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Problem 15: What is the mechanism of the following reaction? Horii Problem 16: Clearly draw the...
Draw the products for the following reactions. Clearly indicate stereochemistry where important. 6. Draw the products...
Draw the products for the following reactions. Clearly indicate
stereochemistry where important.
6. Draw the products for the following reactions. Clearly indicate the stereochemistry where important. 12 pts Br- 1.0, 2. Zn, HO CH,OH KMnO4 1. BH3 2 NaOH, H,0 1. Os0 2. NaHSO3 CHCl,. NaOH Br2 H2. Pd 1. Hg(OAc, HO 2. NaBH
ChemActivity 10: Oxidation and Reduction 149 7. Show a synthesis of each of the following target...
ChemActivity 10: Oxidation and Reduction 149 7. Show a synthesis of each of the following target molecules from methylenecyclohexane. (Some syntheses may be only one step.) methylenecyclohexane (starting material) OH -CC-CH₂ OH OH OH _LOH OCH OH- 8 Draw the product that results when each set of reagents is mixed with methyeyclohexene 1) BHS THE HBr peroxides 2) HOOH NAOH HCI 1) Hg(OAc), THF, H2O 2) NaBH, NaOH Bry Pd 0°, dark, no peroxides Pd 1) MCPBA 2) H SO./...
Predict the major organic product or products of each of the following reactions: Identify the mechanism...
Predict the major organic product
or products of each of the following reactions:
Identify the mechanism
taking place in each of the reactions and please provide
explanation.
H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
Draw a structural formula for the major product of the reaction shown. CH3CH2 S=CHCH2 The CH3CH2...
Draw a structural formula for the major product of the reaction shown. CH3CH2 S=CHCH2 The CH3CH2 Draw a structural formula for the major product of the reaction shown. CH3 CH3CHCH=CH2 Draw a structural formula for the major product of the reaction shown. Cl2 CH3CH2CH2CH=CH2 - H2O Draw structural formulas for all alkenes that could be used to prepare the alcohol shown below by oxymercuration. H3COH , 1. Hg(OAc)2, H2O 2. NaBH4 Draw the structure of the major organic product of...
can someone please answer this? thank you! For each reaction shown below, identify the primary product....
can
someone please answer this? thank you!
For each reaction shown below, identify the primary product. B regiochemistry and stereochemistry if applicable. Br2, H2O KMnO4, NaOH cold 1. Hg(OAc)2, H2O 2. NABH4 1. O3 2. Zn/ACOH 1. BH3 2. H-О, NaOH Cl2 Write the mechanism of the first reaction, the bromohydrin r
Provide the major product(s) for the following reactions: Show Stereochemistry when necessary HBr Br2 CH2Cl2 HBr...
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
Question 13 24 pts Match each reaction with its reagents. HO CI N + enantiomer A.)...
Question 13 24 pts Match each reaction with its reagents. HO CI N + enantiomer A.) PBr3 B.) NBS, hv C.) D.) NaOH E.) NaNH2 F.) Br2 G.) HCI H.) Cl2, H2O 1.) HBO J.) H2 (1 eq), Pt K.) Na, NH3 L.) H2SO4, H2O M.)1. Hg(OAC)2 2. NaBH4 0.) N.) 1. mCPBA 2. H+, H2O P.) 1. BH3 2. H2O2, NaOH
2. What is the major product of the following reaction sequence? 1. H2, Pd/CaCO3, quinoline 2a....
2. What is the major product of the following reaction sequence? 1. H2, Pd/CaCO3, quinoline 2a. Hg(OAc)2, H2O 2b. NaBH4, NaOH A) OH B) OH * HO D) HO, E) 1
match the right reagent 3 OH + enantiomer + enantiomer 5 CO A.) PBrs B.) NBS,...
match the right reagent
3 OH + enantiomer + enantiomer 5 CO A.) PBrs B.) NBS, hv C.) D.) NaOH E.) NaNH2 F.) Br2 G.) HCI H.) Cl2, H2O 1.) HBO J.) H2 (1 eq), Pt K.) Na, NH3 L.) H2SO4, H20 M.)1. Hg(OAC)2 0.) N.) 1. mCPBA 2. H+, H2O 2. NaBH4 P.) 1. BH3 2. H2O2, NaOH 3 OH + enantiomer + enantiomer 6 CO A.) PBrs B.) NBS, hv C.) D.) NaOH E.) NaNH2 F.) Br2 G.)...
For each of the following short reaction schemes, draw the structures of the compounds that would...
For each of the following short reaction schemes, draw the structures of the compounds that would be formed at each spot in the scheme where there is a letter Scheme 1 1. NaBH4 SOCI2 А B H 2. H20 Scheme 2 tosyl chloride H3C-0 Na он с D pyridine H3C-OH Scheme 3 1. H20, Hg(OAC)2 PCC E F 2. NaBH4 CH2Cl2 Scheme 4 Br S NaOH G H + Br I H2N NH2 Scheme 5 1. MCPBA Na2Cr207 J K...
Draw the products for the following reactions. Clearly indicate
stereochemistry where important.
6. Draw the products for the following reactions. Clearly indicate the stereochemistry where important. 12 pts Br- 1.0, 2. Zn, HO CH,OH KMnO4 1. BH3 2 NaOH, H,0 1. Os0 2. NaHSO3 CHCl,. NaOH Br2 H2. Pd 1. Hg(OAc, HO 2. NaBH
ChemActivity 10: Oxidation and Reduction 149 7. Show a synthesis of each of the following target molecules from methylenecyclohexane. (Some syntheses may be only one step.) methylenecyclohexane (starting material) OH -CC-CH₂ OH OH OH _LOH OCH OH- 8 Draw the product that results when each set of reagents is mixed with methyeyclohexene 1) BHS THE HBr peroxides 2) HOOH NAOH HCI 1) Hg(OAc), THF, H2O 2) NaBH, NaOH Bry Pd 0°, dark, no peroxides Pd 1) MCPBA 2) H SO./...
Predict the major organic product
or products of each of the following reactions:
Identify the mechanism
taking place in each of the reactions and please provide
explanation.
H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
Draw a structural formula for the major product of the reaction shown. CH3CH2 S=CHCH2 The CH3CH2 Draw a structural formula for the major product of the reaction shown. CH3 CH3CHCH=CH2 Draw a structural formula for the major product of the reaction shown. Cl2 CH3CH2CH2CH=CH2 - H2O Draw structural formulas for all alkenes that could be used to prepare the alcohol shown below by oxymercuration. H3COH , 1. Hg(OAc)2, H2O 2. NaBH4 Draw the structure of the major organic product of...
can
someone please answer this? thank you!
For each reaction shown below, identify the primary product. B regiochemistry and stereochemistry if applicable. Br2, H2O KMnO4, NaOH cold 1. Hg(OAc)2, H2O 2. NABH4 1. O3 2. Zn/ACOH 1. BH3 2. H-О, NaOH Cl2 Write the mechanism of the first reaction, the bromohydrin r
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C
Question 13 24 pts Match each reaction with its reagents. HO CI N + enantiomer A.) PBr3 B.) NBS, hv C.) D.) NaOH E.) NaNH2 F.) Br2 G.) HCI H.) Cl2, H2O 1.) HBO J.) H2 (1 eq), Pt K.) Na, NH3 L.) H2SO4, H2O M.)1. Hg(OAC)2 2. NaBH4 0.) N.) 1. mCPBA 2. H+, H2O P.) 1. BH3 2. H2O2, NaOH
2. What is the major product of the following reaction sequence? 1. H2, Pd/CaCO3, quinoline 2a. Hg(OAc)2, H2O 2b. NaBH4, NaOH A) OH B) OH * HO D) HO, E) 1
match the right reagent
3 OH + enantiomer + enantiomer 5 CO A.) PBrs B.) NBS, hv C.) D.) NaOH E.) NaNH2 F.) Br2 G.) HCI H.) Cl2, H2O 1.) HBO J.) H2 (1 eq), Pt K.) Na, NH3 L.) H2SO4, H20 M.)1. Hg(OAC)2 0.) N.) 1. mCPBA 2. H+, H2O 2. NaBH4 P.) 1. BH3 2. H2O2, NaOH 3 OH + enantiomer + enantiomer 6 CO A.) PBrs B.) NBS, hv C.) D.) NaOH E.) NaNH2 F.) Br2 G.)...
For each of the following short reaction schemes, draw the structures of the compounds that would be formed at each spot in the scheme where there is a letter Scheme 1 1. NaBH4 SOCI2 А B H 2. H20 Scheme 2 tosyl chloride H3C-0 Na он с D pyridine H3C-OH Scheme 3 1. H20, Hg(OAC)2 PCC E F 2. NaBH4 CH2Cl2 Scheme 4 Br S NaOH G H + Br I H2N NH2 Scheme 5 1. MCPBA Na2Cr207 J K...
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