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Help multiple choice ASAP

What is the overall synthetic outcome (look at the
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14) is option (A), Hydreation proceeds through Markonikov's rule

15) is option (C). Since, alkynes have only one bond in addition to triple bond so, no geometrical isomerism possible incase of alkynes (where as alkenes have two bonds in addition to double bond).

16) is option is (D). Its electrophile H+ being attacked by elecron cloud (nucleophile) its a first step in both acid catalysed hydrationa and hydrobromination or any electrophilic addition to alkenes.

17) is option (A). the steric hinderence increases in give order and as a result nucleophilic attack will be difficult.

Hope this will explains your answers.

All the best

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