1. (6 pts.) Consider the coordination compound Rh(C)(CO)(PPhs)2: Draw the two possible isomers for this square...
2. (3 points) In lab, you will form complexes using different ligands. Use your lab manual to identify and draw the structural formula (lewis formula) for the following: a. A charged monodentate ligand (answer cannot be a halide ion) b. A polydentate ligand c. The CO ligand, not used in the laboratory. Is it likely CO can form a coordinate covalent bond from more than one atom? Explain. NC CN Ni Geometry of Coordination Compounds A compounds geometry (i.e., how...
Part C: Structural Isomers - Coordination Sphere Isomers [Co(H2O),Br]CI and (Co(H2O),CIJBr examples of coordination sphere isomers. compounds with the same chemical formula, but with one or more different bonds. In this example, notice the Cl and Br' are either a ligand or a counter ion. Assuming tetrahedral geometry for these cobalt(II) complexes, build a model for only the first (Co(H2O),Br]CI) complex ion. Use a silver (SN-4, tetrahedral) atom for cobalt, use a green terminal atom for Cl, use a yellow...
1. Consider the following 4-coordinate complexes. For each of these: a. Do you expect the complex to be tetrahedral or square planar? Why? b. Draw an electron-orbital occupancy diagram for the d orbitals. c. If the complex is tetrahedral, calculate an LFSE in units of 4. Note that, for tetrahedral complexes, e orbitals are -3/54 relative to the average d-orbital energy, and t, orbitals are +2/54 relative to the average d-orbital energy. Ni(CO). [Rh(PPh.) (CO), [Rec] [PdCl.Bry] 2. Which of...
Organometallic question: 1) For our purposes, the interesting ligand illustrated below is inflexible, occupying a square plane around the Rh(I) metal center F2 (a) Draw the oxidative addition product of a generic species, X-Y, to complex A. Please assume that both X and Y are bound to rhodium. What is the geometry around rhodium (e.g., trigonal, trigonal bipyramidal, tetrahedral...)? c) Based on you answer in part (a), would you expect Mel to oxidatively add to A? Please succinctly explain your...
1. Name the following molecules: a) [PtBr(NH3)3]I3 b) [Ir(CO)2(OH)2]Cl c) K2[FeCl4(NO3)2] d) [((CH3)3N)3PdBr]Cl e) CoCl3H(dabco)2 2. Draw and give the point group for all the geometrical isomers of a molecule with the general formula: a) MA2B2 (square planar and tetrahedral) b) MA2B (“T”‐shaped and trigonal planar) c) MAB4 (trigonal bipyramidal and square pyramidal) d) MA2B3 (trigonal bipyramidal and square pyramidal) 4. Draw four distinct geometrical isomers of a metal complex of the type M(A‐CH2‐CH2‐B)2. Which of these is chiral? Give...
5-12 Kinetics of Nucleophilie Siebstitution ( 4.) Consider the reaction below (6 pts) + H2O → HCI + Intermediate a. Which isomer of the reactant, 3-chloro-3-methylhexane, is shown? Ror S b. Draw the reaction intermediate. c. Circle the geometry of the intermediate: Planar Trigonal planar Tetrahedral Product d. Draw the organic product of the Sul reaction of 3-chloro-3- methylhexane e. Is the organic product optically active? Y or N f. If you answered yes in "e" is one isomer produced...
5. The [NI(CN)412- ion has a square-planer geometry, whereas the INca diagrams (with d-orbital labels) for these twe complexes and determine if the compound is paramognetic or diamognet ion is tetrahedral. Drow the crystal field splitting 6. The absorption maximum for the complex ion (Co( Hale ccurs at 410 m. Predict the coler of this complex.Explain your reasoning. the Lewis structure of each and state whether the following are monodentate or bide ntate ligands a. c2042 (oxalate ion, ox) b,sar...
4. Give chemical names for the following coordination complexes. a) [Cu(NH3)4]2+ b) [Pt(NH3). Cl]* c) [Mn(CN):)". d) (Co(en)2(PPha)]PO... e) [Ni(bipy)](NO3)2. 5. Give chemical formulas for the following coordination complexes. a) Triammineaquadichlorocobalt(III) chloride. b) Potassium diaquabis(oxalate)manganate(III). c) Tris(acetylacetonato Jiron(III). d) Tri--carbonylbis(tricarbonyliron(O)). e) Li-oxo-bis(pentaamminechromium(III)). 5. Draw a d-orbital energy-level diagram, and predict the number of unpaired electrons. a) [Fe(CN).] b) [Fe(H20):] c) (CoCil (tetrahedral) 6. Of the two complexes (a) (CoFs] and (b) (Coſen)] + one appears yellow and the other appears...
consider the molecule with two chiral centers. draw all remaining possible stereoisomers using solid and dashed wedges label each chiral center as R or S 5. Consider the molecule 1-chloro-3-tertbutylcyclohexane with two chiral centers: a. Using COMPOUND A (below) as a starting molecule, draw all remaining possible stereoisomers using solid and dashed wedges (no chairs). Compound B Compound A Compound C Compound D 6. On BOTH COMPOUND A and COMPOUND D (above), clearly label each chiral center as either R...
2. (4 pts) Draw the structures of the two possible products- 3-chloro-1-butene and 1-chloro-2- butene. What type of isomers are these two compounds?