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3. Draw the product for the following reactions H₂Cro4 H3O* & acetone (Jones' reagent) 1. OH...
1. Provide the Major Product from the following reactions CrO3, H2S04 Acetone HBr Me OH OH...
1. Provide the Major Product from the following reactions CrO3, H2S04 Acetone HBr Me OH OH Tsci, Pyr, NaH он Br 2. Provide Reagents for each Letter in the REDOX Ladder See list of Reagents OH on Back OH PCC DIBAL-H (Diisobutylaluminum Hydride) DMSO, COCh then Et:N Swern Oxidation NaBH4 Sodium Borohydride) H2SO4, CrO Jones Oxidation LiAIH4 Lithium Aluminum Hydride KMnO4 NaOCI HNO3 NaOCI/TEMPC DMP (Dess-Martin Periodinane) H2CrO4 A. B. C. D. E. F.
Choose the best reagent for carrying out the following reactions from the list below. Place the l...
Choose the best reagent for carrying out the following reactions
from the list below. Place the letter of the reagent(s) in the box
over the reaction arrow; use only one letter per box. Some letters
may be used more than once, and not all letters need to be
used.
A) LiA1H4, then H3O+ D) CH:MgBr, then H30* G) NaOCHs, then H3O J) NaCN, then H3O B) NH20H, heat E) CH3NH2, heat H) (CH3)2NH, heat K) NaOCH2CH3, heat L PCC in...
In each reaction box, place the best reagent and conditions from the list below. CH3-C=O-OH 1....
In each reaction box, place the best reagent and conditions from the list below. CH3-C=O-OH 1. 2. __________________________________> CH3-C=(N-H)-H 3. 4. Possible reagents: CH3MgBr H2, Pd NH(CH3)2, cat. H3O+ CH3Br PCC NH2NH2 LiAlH4 NH2CH3, cat. H3O+ KMnO4 NH3,cat. H3O+ NaBH4 H2CrO4 H2O
complete the following reactions with the proper stereochemistry as need оCHbb H2SO4 (dilute) OH H2O HBr...
complete the following reactions with the proper
stereochemistry as need
оCHbb H2SO4 (dilute) OH H2O HBr (conc) но H но heat но но H CHs MCPBA OH Jones (CrO3. H,SO4) H2O, acetone 1. MCPBA OH PCC 2. NaCN 3. Hy0 pyridinium chlorochromate CH2CI2, 25 C 1. MCPBA PCC OH pyridinium chlorochromate 2. HBr Cн-Cl, 25 C NaBH OH Hао 1. DMSO, (COCI)2, -60C 1. LIAIH 2. Et N 2. H,0
оCHbb H2SO4 (dilute) OH H2O HBr (conc) но H но...
(1) Show the product of each alcohol oxidation reaction below: OH Croz H30", acetone PCC CH2Cl2...
(1) Show the product of each alcohol oxidation reaction below: OH Croz H30", acetone PCC CH2Cl2 OH Cr₂O, OH H.SO 4, H2O PCC HO CH2Cl2 Nag H2S04, H20 (2) Propose an efficient synthesis for each transformation below mocow OH НО? .name مل.بلو HO / تم.-م" (E) Ph amion e no (F) OMe
help please! 1) Reactions. Provide the major product for each reaction sequence, account for stereochemistry. 1)...
help please!
1) Reactions. Provide the major product for each reaction sequence, account for stereochemistry. 1) PCC, CH2Cl2 2) Brz, acetic acid OH 3) KotBu, A 4) NaOEt, EtOH P CO 8 5) H2O+ workup 6) THF, H.CaPPha HCB , cat. PdOAC) cat. PPh3, DMF, EN | CHA 0 нс. CH32) LDA, THF, -78 °C CHICH,then H3O+ workup 4) NaBH4, EtOH, then H3O+ workup 5) cat. TSOH, benzaldehyde 1) cat. H2SO4, A 2) O3. CH2Cl2, then (CH3)2S CH; 3) NaOE,...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO ROOR Question 2: Draw a mechanism for the following transformations: a) H₃C CH3 HCI H₂C T CH3 HAC CH3 нс с Question 3: Draw the mechanism for the following transformations: нс сH3 CH3 о (H,SO4), он H₂C7 Question 4 HĄCE 1) Hg(OAC), H, 2) NaBH, HEC CH, Question : Predict the product(s) of the following reaction: 1) BHZ. THE Н4С SCH, 2) H2O, NaOH...
1 & 2) Draw the product to the reaction below. 3) Select the chiral atoms in...
1 & 2) Draw the product to the reaction below.
3) Select the chiral atoms in the aspartame molecule.
Draw the product to the reaction below: + OH CH3 H3C—_—HĆ-CH3 + H3C—CH2-OH 6-CH2-CH3 + H20 Draw the product to the reaction below: H3C-CH2-0 H3C—CH2—C—OH + CH3 H3C—CH2-OH + H20 Aspartame is a popular sugar substitute. It is 150 times sweeter than sucrose so very little is needed to sweeten foods. Identify the chirality center(s), sometimes called chiral carbon atoms, in...
1. Give a sequence of reactions to accomplish the following transformation? Show mechanism 2. What reagent(s)...
1. Give a sequence of reactions to accomplish the following transformation? Show mechanism 2. What reagent(s) would accomplish the following? Show mechanism. R-CH2-NH2 R-C-NH2 3. What would result from the reactions shown below? Hsco-s-OCH3 large excess) NaOH нон H,0 но ОН "ОН (a and B) 4. Predict the major product of the following reaction. CHNNH 3 equivalents) но CHCH2OH Heat он CH2OH Draw the Haworth projection for chair conformation of a-D-Glucopyranose (shown below) CH2OH HO H OH OH
Given the Reactant and Product of both reactions above, give the appropriate reagent (1 point) for...
Given the Reactant and Product of both reactions above, give the
appropriate reagent (1 point) for the following alkyne reactions.
Describe the reaction's mechanism (1 point) as well as the product.
Consider the reduction of alkynes in each answer.
H3c— = -CH3 H3c— = CH2
1. Provide the Major Product from the following reactions CrO3, H2S04 Acetone HBr Me OH OH Tsci, Pyr, NaH он Br 2. Provide Reagents for each Letter in the REDOX Ladder See list of Reagents OH on Back OH PCC DIBAL-H (Diisobutylaluminum Hydride) DMSO, COCh then Et:N Swern Oxidation NaBH4 Sodium Borohydride) H2SO4, CrO Jones Oxidation LiAIH4 Lithium Aluminum Hydride KMnO4 NaOCI HNO3 NaOCI/TEMPC DMP (Dess-Martin Periodinane) H2CrO4 A. B. C. D. E. F.
Choose the best reagent for carrying out the following reactions
from the list below. Place the letter of the reagent(s) in the box
over the reaction arrow; use only one letter per box. Some letters
may be used more than once, and not all letters need to be
used.
A) LiA1H4, then H3O+ D) CH:MgBr, then H30* G) NaOCHs, then H3O J) NaCN, then H3O B) NH20H, heat E) CH3NH2, heat H) (CH3)2NH, heat K) NaOCH2CH3, heat L PCC in...
complete the following reactions with the proper
stereochemistry as need
оCHbb H2SO4 (dilute) OH H2O HBr (conc) но H но heat но но H CHs MCPBA OH Jones (CrO3. H,SO4) H2O, acetone 1. MCPBA OH PCC 2. NaCN 3. Hy0 pyridinium chlorochromate CH2CI2, 25 C 1. MCPBA PCC OH pyridinium chlorochromate 2. HBr Cн-Cl, 25 C NaBH OH Hао 1. DMSO, (COCI)2, -60C 1. LIAIH 2. Et N 2. H,0
оCHbb H2SO4 (dilute) OH H2O HBr (conc) но H но...
(1) Show the product of each alcohol oxidation reaction below: OH Croz H30", acetone PCC CH2Cl2 OH Cr₂O, OH H.SO 4, H2O PCC HO CH2Cl2 Nag H2S04, H20 (2) Propose an efficient synthesis for each transformation below mocow OH НО? .name مل.بلو HO / تم.-م" (E) Ph amion e no (F) OMe
help please!
1) Reactions. Provide the major product for each reaction sequence, account for stereochemistry. 1) PCC, CH2Cl2 2) Brz, acetic acid OH 3) KotBu, A 4) NaOEt, EtOH P CO 8 5) H2O+ workup 6) THF, H.CaPPha HCB , cat. PdOAC) cat. PPh3, DMF, EN | CHA 0 нс. CH32) LDA, THF, -78 °C CHICH,then H3O+ workup 4) NaBH4, EtOH, then H3O+ workup 5) cat. TSOH, benzaldehyde 1) cat. H2SO4, A 2) O3. CH2Cl2, then (CH3)2S CH; 3) NaOE,...
Question 1: Draw the expected major product for the following reactions: НІ HC CH CH₂ HBO ROOR Question 2: Draw a mechanism for the following transformations: a) H₃C CH3 HCI H₂C T CH3 HAC CH3 нс с Question 3: Draw the mechanism for the following transformations: нс сH3 CH3 о (H,SO4), он H₂C7 Question 4 HĄCE 1) Hg(OAC), H, 2) NaBH, HEC CH, Question : Predict the product(s) of the following reaction: 1) BHZ. THE Н4С SCH, 2) H2O, NaOH...
1 & 2) Draw the product to the reaction below.
3) Select the chiral atoms in the aspartame molecule.
Draw the product to the reaction below: + OH CH3 H3C—_—HĆ-CH3 + H3C—CH2-OH 6-CH2-CH3 + H20 Draw the product to the reaction below: H3C-CH2-0 H3C—CH2—C—OH + CH3 H3C—CH2-OH + H20 Aspartame is a popular sugar substitute. It is 150 times sweeter than sucrose so very little is needed to sweeten foods. Identify the chirality center(s), sometimes called chiral carbon atoms, in...
1. Give a sequence of reactions to accomplish the following transformation? Show mechanism 2. What reagent(s) would accomplish the following? Show mechanism. R-CH2-NH2 R-C-NH2 3. What would result from the reactions shown below? Hsco-s-OCH3 large excess) NaOH нон H,0 но ОН "ОН (a and B) 4. Predict the major product of the following reaction. CHNNH 3 equivalents) но CHCH2OH Heat он CH2OH Draw the Haworth projection for chair conformation of a-D-Glucopyranose (shown below) CH2OH HO H OH OH
Given the Reactant and Product of both reactions above, give the
appropriate reagent (1 point) for the following alkyne reactions.
Describe the reaction's mechanism (1 point) as well as the product.
Consider the reduction of alkynes in each answer.
H3c— = -CH3 H3c— = CH2
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