This is for my mass spectrometry lab report. I have to figure out the m/z of...
In Lab H, you will be introduced to mass spectrometry as a new analytical technique for identifying molecules. A simplified mass spectrum for ethane is shown below. Use the dropdown menus to identify the base peak and molecular ion peak 14 16 18 20 22 24 26 28 30 32 (m/z) BASE PEAK: Select ] MOLECULAR ION PEAK: [ Select ] Given the mass of the base and molecular ion peaks, choose the two most common fragments of ethane: FRAGMENT...
In Mass Spectrometry (MS) the molar mass of compounds can be determined. The so-called "molecular ion" corresponds to the molecular mass when Electron Impact Mass Spectrometry (EIMS, one of several common MS techniques) is used. It is important to realize, though, that the mass detected by MS depends on the isotopes present in the molecule. The questions below try illustrate the impact of isotope distribution in a molecule. What is the molar mass of the compound shown below? What is...
Mass Spec Diethyl Phthalate Mass Spectrum Relative Intensity m/z MS diethylphthalate (note: major m/z values of 222, 193, 177, 149 are present) 3) Propose structures for TWO fragments in the mass spectrum. Note: the molecular ion peak at 222 m/z is NOT a fragment.
The molecular weight of a compound is typically indicated by the heaviest peak on a mass spectrum, which i presumed to correspond to the molecular ion (M*). For smaller compounds, the heaviest peak tends to also be the most intense peak. The lighter peaks in the spectrum result from fragmentation of the molecule into smaller ions. Since peak intensity correlates to the relative stability of the ions produced, the peaks of the ionized fragments can be more intense than the...
2. Draw the structure of the cation responsible for the base peak (m/z=58) in the mass spectrum of 3-aminopentane shown below: 3. Below is given the mass spectrum of a simple alkane. What is the chemical formula of the alkane? What is the name of the alkane? Explain how you determined the exact structure of the alkane from the observed fragments. 4. Below is a mass spectrum of an ester. Identify the ester. Consider that the dominant fragmentation pathway involves...
The mass spectrum of compound A shows molecular ion peak at m/z 88. The IR spectrum of this compound has a broad peak between 3200 and 3550 cm-1. The 1H NMR spectrum of A shows the following peaks: a triplet at d 0.9, a singlet at d 1.1, one more singlet at d 1.15, and a quartet at d 1.6. The area ratio of these peaks is 3:6:1:2. The 13C NMR contains 4 signals. In the space below, propose a...
4. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. 33 N - PPM 5. Propose a structure for a molecule whose mass spectrum shows a parent ion at m/z 100 with a base peak at m/z 43, an IR peak at 1720 cm' which gave the following 'H NMR spectrum. doublet 2...
Draw the mass spectrum for Vinyl Acetate: C4H6O2 a. Draw out the structure. b. Label the molecular ion peak and base peak. C. Assign structures to the fragment ion peaks at m/e 43, m/e 28 and m/e 15. 100 (43-Base Peak Relative Intensity 20 28 15 86 Mt TTT 20 60 100 120 160 140 mle
Description: Shown below is an EI-MS spectrum for t-butyl chloride. 1) Clearly label the base peak in the spectrum. Draw the structure of the fragment the base peak corresponds to. 2) Is there a molecular ion present in the spectrum? If so, label the peak that corresponds to the molecular ion. 3) Is there any evidence that the following EI-MS spectrum represents a chlorine containing compound? If so, label the necessary peaks and explain briefly why there is sufficient evidence...
Lab 6 Mass Spectrometry Worksheet Please show your work for the following problems in your laboratory notebook. Your notebook carbons will be collected at the beginning of the next lab period. 1. For each of the following molecular formulas, calculate the index of hydrogen deficiency (IHD), and draw at least two possible structures: a. CaH4 22+2--6+04-2 b. CaHs c. CoHsNO2 26)-54t 4 d. CHioBr2 2 215)+2--0+o 2. Write the molecular formulas for three hydrocarbons with the following molecular ion (M)...