In the preparation of methyl benzoate from benzoic acid, methanol, concentrated H2SO4, and heat, why is methanol used as the excess reagent? Thank you
In the preparation of methyl benzoate from benzoic acid, methanol, concentrated H2SO4, and heat, why is...
5. The equilibrium constant (K) for the formation of methyl benzoate from methanol and benzoic acid at 25°C is 3.77. Use the equation for the equilibrium constant to calculate the theoretical yield of methyl benzoate for the following conditions. (6 marks) a) With equal initial amounts of the reactants (1 mole of each reactant) b) With a threefold (x 3) excess of methanol (1 mole of benzoic acid and 3 moles of methanol) 6. Suggest a chemical reaction (include structures...
using the picture of the synthesis of methyl benzoate as a reference, name and draw the structure of the product of the reaction involving propionic acid and isopropyl alcohol. Is the product a liquid or a solid? H2SO4 Y OH + H2C-OH 0 + H2O benzoic acid methanol benzoic acid methanol methyl benzoate methyl benzoate + H₂O OH propionic acid isopropyl alcohol
24. What would have been the effect of omitting the sulfuric acid from methyl benzoate preparation by reacting benzoic acid with methanol? 25. Criticize the following techniques: (a) Heating a mixture that contains n-hexane using an open flame. (b) For a reaction, heating a mixture that contains a large amount of toluene using hot water bath. (c) Running s reaction with tert-butyl alcohol that is cooled to 0°C in an ice bath. (d) A 100-ml graduated cylinder is used to...
A reaction was performed in which 3.022 g of benzoic acid was reacted with excess methanol to make 1.1 g of methyl benzoate. Calculate the theoretical yield and percent yield for this reaction.
What would be the product(s) of this reaction if toluene replaced methyl benzoate? If only concentrated nitric acid were used in this reaction, will that increase the % yield of the reaction? And why? What is the function of concentrated sulfuric acid? Please use a reaction equation to show your answer. These are questions from my organic chemistry lab regarding the nitration of methyl benzoate to form m-nitrobenzoate through electrophilic aromatic substitution rxn.
ethyl Propanoate methyl benzoate 3. Write a balanced chemical equation for the preparation of (a) octyl acetate and (b) methyl salievlete from essary starting materials in this experiment. Note: Salicylic acid is 2-hydroxybenzoic acid. 4. What is the purpose of concentrated sulfuric acid in ester synthesis? What precautions are necessary when working with concentrated sulfuric acid? Laboratory Experiments for General, Organic and Biological Chemistry
QUESTIONS 1. Why does methyl benzoate dissolve in concentrated sulfuric acid? 2. What is the EQUATION for the reaction between concentrated nitric and sulfuric acids? 3. What is the DOT STRUCTURE for NO,"? 4. What is the MECHANISM for the formation of m-nitromethylbenzoate? 5. WHY does reaction occur at the META position only? 6. What is the PURITY of the m-nitromethylbenzoate recovered based on its melting range?
In the nitration of methyl benzoate, an excess of nitric acid is used. Explain why the reaction stops at the single nitration and does not go on further to the double nitration.
What can cause a low percent yield? In lab we did fischer esterification using benzoic acid and methanol to yield methyl benzoate. 3.05 grams of benzoic acid were used and 1.10 grams of methyl benzoate were produced. We also washed the product multiple times with water, 10% sodium bicarbonate solution, then saturated sodium chloride solution. Could the washing cause a low percent yield? If so, can you explain why?
Why is the partition coefficient different for benzoic acid and sodium benzoate? Explain chemical reasons why the two values differ. Especially note the type of intermolecular forces that exist in the solute and the two solvents. Partition Coefficient of Benzoic Acid Benzoic acid in water layer and organic layer (dichloromethane) as organic layer. 3.1 Partition Coefficient of Sodium benzoate Benzoic acid in aqueous layer (water and sodium bicarbonate) and dichloromethane as organic layer. 0.12