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Identify the product(s) of the following reaction, rationalizing their formation by drawing a detailed mechanism. Be...
9. a) Write the detailed Sn1 mechanism for the reaction of (S)-3-bromo-3-methylhexane with H20, showing curved...
9. a) Write the detailed Sn1 mechanism for the reaction of (S)-3-bromo-3-methylhexane with H20, showing curved arrows, relevant lone pairs, formal charges, stereochemistry for each step. Include any transition states and/or intermediates, and name the product(s). b) A racemic mixture results from a reaction of the chiral alkylbromide starting material below, and acetate. at hope ܬ Write the complete mechanism for the synthesis. Show the curly arrows, relevant lone pairs and all formal charges for each step. Include any transition...
7. Predict the product(s) of each of the following reactions include stereochemistry where important and indicate...
7. Predict the product(s) of each of the following reactions include stereochemistry where important and indicate the mechanism (S, S,2, El, E2). 80°C a 2-chloro-2-methylbutane NaOH Н.о b. (R)-2-chloropentane Nac c-H DMSO с1 (снс. Cн, CH,ОН d. trans-1-chloro-3-methylcyclohexane+ NaOC(CH) e. 2-chloro-3-phenylbutane Н.о f. trans-1-bromo-3-methyleyclopentane Nal acetone NaOCH THон g 2-chloro-2-methylbutane EIOH h R-3-bromo-2-methylpentane . trans-1-bromo-2-isopropyleyclohexane CHCOK NaSH Н,о j. 1-bromopropaе NaOCH снон CH коссH). I-bromobutane m. cis-1-chloro-3-methyleyclobutane Nal DMSO сHсH,он n. (R)-2-iodo-2-phenylethane NaOH o. 1-iodobutane p. 2-bromo-3-methylbutane KOC(CH). но (S)-3-chlorocyclopentene...
Draw a detailed mechanism for the following transformation 1. Br. Br HBr HO 2. What are the major product (s) formed in...
Draw a detailed mechanism for the following transformation 1. Br. Br HBr HO 2. What are the major product (s) formed in the following substitution reaction? Draw as Fisher projections CH;CH2ОH CH-CHз Нас— вr CH2CH2CH3 Draw the mechanism for the following reaction. 3. HO Br Draw the major organic product(s) produced in the following reaction as Fischer projection. 4. CHз ОСHЗ Н NaN3 Н. -CH3 Н- Br DMSO CH3 Draw the mechanism for the following reaction to demonstrate how the...
Que. 14) What is (are) the major organic product(s) obtained from the following reaction? НО HO...
Que. 14) What is (are) the major organic product(s) obtained from the following reaction? НО HO НО НО СН,ОН CH OH CH2OCH Сньон CH3OH OCH H ОН OH ОН ОН ОН OCH он ОН OH a. only 1 b. only 2 c. only 2 and 3 d. 1, 2 and 3 Que. 15) Which of the following represents a furanose? он СН,ОН HO HO CHO HOH Hнон но, HO, ён,он ОН ОН Hно a. only 1 b. only 2 c....
Draw the structure(s) of the major organic product(s) obtained after workup of the following reaction. NaOH...
Draw the structure(s) of the major organic product(s) obtained after workup of the following reaction. NaOH O-S CH3 excess NH2 workup . You do not have to consider stereochemistry. If no reaction occurs, draw the organic starting material. Draw structure(s) of product(s) after workup to neutralize acid. Include counter-ions, e.g., Nat, I, in your submission, but draw them in their own separate sketcher. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner....
Draw the major organic product(s) of the following reaction. CH3 HỌC-C CI CH3 + NaOH 2rea...
Draw the major organic product(s) of the following reaction. CH3 HỌC-C CI CH3 + NaOH 2rea • You do not have to consider stereochemistry. • If no reaction occurs, draw the organic starting material. • When Sn1 & El pathways compete, show both the substitution and the elimination products. Separate multiple products using the + sign from the drop-down menu. Do not include counter-ions, e.g., Na", 1", in your answer. Draw the major organic product(s) of the following reaction. HEC-Br...
9. a) Write the detailed Sn1 mechanism for the reaction of (S)-3-bromo-3-methylhexane with H20, showing curved arrows, relevant lone pairs, formal charges, stereochemistry for each step. Include any transition states and/or intermediates, and name the product(s). b) A racemic mixture results from a reaction of the chiral alkylbromide starting material below, and acetate. at hope ܬ Write the complete mechanism for the synthesis. Show the curly arrows, relevant lone pairs and all formal charges for each step. Include any transition...
7. Predict the product(s) of each of the following reactions include stereochemistry where important and indicate the mechanism (S, S,2, El, E2). 80°C a 2-chloro-2-methylbutane NaOH Н.о b. (R)-2-chloropentane Nac c-H DMSO с1 (снс. Cн, CH,ОН d. trans-1-chloro-3-methylcyclohexane+ NaOC(CH) e. 2-chloro-3-phenylbutane Н.о f. trans-1-bromo-3-methyleyclopentane Nal acetone NaOCH THон g 2-chloro-2-methylbutane EIOH h R-3-bromo-2-methylpentane . trans-1-bromo-2-isopropyleyclohexane CHCOK NaSH Н,о j. 1-bromopropaе NaOCH снон CH коссH). I-bromobutane m. cis-1-chloro-3-methyleyclobutane Nal DMSO сHсH,он n. (R)-2-iodo-2-phenylethane NaOH o. 1-iodobutane p. 2-bromo-3-methylbutane KOC(CH). но (S)-3-chlorocyclopentene...
Draw a detailed mechanism for the following transformation 1. Br. Br HBr HO 2. What are the major product (s) formed in the following substitution reaction? Draw as Fisher projections CH;CH2ОH CH-CHз Нас— вr CH2CH2CH3 Draw the mechanism for the following reaction. 3. HO Br Draw the major organic product(s) produced in the following reaction as Fischer projection. 4. CHз ОСHЗ Н NaN3 Н. -CH3 Н- Br DMSO CH3 Draw the mechanism for the following reaction to demonstrate how the...
Que. 14) What is (are) the major organic product(s) obtained from the following reaction? НО HO НО НО СН,ОН CH OH CH2OCH Сньон CH3OH OCH H ОН OH ОН ОН ОН OCH он ОН OH a. only 1 b. only 2 c. only 2 and 3 d. 1, 2 and 3 Que. 15) Which of the following represents a furanose? он СН,ОН HO HO CHO HOH Hнон но, HO, ён,он ОН ОН Hно a. only 1 b. only 2 c....
Draw the structure(s) of the major organic product(s) obtained after workup of the following reaction. NaOH O-S CH3 excess NH2 workup . You do not have to consider stereochemistry. If no reaction occurs, draw the organic starting material. Draw structure(s) of product(s) after workup to neutralize acid. Include counter-ions, e.g., Nat, I, in your submission, but draw them in their own separate sketcher. Draw one structure per sketcher. Add additional sketchers using the drop-down menu in the bottom right corner....
Draw the major organic product(s) of the following reaction. CH3 HỌC-C CI CH3 + NaOH 2rea • You do not have to consider stereochemistry. • If no reaction occurs, draw the organic starting material. • When Sn1 & El pathways compete, show both the substitution and the elimination products. Separate multiple products using the + sign from the drop-down menu. Do not include counter-ions, e.g., Na", 1", in your answer. Draw the major organic product(s) of the following reaction. HEC-Br...
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