(\mathrm{~g})+2 \mathrm{O}_{2}(\mathrm{~g}) \longrightarrow 2 \mathrm{NO}_{2}(\mathrm{~g}) \quad \Delta \mathrm{H}^{\circ}=66.4 \mathrm{~kJ}\)(2) \(2 \mathbf{N}_{2} \mathrm{O}(\mathrm{g}) \longrightarrow \mathbf{2 N}_{2}(\mathbf{g})+\mathbf{O}_{2}(\mathrm{~g}) \quad \Delta \mathrm{H}^{\circ}=-\mathbf{1 6...