5.15 Use a ligand group orbital approach to describe the bonding in [NH41. Draw schematic representations...
Draw the molecular orbital diagram for: (indicate the point group symmetry and draw with bonding and non bonding labeled, SALCS, and connecting lines) 1. SCl4 2. CO2
Draw the molecular orbital diagram for: (indicate the point group symmetry and draw with bonding and non bonding labeled, SALCS, and connecting lines) 1. PF5 2. SCl4
Draw the structure of 1,3-pentadiene. Use valence-bond and molecular orbital pictures to describe the bonding for the s–framework and p–orbitals, respectively.
Re Use molecular orbital theory to explain bonding in N N, and N, Part A Draw molecular orbital diagrams to the corresponding molecules or ons Drag the appropriate labels to their respective targets. Reset Help Group 2 Group 2 Group 2 Group? Group 2 Group 2 CO2 Group 2 Hypertrophy vs Hypot
Draw the d-orbital energy diagram for a square planar complex [M(L)4]2+. Draw a schematic representation (i.e. simple 2D picture) of the metal-ligand antibonding orbital that corresponds to the highest energy orbital of the splitting diagram. How is this square planar splitting diagram related to the d-orbital splitting diagram for a Jahn-Teller distorted octahedral complex?
Could you show how to do (d) step by step, please?
AO = Atomic orbital
MO = Molecular orbital
(L)GO= (Ligand) Group orbital
2. TaHs has a square pyramidal geometry and a Cev symmetry. (a) Assign x, y, z coordinates on the atoms: - Z axis on central Ta atom is the principal rotation axis (z axes on other atoms are colinear) - X, y axes on central Ta atom match Ta-H bonds (x, y axes on other atoms are...
4. Draw an MO diagram for CN- including: a. The irreducible representations describing each basis orbital. b. The relative energies of the basis orbitals. c. The relative energies of the product orbitals. d. The irreducible representations describing each product molecular orbital. e. The electron occupancy of each product molecular orbital.
Use the molecular orbital theory to describe the bonding in O2 + , O2, O2 - and O2 2- . Predict the bond order and relative bond lengths for these four species. Are they paramagnetic or diamagnetic?
Draw the molecular orbital diagram for SCl4. PLEASE indicate the point group symmetry and draw with bonding and non bonding labeled, SALCS, and connecting lines!
2. Use the group orbitals of CH3 and CH2 to create a Qualitative Molecular Orbital Theory diagram of the bonding in CH3NH2 (14 electrons) Draw a separate picture attempting to illustrate what the molecular orbital will look like A few points to help you in making this diagram: • Better overlap (as in head-on versus side-by-side) leads to greater stabilization of bonding orbital • If bonding interaction is highly stabilized, the anti-bonding interaction is even more destabilized • The 2p...