Question

Pb2+(aq) + 2e− ⇌ Pb(s) E° = -0.126 V 2H+(aq) + 2e− ⇌ H2(g) E° =...

Pb2+(aq) + 2e− ⇌ Pb(s) E° = -0.126 V

2H+(aq) + 2e− ⇌ H2(g) E° = 0.000 V

E°cell (in V)= 0.126 V

2. The electrochemical cell is comprised of a Pb electrode in a 1.67 × 100 M solution of Pb2+ (aq) coupled to a Pt electrode in a solution containing H+ (aq) where the pH of the solution is 0.37 and the partial pressure of H2(g) is 0.571 atm. The temperature of the cell is held constant at 25°C.

(a)What is Ecell (in V) for the electrochemical cell? Report your answer to three decimal places in standard notation (i.e., 0.123 V) \

(b) If the pH of the the cell compartment on the right is decreased to -1.38 while the other partial pressures and concentrations remain the same as in question 2, what will be the new Ecell (in V)? Report your answer to three decimal places in standard notation (i.e., 0.123 V).

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Answer #1

ナナ a»うナ叶 +3 10 -C-1-35) C-034づ

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