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D. Questions: Common Ion Effect on a Chemical System Common Ion Effect on a Chemical System - Fe3+(aq) + SCN (aq) [Fe(SCN)]2+
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Answer #1

Answer 1:

  • This is based on the Le chatelier's principle.
  • The color of Fe3+ ions is yellow while that of SCN- is colorless.
  • The colour of the iron thiocynate complex is deep blood red.
  • Therefore, here the evidence of the shift in equilibrium is provided by a color change.
  • If the equilibrium shifts to the right a deeper red color will be seen while if it shifts to the left, a lighter red color will be observed.

Answer b:

  • ​​​​​​Iron(3)Chloride will give Fe3+ ions.
  • Therefore, the additional Fe3+ will disturb the equilibrium as now it is in a higher concentration than it should be at equilibrium.
  • Therefore, the equilibrium shifts to the right to reduce the concentration of iron ions and increase the concentration of the complex.

Answer c:

  • As explained above, the stress created on the system is due to the Fe3+ ions.

Thank You!

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