![BL#1: You find a bottle in the lab that is labeled, organic liquid. You run an IR, 13C NMR, and iH NMR of the sample. From this, you determine a structure that contains a chiral center. How can you determine which enantiomer, R or S, that you have? Explain. BL#2: You dilute 1 g of an organic liquid, with ethanol, to 10 mL in a volumetric flask. What concentration is used to calculate the specific rotation, [a] ? 20 -6.8° is BL#3: The solution from BL#2 is analyzed using polarimetry (at 20°C), and an optical rotation of observed. Calculate the specific rotation of the organic liquid, if the sample cell that was used was 100 mm.](http://img.homeworklib.com/questions/737f2940-6355-11eb-a009-afe6ba4f701c.png?x-oss-process=image/resize,w_560)
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BL#1: You find a bottle in the lab that is labeled, "organic liquid". You run an...
question #4 Prelab Question #1: (answer the three prelab questions on this printed handout; this question...
question #4
Prelab Question #1: (answer the three prelab questions on this printed handout; this question is 2) related to polarimetry of Limonene): A student dissolves 0.20g of pure R-Limonene in a total of 5 mL of ethanol using a volumetric flask. The student fills a 2 dm polarimetry tube with this solution and observes a rotation of + 8.2° from that sample. Calculate the specific rotation of the student's sample of R-Limonene. 102.5 Formula to use: [a] = 1075...
What more info do you need? this is all we were given. 81% ent Elements Tables...
What more info do you need?
this is all we were given.
81% ent Elements Tables Charts SmartArt Review Paragraph AaBbCcDd Your company, Chiral Synthesis Inc., is looking to procure a supplier of (R)-( 2-phenoxy. propionic acid. A potential supplier, the L.B. Enzyme Company, provided a sample for your inspection. The I.B. Enzyme Company maintains that ther enzymatic generation of (R)-(-). 2 phenoxypropionic acid gives a high quality product that is worth its weight in enzyme. CH, (a) You initially...
1. Polarimetry can be used to: (more than one answer may be correct) -measure the rotation...
1. Polarimetry can be used to: (more than one answer may be correct) -measure the rotation of plane polarized light, but no further analysis can be carried out using the sample. -separate a pair of optical isomers. -find out which isomer of a chiral product you have made, by comparing the specific rotation to literature values for the same solvent, temperature, and wavelength. -determine the optical purity of the purified product from an enantioselective reaction. -determine the optical purity of...
Please help with pre-lab questions. Pre-Lab Questions: 1. A sample of 2-butanol has a specific rotation...
Please help with pre-lab questions.
Pre-Lab Questions: 1. A sample of 2-butanol has a specific rotation of +3.25. Determine the optical purity (%ee) and percent composition of this sample (see Mohrig section 17.4). The specific rotation of pure (+)-2-butanol is +13.0°. 2. The equation for the formation of the diastereomeric salts is shown in the background information (performed in Part A of the procedure). Write this chemical equation in your notebook, then ALSO write a balanced equation for the formation...
ootical for pure substance is +40 1. As the new chemist working at "Drugs Us", you...
ootical for pure substance is +40
1. As the new chemist working at "Drugs Us", you are given the task of resolving racemic phenylethyl- amine into its individual enantiomers using (S)-malic acid as resolving agent. After you carried out the resolution, you labeled the products you isolated "Sample A" and "Sample B. You subjected both samples to polarimetry ( = 589 nm (sodium D-line), 1-dm cell) and obtained the following results. Sample A: 1.00 g dissolved in 10.0 mL methanol...
NMR Exercise Lab Determine the structure of the following unknown organic compounds from the 'H and...
NMR Exercise Lab Determine the structure of the following unknown organic compounds from the 'H and C NM below. When supplying spectroscopic information for parts b-c below, be sure to give units appropriately when identifying specific peaks in a spectrum that are associated with specific portions of the structural formula that you give in part a. (a) Provide a structural formula which is consistent with all of the given information; give the degrees of unsaturation (DoU). (b) For the 15'C...
You must read the experiment and then answer these questions. 1. Look at the procedure for...
You must read the experiment and then answer these questions. 1. Look at the procedure for using a pipet. Why should you not force the last remaining amount of liquid out of the pipet? 2. If you have a 50.00 mL volumetric flask (a flask marked at a specific volume) and a pipette that measures up to 10-mL with marks to the nearest 1/10 mL, how much solute would you add to the flask to make 50.00 mL of a...
Pre-Lab Assignment 1) Draw the reaction mechanism for the reaction. 2) Determine the limiting reagent. Procedure...
Pre-Lab Assignment
1) Draw the reaction mechanism for the reaction.
2) Determine the limiting reagent.
Procedure 1 Place approximately 1 g of stilbene dibromide prepared in last week's experiment in a 50 mL round bottom flask. Record the exact mass. Add 0.8 g of KOH and 4 mL of triethylene glycol from the syringe provided in the fume hood (rinse any crystals from the sides of the flask while adding triethylene glycol). 2 Heat the stirred reaction mixture to a...
need hep with these two questions! here is the information for the lab K2Cr₂O + H₂...
need hep with these two questions!
here is the information for the lab
K2Cr₂O + H₂ C₂04 2H2O sklor (C204) [H202₂/2 H2otca 2k12 2 cr=x2 (+8ly kzcrgo7+ I 142 C204-21420 2 k cellow). (1) 2 - 2 H2O toc -=S7 30-4521 2. Calculate the theoretical yield of K[Cr(C,0.),(H,0), 2H,0. 3. What is the theoretical percentage by weight of Cr in K[Cr(C,0.),(H,0), 2H,0? using the spectrophotometer at your desk, at the wavelength of maximum absorbance of the blue-green chromium ion, measure...
The following questions are from an experiment titled Friedel-Crafts Alkylation for Organic Chemistry II Lab. There...
The following questions are from an experiment titled
Friedel-Crafts Alkylation for Organic Chemistry II Lab. There are
pictures attached of the lab manual.
2) Is this method a good route for the preparation of
p-sec-butyltoulene? Give reasons for your answer.
3) Why do you use a large excess of toulene. What are its
functions?
4) What is the purpose for adding the hydrochloric acid to the
water in the separatory funnel in step 5? Hint: If no acid is
added,...
question #4
Prelab Question #1: (answer the three prelab questions on this printed handout; this question is 2) related to polarimetry of Limonene): A student dissolves 0.20g of pure R-Limonene in a total of 5 mL of ethanol using a volumetric flask. The student fills a 2 dm polarimetry tube with this solution and observes a rotation of + 8.2° from that sample. Calculate the specific rotation of the student's sample of R-Limonene. 102.5 Formula to use: [a] = 1075...
What more info do you need?
this is all we were given.
81% ent Elements Tables Charts SmartArt Review Paragraph AaBbCcDd Your company, Chiral Synthesis Inc., is looking to procure a supplier of (R)-( 2-phenoxy. propionic acid. A potential supplier, the L.B. Enzyme Company, provided a sample for your inspection. The I.B. Enzyme Company maintains that ther enzymatic generation of (R)-(-). 2 phenoxypropionic acid gives a high quality product that is worth its weight in enzyme. CH, (a) You initially...
Please help with pre-lab questions.
Pre-Lab Questions: 1. A sample of 2-butanol has a specific rotation of +3.25. Determine the optical purity (%ee) and percent composition of this sample (see Mohrig section 17.4). The specific rotation of pure (+)-2-butanol is +13.0°. 2. The equation for the formation of the diastereomeric salts is shown in the background information (performed in Part A of the procedure). Write this chemical equation in your notebook, then ALSO write a balanced equation for the formation...
ootical for pure substance is +40
1. As the new chemist working at "Drugs Us", you are given the task of resolving racemic phenylethyl- amine into its individual enantiomers using (S)-malic acid as resolving agent. After you carried out the resolution, you labeled the products you isolated "Sample A" and "Sample B. You subjected both samples to polarimetry ( = 589 nm (sodium D-line), 1-dm cell) and obtained the following results. Sample A: 1.00 g dissolved in 10.0 mL methanol...
NMR Exercise Lab Determine the structure of the following unknown organic compounds from the 'H and C NM below. When supplying spectroscopic information for parts b-c below, be sure to give units appropriately when identifying specific peaks in a spectrum that are associated with specific portions of the structural formula that you give in part a. (a) Provide a structural formula which is consistent with all of the given information; give the degrees of unsaturation (DoU). (b) For the 15'C...
You must read the experiment and then answer these questions. 1. Look at the procedure for using a pipet. Why should you not force the last remaining amount of liquid out of the pipet? 2. If you have a 50.00 mL volumetric flask (a flask marked at a specific volume) and a pipette that measures up to 10-mL with marks to the nearest 1/10 mL, how much solute would you add to the flask to make 50.00 mL of a...
Pre-Lab Assignment
1) Draw the reaction mechanism for the reaction.
2) Determine the limiting reagent.
Procedure 1 Place approximately 1 g of stilbene dibromide prepared in last week's experiment in a 50 mL round bottom flask. Record the exact mass. Add 0.8 g of KOH and 4 mL of triethylene glycol from the syringe provided in the fume hood (rinse any crystals from the sides of the flask while adding triethylene glycol). 2 Heat the stirred reaction mixture to a...
need hep with these two questions!
here is the information for the lab
K2Cr₂O + H₂ C₂04 2H2O sklor (C204) [H202₂/2 H2otca 2k12 2 cr=x2 (+8ly kzcrgo7+ I 142 C204-21420 2 k cellow). (1) 2 - 2 H2O toc -=S7 30-4521 2. Calculate the theoretical yield of K[Cr(C,0.),(H,0), 2H,0. 3. What is the theoretical percentage by weight of Cr in K[Cr(C,0.),(H,0), 2H,0? using the spectrophotometer at your desk, at the wavelength of maximum absorbance of the blue-green chromium ion, measure...
The following questions are from an experiment titled
Friedel-Crafts Alkylation for Organic Chemistry II Lab. There are
pictures attached of the lab manual.
2) Is this method a good route for the preparation of
p-sec-butyltoulene? Give reasons for your answer.
3) Why do you use a large excess of toulene. What are its
functions?
4) What is the purpose for adding the hydrochloric acid to the
water in the separatory funnel in step 5? Hint: If no acid is
added,...
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