Ethylene oxide is the starting material for the synthesis of 1, 4-dioxane. Write a detailed mechanism...
LILIT OH O Но Ethylene oxide is the starting material for the synthesis of 1,4-dioxane. Write a detailed mechanism for this synthesis (shown above). Then draw curved arrows that depict electron reorganization for Step 1 of the mechanism shown below. Unless specified otherwise, do not count proton transfers when counting steps. The starting materials of this step are provided. Arrow-pushing Instructions in + XT H₂C- CH₂
Write a detailed mechanism for the reaction shown above which proceeds in six steps including proton transfer steps. Then draw curved arrows that depict electron reorganization for the mechanism step below.
HO OH ОН Ethylene oxide is the starting material for the synthesis of 1,4-dioxepane. Draw curved arrows to show the movement of electrons in this step of the reaction mechanism. Arrow-pushing Instructions :o: Hö: H-OH :0:
H3C Нас H3C CO2H Br 1. NaOH, H20 2 HJo Write a detailed mechanism for the Favorski rearrangement (shown above) which proceeds in two steps followed by a proton transfer. Then draw curved arrows that depict electron reorganization for the mechanism step below Arrow-pushing Instructions IIn OOH H3C H3C Br. :O-H
Write a detailed mechanism for the reaction of dimethylamine in water with acetic anhydride to create N,N-dimethylacetamide which proceeds in 3 steps including proton transfer steps. Then draw curved arrows that depict electron reorganization for the mechanism step below. Arrow-pushing Instructions nno XT :0: :0 H CH3 :N-Me 1 нс N-Me Me Me
Propose a detailed step-by-step mechanism for the reaction shown below. Clearly show movement of electrons using curved arrows and do not combine steps unless you are certain they occur simultaneously. 4. (4 pts) Propose a detailed step-by-step mechanism for the reaction shown below. Clearly show the movement of electrons using curved arrows. Do not combine steps unless your are certain they occur simultaneously (2 equiv.) 2. H3O+
Write a detailed mechanism for the reaction above, then draw curved arrows to detect electron reorganization for the step below. To make a bond to a specific carbon of a double bond, use the "hit box" nearest that carbon.
extra credit orgo chem NaBH MOH 1.Write two starting materials (five or fewer C's) that react to form the target molecule starting from any carbonyl compound and any organometallic reagent. OH Part IV. Mechanistic Puzzlers (16 pts) 10. Reduction of cyclohexanone using lithium aluminum hydride gives a deuterated alcohol when D.O is used instead of H.O in the workup step. Account for this outcome with a mechanism, showing curved arrows, the key intermediate, and lone pairs and charges. (6 pts)...
9. a) Write the detailed Sn1 mechanism for the reaction of (S)-3-bromo-3-methylhexane with H20, showing curved arrows, relevant lone pairs, formal charges, stereochemistry for each step. Include any transition states and/or intermediates, and name the product(s). b) A racemic mixture results from a reaction of the chiral alkylbromide starting material below, and acetate. at hope ܬ Write the complete mechanism for the synthesis. Show the curly arrows, relevant lone pairs and all formal charges for each step. Include any transition...
4-Suggest a synthesis of the target molecule from the indicated starting material. More than one step will be required. For each step of your reaction sequence, show reagents used and product(s) formed. No curved arrows are required.(6 Marks)