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Consider a given reaction , C2H2 (g) + 5 /2 O 2 (g) 2 CO 2(g) + H2O (g )
The standard enthalpy change of reaction is given as , r H 0 = H 0f ( products ) - H 0f ( reactants )
H 0f (products) =2 H 0f CO 2 (g) + H 0f H2O (g)
H 0f (products) = 2 (- 393.5 kJ mol -1 ) + ( - 241.8 kJ mol -1 )
H 0f (products) = - 1028.8 kJ mol -1
H 0f (reactants) = H 0f C2H2 (g) + 5/ 2 H 0f O 2 (g)
H 0f (reactants) = H 0f C2H2 (g) + 5/ 2 ( 0 ) kJ mol -1
i e H 0f (reactants) = H 0f C2H2 (g)
We have , r H 0 = - 1255.8 kJ mol -1 & r H 0 = H 0f ( products ) - H 0f ( reactants )
- 1255.8 kJ mol -1 =- 1028.8 kJ mol -1 - H 0f C2H2 (g)
1255.8 kJ mol -1 = 1028.8 kJ mol -1 + H 0f C2H2 (g)
H 0f C2H2 (g) = 1255.8 kJ mol -1 - 1028.8 kJ mol -1
H 0f C2H2 (g) = + 227.0 k J mol -1
ANSWER : H 0f C2H2 (g) = + 227.0 k J mol -1
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