Draw the structures of the aldehydes or ketones and alcohols formed when these acetals are treated with aqueous acid and hydrolyzed.
(a) Name and structure of the following an acetal is
The 2, 2-diethyl-1, 3-dioxolane molecule undergoes acid catalyzed hydrolysis gives 3-pentanone and 1, 2-ethanediol as a products.
The products are shown in the following reaction:
(b) Name and structure of the following an acetal is
The acid catalyzed hydrolysis of 1-(dimethoxymethyl)-2-methoxybenzene results in the formation of 2-methoxybenzaldehyde and methanol.
The products are shown in the following reaction:
(c) Name and structure of the following an acetal is
The acid catalyzed hydrolysis of 1, 1-dimethoxycyclohexane results in the formation of cyclohexanone and methanol.
The products are shown in the following reaction:
(d) Name and structure of the following an acetal is
The acid catalyzed hydrolysis of 2-methoxytetrahydro-2H-pyran results in the formation of 5-hydroxypentanal and methanol.
The products are shown in the following reaction:
Draw the structures of the aldehydes or ketones and alcohols formed when these acetals are treated...
Wittig reactions with α-chloroethers can be used for the synthesis of aldehydes and ketones. An enol ether is formed by treating cyclohexanone with the Wittig reagent derived from this chloroether. Draw the structures of the products formed when this enol ether is hydrolyzed with HI. Ignore alkene stereochemistry. When drawing products of Wittig reactions, draw only the alkene formed, do not include triphenylphosphine oxide. Draw Wittig reagents in ylide form. Draw one structure per sketcher. Add additional sketchers using the...
7. Acetals can serve as protecting groups for 1,2-diols, as well as for aldehydes and ketones. When the acetal is formed from acetone plus the diol, the acetal is called an acetonide. Show the acetonides formed from these diols with acetone under acid catalysis. You do NOT need to provide mechanisms. ОН HO OH OH ho b. H0 OM b. HO c. Ho
Draw the structures of the aldehydes or ketones below9-1.jpg
Draw both resonance structures of the enolate formed when each of the following ketones is treated with a strong base. Show mechanisms.
Draw structures of lactol/cyclic hemiacetal or cyclic acetal formed from intramolecular cyclization of the hydroxy aldehydes/ketones9-6.jpg
omenclature of aldehydes and ketones: name the structures
Name Structure Examples Alcohols Ethers Aldehydes Ketones Carboxylic Acids Ester
write three reaction in the synthesis of alcohols, aldehydes and ketones using the reducing agent LiAlH4
College Chem I CHE 132 Alcohols, Aldehydes, & Ketones Draw the structure of the product for each reaction. Name the reactant and the product. + Hz OH ciH 2 netng gelopentanol +HNi Ciy CHy c) CCyC нос 180 Ho e) CH5-CH-CH- PE CHS CAS u-Ca-aes CHS
Incorporate the protection and deprotection of ketones, aldehydes, and alcohols in syntheses. 6. The following reaction will not go as protection/deprotection that will improve the outcome of the synthesis planned. Devise a plan for NaSCH3 H3CS Br