Homework Answers
(h) The treatment of methyl cyclohexene with mercuric acetate and water followed by reaction with NaBH4 will give tertiary alcohol via oxymercuration-demercuration reaction. It is Markovnikov's addition of water across a double bond.
(i) Palladium is poor catalyst for the hydrogenation of carbonyl groups. Hence it reduces nitro group only.
(j) KMnO4 dihydroxylation of alkenes is a syn cyclo addition, that will produce vicinal diols with cis stereochemistry.
NaBH4 CC Hg(OAC)2 H20, THE NaOH 1. Hg(O2CCF3)2, 'ProH 2. NaBH4, NaOH 1. BHz •THF 2....
NaBH4 CC Hg(OAC)2 H20, THE NaOH 1. Hg(O2CCF3)2, 'ProH 2. NaBH4, NaOH 1. BHz •THF 2. H2O2, HOⓇ R-OH + Nax — NaCN DMSO TSCI pyridine ОН MSCI pyridine NasMe DMSO cat. HA MeOH + g. Arrange in the Increasing acidity order HẠO ROH RC=CH HA NHA RH. cold KMnO4, HOor 1. Os04 2. NaHSO3 MICH3 1. mCPBA 2. H+, CH3OH, H2O 1. mCPBA 2. NaOCH3, H20 H2O / H+ Hg(OAC)2 H2O, THE NaBH4 NaOH 1. BH3 THF 2. HaO2...
Take Home Quiz_Verma_2217-Fall2019-Due- Nov. 7", 2019 Name: Page 1 of 2 NaBH4 S=C H20 metra Hg(OAC)2...
Take Home Quiz_Verma_2217-Fall2019-Due- Nov. 7", 2019 Name: Page 1 of 2 NaBH4 S=C H20 metra Hg(OAC)2 H2O, THE NaOH 1. Hg(O2CCF3)2, 'POH 2. NaBH4, NaOH 1. BHz - THE a 1.900 2. H2O2, HO R-OH + Nax- TSCI NaCN DMSO pyridine OH tot en MsCI pyridine NasMe DMSO cat. HA MeOH + g. Arrange in the Increasing acidity order H2O ROHRCECH H2 NH3 RH Take Home Quiz_Verma_2217-Fall2019-Due- Nov.7", 2019 Name Page 2 of 2 cold KMnO4, HO or 1. Os04...
H2O / H+ Hg(OAC)2 H2O, THF NaBH4 NaOH 1. BH3 THE 2. H2O2, HOⓇ
H2O / H+ Hg(OAC)2 H2O, THF NaBH4 NaOH 1. BH3 THE 2. H2O2, HOⓇ
Examples H30+ H3O+ ou won Hg(OAc)2 NaBH4 Hg(OAC)2 NaBH4
Examples H30+ H3O+ ou won Hg(OAc)2 NaBH4 Hg(OAC)2 NaBH4
provide the major product for the following reaction? 1) Hg(OAC)2, H2O/THI 2) NaBH4 HY
provide the major product for
the following reaction?
1) Hg(OAC)2, H2O/THI 2) NaBH4 HY
1. Name the starting compound, give one Major product H2O/H2SO 1. Hg(OAc), H2O Br/MeOH 2. NaBH4,...
1. Name the starting compound, give one Major product H2O/H2SO 1. Hg(OAc), H2O Br/MeOH 2. NaBH4, NaOH, H20 Cl2 CH2Cl2
1. Hg (OAc)2, H20 NaBH4 NH 1. MgBr, ether 2. POCl3 Pyridine 0o 3. H2 Pto2,...
1. Hg (OAc)2, H20 NaBH4 NH 1. MgBr, ether 2. POCl3 Pyridine 0o 3. H2 Pto2, ether ether, heat
2. What is the major product of the following reaction sequence? 1. H2, Pd/CaCO3, quinoline 2a....
2. What is the major product of the following reaction sequence? 1. H2, Pd/CaCO3, quinoline 2a. Hg(OAc)2, H2O 2b. NaBH4, NaOH A) OH B) OH * HO D) HO, E) 1
Draw all likely products for the following reactions. EI 1-Hg (OAc), HO, 2- NaBH4 [Fl 1-...
Draw all likely products for the following reactions.
EI 1-Hg (OAc), HO, 2- NaBH4 [Fl 1- BH 2- H202, NaOH H2 H2 C-C 1)-THF / Li 2)- H3O
Choose from the following list of reagents: RCO3H H2, Lindlar's cat. 1) Hg(OAC)2, EtOH 2) NaBH4...
Choose from the following list of reagents: RCO3H H2, Lindlar's cat. 1) Hg(OAC)2, EtOH 2) NaBH4 1) NaNH2 2) MEI Na, NH3 1) H2SO4 2) EtOH 1) NaNH2 2) Eti 1) NaOH 2) Mei 1) RCO3H 1) RCO3H 2) EtOH, [H2SO4] 2) MeOH, [H2SO4] 1) Br2, H2O 2) RCO3H 1) Br2, H20 2) Mei Enter the correct letter for each step of the reaction in the boxes below. (Reagents can be used more than once.) Step A: Step B: Step...
NaBH4 CC Hg(OAC)2 H20, THE NaOH 1. Hg(O2CCF3)2, 'ProH 2. NaBH4, NaOH 1. BHz •THF 2. H2O2, HOⓇ R-OH + Nax — NaCN DMSO TSCI pyridine ОН MSCI pyridine NasMe DMSO cat. HA MeOH + g. Arrange in the Increasing acidity order HẠO ROH RC=CH HA NHA RH. cold KMnO4, HOor 1. Os04 2. NaHSO3 MICH3 1. mCPBA 2. H+, CH3OH, H2O 1. mCPBA 2. NaOCH3, H20 H2O / H+ Hg(OAC)2 H2O, THE NaBH4 NaOH 1. BH3 THF 2. HaO2...
Take Home Quiz_Verma_2217-Fall2019-Due- Nov. 7", 2019 Name: Page 1 of 2 NaBH4 S=C H20 metra Hg(OAC)2 H2O, THE NaOH 1. Hg(O2CCF3)2, 'POH 2. NaBH4, NaOH 1. BHz - THE a 1.900 2. H2O2, HO R-OH + Nax- TSCI NaCN DMSO pyridine OH tot en MsCI pyridine NasMe DMSO cat. HA MeOH + g. Arrange in the Increasing acidity order H2O ROHRCECH H2 NH3 RH Take Home Quiz_Verma_2217-Fall2019-Due- Nov.7", 2019 Name Page 2 of 2 cold KMnO4, HO or 1. Os04...
H2O / H+ Hg(OAC)2 H2O, THF NaBH4 NaOH 1. BH3 THE 2. H2O2, HOⓇ
Examples H30+ H3O+ ou won Hg(OAc)2 NaBH4 Hg(OAC)2 NaBH4
provide the major product for
the following reaction?
1) Hg(OAC)2, H2O/THI 2) NaBH4 HY
1. Name the starting compound, give one Major product H2O/H2SO 1. Hg(OAc), H2O Br/MeOH 2. NaBH4, NaOH, H20 Cl2 CH2Cl2
1. Hg (OAc)2, H20 NaBH4 NH 1. MgBr, ether 2. POCl3 Pyridine 0o 3. H2 Pto2, ether ether, heat
2. What is the major product of the following reaction sequence? 1. H2, Pd/CaCO3, quinoline 2a. Hg(OAc)2, H2O 2b. NaBH4, NaOH A) OH B) OH * HO D) HO, E) 1
Draw all likely products for the following reactions.
EI 1-Hg (OAc), HO, 2- NaBH4 [Fl 1- BH 2- H202, NaOH H2 H2 C-C 1)-THF / Li 2)- H3O
Choose from the following list of reagents: RCO3H H2, Lindlar's cat. 1) Hg(OAC)2, EtOH 2) NaBH4 1) NaNH2 2) MEI Na, NH3 1) H2SO4 2) EtOH 1) NaNH2 2) Eti 1) NaOH 2) Mei 1) RCO3H 1) RCO3H 2) EtOH, [H2SO4] 2) MeOH, [H2SO4] 1) Br2, H2O 2) RCO3H 1) Br2, H20 2) Mei Enter the correct letter for each step of the reaction in the boxes below. (Reagents can be used more than once.) Step A: Step B: Step...
Most questions answered within 3 hours.
-
1. What is the meaning of the term communication style?
2. What are the benefits to...
asked 7 minutes ago -
9.) You are buying a car that cost $26,500. You make payments of
$412 each month...
asked 32 minutes ago -
. Suppose a discrete random variable has probability
distribution
P(x) = .2 if x = 0...
asked 1 hour ago -
Problem #1
The area between Z = 0 and Z = 2.50
The area between Z...
asked 48 minutes ago -
Under the influence of its drive force, a snowmobile is moving
at a constant velocity along...
asked 2 hours ago -
Why do organizations decline? What steps can top
management take to halt, decline, and restore organizational...
asked 2 hours ago -
What mechanisms Drive speciation??
(I.e. what was Dawins theory on the orgin of species, and how...
asked 3 hours ago -
The manager at a car assembly plant believes that the mean
assembly time for a car...
asked 4 hours ago -
Which of the following is true of electron capture?
A) It decreases the nuclide's mass number...
asked 6 hours ago -
Assuming an efficiency of 43.10%, calculate the actual yield of
magnesium nitrate formed from 114.9 g...
asked 6 hours ago -
The highly pathogenic bacterium Clostridium
perfringens causes gangrene, a disease that results in the
destruction of...
asked 8 hours ago -
In the context of situation analysis, which of the following is
a category for analysis in...
asked 8 hours ago