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In the electrolysis cell used for the industrial preparation of Cl2 from aqueous NaCl, a diaphragm...

In the electrolysis cell used for the industrial preparation of Cl2 from aqueous NaCl, a diaphragm is used to separate the products. Give an equation for the reaction that would occur in the absence of the diaphragm and describe the nature of the reaction.

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Answer #1

At Anode :

2Cl- ----> Cl2 + 2e-

At cathode :

2H+ + 2e- ----> H2

In the absence of diaphragm

H2 + Cl2 ---> 2HCl [ Normal synthesis typre reaction ]

However there is another reactant which reacts with Cl2

NaOH + Cl2 ---> NaClO3 + NaCl

It is a disproportination reaction where Cl undergos oxidation and reduction .

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