pedict the product and only provide the major product Br2, CCL 2 eq. (CH3),COK, DMSO DBN...
Section 2 Predict the Product/Intermediate for each Organic Reaction Provide only the major organic product(s) formed for each reaction below. (0.5 pt. each) For Stereoisomers: If the reaction is diastereoselective then you must provide the correct relative configuration for the diastereomer(s) formed as a result of the reaction. Br2, CCL 2 eq. (CH3),COK, DMSO DBN Na, Liquid NH Nal, Acetone 2) OH, H202 Draw intermediate 1.0 eq. HB Draw Intermediate HgSo., H2SO., H,0
provide the structure of the major product formed in the following
reaction
CHM2220 Name Provide the structure of the major product formed in HBr 13 NBS (1 eq) CH C, light DMSO ONa н,с 15. Nal acetone 16 CH,CH20Na CH,CH2OH 17 CH,SNa Нс. Ethanol (pk, CH,SH-10.5) 18. HBr (aq) Н-о 19. CH2OH Вr Methanol 20. CHа CHSCH2ONA* CH2CH2OH 21. HBr Peroxides 22. Br CH,ОН 23. Methanol
2) Provide the structure of the major organic product of the reaction below. -CH3 Br2, H2O 3) Draw the major organic product generated in the reaction below. Pay particular attention to regio- and stereochemical detail. H, H20 dilute aqueous acid 4) Draw the major organic product generated in the reaction below. Pay particular attention to regio- and stereochemical detail. CH3 1. Hg(OAc)2, H20 2. NaBH 5) Provide the structure of the major organic product of the reaction below. 1. BH3...
8. Provide the major organic product which results when PhCH2CH2CO2H is treated with 2 eq. butyllithium followed by H30+. 9. Provide the major organic product which results when (CH3)2CHCH2CH2COCI is treated with LIAIH[OC(CH3)313-
Is there only a major product or major and minor products?
Please provide the product(s).
CH3-0 1. LiAlH HNCHE 2 H,0*
(30 pt) Draw the structures of the MAJOR products for the
following reactions. Be sure to clearly show the REGIO- and
STEREOCHEMISTRY of each product.
H2SO4 X - H2O BH3 H2O2 THF H20, OH Br2 CH2OH excess HBO d) CH3-C=C-CH3 1 eq Cl2 e) CH3 -C=C-CH3 CH2Cl2 Na CH3CO2H 9) CH.-C=C-H, under CH3COH f) CH3-CEC-CH3 liquid NH3 -78 °C H202 g) CH3CH2-CEC-H R2BH THE H2O, OH NaNH2 CH3CH2Br H2SO4 h) CH3CH2-CEC-H my Chcn=c20-n, Nanets, Cheka na H2O HgSO4 heat 1...
1. Provide the missing reagent(s) and major product(s) for the following reactions. NaCN DMSO HO Br (CH3)3COK (CH3),COH OH HCro, Acetone 2. Provide a structure of each of the following. a. 4-ethyl-3-hexen-1-ol b. meta-ethylfluorobenzene C. R-3-methyl-3-ethoxyheptane 3. Rank the following: a. According to boiling point, 1 being the highest and 4 the lowest. он Л лон он F b. According to reactivity in an electrophilic aromatic substitution reaction, 1 being the most reactive and 4 the least. c. According to...
Starting with benzene what is the major product to the following reagents. 1. Br2/FeBr3, (CH3)2CCOCl/AlCl3 2. (CH3)2CCOCl/AlCl3, Br2/FeBr3 3. Br2/FeBr3, H2SO4, (CH3)2CCOCl/AlCl3, H2O Which major product of the three will give the most one product if reacted with HNO3/H2SO4?
ADraw the reactant required to produce each major product. Be sure to indicate the correct stereochemistry where appropriate. Нс CI Cl2, CH2CI, hv NH3 NH2 OCH3 KCO3 (a base) then CHaBr 1. Na (metal) 2. butyl bromide Осн Н.с. 1. Br2, hv, CHCl 2. methanolysis 1. mesyl chloride, pyridine NH2 HO 2. NH3 Он 1.TICI, py 2. H2O (hydrolysis) 1.TsCl, K2CO3 2. Nal (acetone) Page 5 of 8
Provide the major product for the following reactions:
b. NaH, THF CH Br 1.1 eq LDA, THF D O NaOD 1. LDA (1.1 eq) 2. CH2CH 3. LDA (1.1 eq, -78 °C) 4. CH 1 equiv. Br2 NaOH, H2O