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Starting materials Eo ho la Eto V OEt H3C Et k. NaOH, H20 1.HCI, H2O, heat Reagents a. CH3Br f. Eto Na b. CH3CH2Br g. SOCI C. CH3CH2CH2Br h. NH3 d. (CH3)2CHBO i. CH3NH2 e. CH2CH2CH(Br)CH3 j. NH(CH3)2 Compound 1: 1fcfclgi Compound 2: 2fafbkl
O HO Et OH Ph NMe on Ph Et Ph OH Ph OEt Ph A B с D E OET o O O-Et OH Ph OEt Ph Et Ph NH2 Ph Ph F G H J From the list of structures above, select the product for each reaction and enter the letter in the box. For these reactions, assume excess reagent is available to react with the organic compound. o Ph + ОMe EtMgBr 5 0 Ph CI + EtOH...
O HO Et OH Ph NMez Et Ph ОН Ph OEt Ph A B с D E OEt O 0 Et 0- OH Ph OEt Pn Et Ph NH2 Ph Ph ד G H I From the list of structures above, select the product for each reaction and enter the letter in the box. (Assume aqueous workup when needed.) O + Ph NaBH 1 O + CH,Li Ph Н. 2 Product 1 Product 2
Starting with diethylmalonate, which sequence of reactions will give cyclopropane carboxylic acid? -0% OH Eto OEt 1. Excess KOEt 2. Br(CH2)5Br 3. H2O/H307, A O A. 1. Excess KOEt 2. Br(CH2)4Br 3.H2O/H307, A ОВ. 1. Excess KOEt 2. 1,1-dibromocyclopentane 3. H2O/H307, A Ос. 1. Excess KOEt 2. C5H9Br 3. H2O/H307, A OD Which is a mechanistic step in the sulfonation of benzene? SO3H fuming H2SO4 S SEO OH OH A B с D А B с D Which compound has...
Multi-step synthesis ci R R NH, OEt А OH B 1. Br2 / uv light 2. SOCI2 / THE 3. Mg/Et20 4. Meu/hexane S. CH3CH2MgCl 6. Ph MgBe 7. NaBHA 8. LAHA 9. BH3 /OX 10. POCl/pyridine/ THF 11.03/THE 12. PCC / CH2 13.H/H20 14. ELOH/H 15. t-butaxide 16. OH/H20 17. NHS 18.CO2 19. acetic anhydride 20.HNMez/THE In each box, type out the list of reagents in proper order that will carry out the synthesis of the final product (This...
Match each reaction with its reagents. HO CI 2 + enantiomer CI 3 -OH 4 + enantiomer + enantiomer 5 6 OH 8 OH 10 HO 9 Br + enantiomer Br 12 11 aBr 11 Br 12 Reagents: A.) PB B.) NBS, hv c.) D. NaOH E.) NaNH2 F.) Br2 G.) HCI H.) Cl2, H2O 1.) HBO J.) H2 (1 eq), Pt K)Na, NHA L.) H2SO., H2O 0.) M.)1. Hg(OAc)2 2. NaBHA N.) 1. mCPBA 2. H, H2O P.) 1....
3) Which of the following compounds is chiral? A) H Н-С-н н B) H HO C-OH Н C) CH3 HO-C-H Cl D) Br Н-С-ОН н E) C Br- C-C Br 4) In the L- isomer of a Fischer projection of a monosaccharide, the -OH group furthest from the carbonyl is written A) on the left of the top chiral carbon B) on the right of the top chiral carbon C) on the left of the middle chiral carbon D) on...
What is the expected major product for the following reaction sequence? 1. BH, THF 2, H2O, NaOH HO HO HO OH HO Hd + enantiomer + enantiomer + enantiomer 11 III V V 11 TV с и
Match each reaction with its reagents. HO CI N 1 + enantiomer -OH 4 3 + enantiomer + enantiomer 6 5 OH w 8 } OH Hol Bre 10 Br + enantiomer to C 10 Br + enantiomer Br 11 Br 12 Reagents: B.) NBS, hv A.) PBr3 C.) - D.) NaOH E.) NaNH2 F.) Br2 H.) Cl2, H2O G.) HCI 1.) HBO J.) H2 (1 eq), Pt K.) Na, NH3 L.) H2SO4, H2O 0.) M.)1. Hg(OAC)2 2. NaBH4 N.)...
What is the major product for the following reaction 1. BH/THF 2. HO,H,O2, H2 i OH HO OH HO OH OH