7) At 1500°C the equilibrium constant for the reaction CO(g) + 2H2(g) → 키.4x10-7. Calculate AG)for...
A) Use tabulated electrode potentials to calculate ΔG∘ for the reaction. 2K(s)+2H2O(l)→H2(g)+2OH−(aq)+2K+(aq) B) (Refer to the following standard reduction half-cell potentials at 25∘C: VO2+(aq)+Ni2+(aq)2H+(aq)++2e−e−→ →Ni(s)VO2+(aq) +H2O(l)E∘=−0.23V E∘=0.99V) An electrochemical cell is based on these two half-reactions: Oxidation:Reduction:Ni(s)VO2+(aq,0.024M)+2H+(aq,1.4M)+e−→→Ni2+(aq,1.8M)+2e−VO2+(aq,1.8M)+H2O(l) Calculate the cell potential under these nonstandard concentrations. C) Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V ) Half-reaction E∘ (V ) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) − 0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) − 0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) − 0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) − 0.76...
What is the standard emf of a galvanic cell made of a Co electrode in a 1.0 M Co(NO32 solution and a Al electrode in a 1.0 M AI(NO3)3 solution at 25°C? 0 cell Standard Reduction Potentials at 25°C Half-Reaction E(V +2.87 +2.07 +1.82 O,(g) 2H (aq)2e0(g)+HO Co3+(aq) + e-_? Co2+(aq) H,02(aq) + 2H"(aq) + 2e-_ 2H20 Cu2+(aq) + 2e-? Cu(s) AgCIs) + Ag(s) + CI(a) S02-(aq) + 4H'(aq) + 2e S02(g) + 2H20 Cu2+(aq) + e-_ Cu+(aq) Sn (aq)...
1.) Given the following notation for an electrochemical cell Pt(s) | H2(g) | H+(aq) || Ag+(aq) | Ag(s), what is the balanced overall (net) cell reaction? A. H2(g) + 2Ag(s) ® H+(aq) + 2Ag+(aq B. H2(g) + 2Ag+(aq) ® 2H+(aq) + 2Ag(s) C. H2(g) + Ag+(aq) ® H+(aq) + Ag(s D. 2H+(aq) + 2Ag(s) ® H2(g) + 2Ag+(aq) E. 2H+(aq) + 2Ag+(aq) ® H2(g) + 2Ag(s) 2.) Calculate E°cell for the following (nonspontaneous) reaction: Cd(s) + 2Fe3+(aq) ® 2Fe2+(aq) + Cd2+(aq) → A. -0.37...
Separate galvanic cells are made from the following half-cells: cell 1: H+(aq)/H2(g) and Pb2+(aq)/Pb(s) cell 2: Fe2+(aq)/Fe(s) and Zn2+(aq)/Zn(s) Which of the following is correct for the working cells? Standard reduction potentials, 298 K, Aqueous Solution (pH = 0): Cl2(g) + 2e --> 2C1-(aq); E° = +1.36 V Fe3+(aq) + e --> Fe2+(aq); E° = +0.77 V Cu2+(aq) + 2e --> Cu(s); E° = +0.34 V 2H+(aq) + 2e --> H2(g); E° = 0.00 V Pb2+(aq) + 2e --> Pb(s);...
Given which of the following sets of thermodynamic parameters is a reaction spontaneous only at higher temperatures? A) ΔH < 0 and ΔS < 0 B) ΔH < 0 and ΔS > 0 C) ΔH > 0 and ΔS > 0 D) ΔH > 0 and ΔS < 0 ---------------------------------------------------------------------------------------------------------------------------- A galvanic cell is constructed using a zinc electrode immersed in a 1.0 M Zn2+ solution and a silver electrode immersed in a 1.0 M Ag+ solution. What is the...
Calculate the equilibrium constant for each of the reactions at 25 ∘C. Standard Electrode Potentials at 25 ∘C Reduction Half-Reaction E∘(V) Pb2+(aq)+2e− →Pb(s) -0.13 Zn2+(aq)+2e− →Zn(s) -0.76 Br2(l)+2e− →2Br−(aq) 1.09 Cl2(g)+2e− →2Cl−(aq) 1.36 MnO2(s)+4H+(aq)+2e− →Mn2+(aq)+2H2O(l) 1.21 Pb2+(aq)+2e− →Pb(s) -0.13 Br2(l)+2Cl−(aq)→2Br−(aq)+Cl2(g) Express your answer using two significant figures.
- Zn2+ Choose... Choose... (1pts) Identify the complete redox reaction for a ZnZn2+1|Cu2+1Cu cell. A. Zn(s) + Cu?+ (aq) (aq) + Cu(s) B. Zn(s) + Cu(s) → Zn2+ (aq) + Cu2+ (aq) C. Zn2+ (aq) + Cu(s) Zn(s) + Cu2+ (aq) D. Zn (s) + 2 Cu(s) — Zn2+ (aq) + 2 Cu2+ (aq) (1pts) Identify the complete redox reaction for a Zn/Zn2+||Pb2+1Pb cell. A. Zn (s) + Pb(s) Zn2+ (aq) + Pb2+ (aq) B. Zn2+ (aq) + Pb(s) Zn(s)...
Pb2+(aq) + 2e− ⇌ Pb(s) E° = -0.126 V 2H+(aq) + 2e− ⇌ H2(g) E° = 0.000 V E°cell (in V)= 0.126 V 2. The electrochemical cell is comprised of a Pb electrode in a 1.67 × 100 M solution of Pb2+ (aq) coupled to a Pt electrode in a solution containing H+ (aq) where the pH of the solution is 0.37 and the partial pressure of H2(g) is 0.571 atm. The temperature of the cell is held constant at...
Use the tabulated electrode potentials to calculate K for the oxidation of nickel by H+: Ni(s)+2H+(aq)→Ni2+(aq)+H2(g) Express your answer using two significant figures. Standard reduction half-cell potentials at 25∘C Half-reaction E∘ (V) Half-reaction E∘ (V) Au3+(aq)+3e−→Au(s) 1.50 Fe2+(aq)+2e−→Fe(s) −0.45 Ag+(aq)+e−→Ag(s) 0.80 Cr3+(aq)+e−→Cr2+(aq) −0.50 Fe3+(aq)+3e−→Fe2+(aq) 0.77 Cr3+(aq)+3e−→Cr(s) −0.73 Cu+(aq)+e−→Cu(s) 0.52 Zn2+(aq)+2e−→Zn(s) −0.76 Cu2+(aq)+2e−→Cu(s) 0.34 Mn2+(aq)+2e−→Mn(s) −1.18 2H+(aq)+2e−→H2(g) 0.00 Al3+(aq)+3e−→Al(s) −1.66 Fe3+(aq)+3e−→Fe(s) −0.036 Mg2+(aq)+2e−→Mg(s) −2.37 Pb2+(aq)+2e−→Pb(s) −0.13 Na+(aq)+e−→Na(s) −2.71 Sn2+(aq)+2e−→Sn(s) −0.14 Ca2+(aq)+2e−→Ca(s) −2.76 Ni2+(aq)+2e−→Ni(s) −0.23 Ba2+(aq)+2e−→Ba(s) −2.90 Co2+(aq)+2e−→Co(s) −0.28 K+(aq)+e−→K(s) −2.92 Cd2+(aq)+2e−→Cd(s)...
Consider an electrochemical cell constructed from the following half cells, linked by an external circuit and by a KCl salt bridge.?• an Al(s) electrode in 1.0 M Al(NO3)3 solution? • a Pb(s) electrode in 1.0 M Pb(NO3)2 solution?The balanced overall (net) cell reaction isA. Pb(s) + Al3+(aq) ? Pb2+(aq) + Al(s).B. 3Pb(s) + 2Al3+(aq) ? 3Pb2+(aq) + 2Al(s).C. 3Pb2+(aq) + 2Al(s) ? 3Pb(s) + 2Al3+(aq).D. Pb2+(aq) + Al(s) ? Pb(s) + Al3+(aq).Can you explain and show steps of how to...