What are the products of the following reactions? Use the letters to assign the right products....
The below reaction is accomplished with one reagent. Br The letters below represent all reagents you have learned in chapters 6-8. Which of the below reagents would you use to accomplish this process? Enter the ONE correct letter below. • a. H2SO4, H20 b.HBO c. Br2 • d. Br2. H20 e. 1) BH3 (or R2BH), 2) NaOH, H20 • f. 1) OsO4, 2) NaHSO3, H20 g. 1) O3. 2) CH3SCH3 h.mCPBA • i.H2.Pd/C j. NaNH2 k 2 eg NaNH2 ....
1. PREDICT THE PRODUCT: Provide the structure of the major product expected from the following reactions or reaction sequences. Make sure you account for any regio- and/or stereochemistry! (24 pts.) H2O 1. Hg(OAC), CH, OH 2. NaBH H2SO4 H20 1) BH-THF 2) H202, KOH HBr Bry, H2O HBr ROOR 1. BH3-THF 2. H2O2, NaOH H20, H2SO4 1. NaNH2 H2 H-CEC-CH2 CH2 CH3 2. CH CH Br Lindlar cat 1. Sia BH-THF 2. H2O2, H2O
Predict the major organic product
or products of each of the following reactions:
Identify the mechanism
taking place in each of the reactions and please provide
explanation.
H2SO4 a) (CHỊ) CH CH=CH, HO Hg(OAc)2 NaBH4 b) (CH3)2CH CH=CH2 H2O BH3: THE H2O2, NaOH c) (CH3),CH CH=CH2 H2SO4, H2O d) CHCECH HgSO4 HZ/Ni f) + Cl2 + H2O g) Cold KMnO4 dilute h) 1. CH CO-OH 2. Hz0 Br2 i) CC14
1. Provide products for the following reactions. Show appropriate stereochemistry where appropriate. HI H2SO4 CH,OH 1. Hg(OAc),/H,0 2. NaBH4 1. BH; 2. H,Oz/NaOH H/Pd H2SO4/H2O 4. Provide the missing reagents or starting materials in the following reactions. OH Br HO 1. Br2 2, NaNH (excess) 3. H2O
1. Indicate the conditions you would use to accomplish each of the following transformations by selecting the appropriate letter from this list. Write the letter above the reaction arrow. You may use some choices more than once, or not at all. A 1) Hg(OAc)2, H20; 2) NaBH B 1) BHs 2) H2O2, NaOH, H2O C 1)Os, 2) (CH3)2S D Os04, TBHP, H20 E 1)Os; 2) H202 F HBr H H2SO4 (cat), H2O I Br2, H20 J H2, Pd/C K NaOH...
(30 pt) Draw the structures of the MAJOR products for the
following reactions. Be sure to clearly show the REGIO- and
STEREOCHEMISTRY of each product.
H2SO4 X - H2O BH3 H2O2 THF H20, OH Br2 CH2OH excess HBO d) CH3-C=C-CH3 1 eq Cl2 e) CH3 -C=C-CH3 CH2Cl2 Na CH3CO2H 9) CH.-C=C-H, under CH3COH f) CH3-CEC-CH3 liquid NH3 -78 °C H202 g) CH3CH2-CEC-H R2BH THE H2O, OH NaNH2 CH3CH2Br H2SO4 h) CH3CH2-CEC-H my Chcn=c20-n, Nanets, Cheka na H2O HgSO4 heat 1...
Provide the products and mechanisms of the reactions of 1-methylcyclohexene with the following reagents: A.) CHBr3, OH- B.) Simmons-Smith Reagent C.) H+, H2O D.) 1. BH3 * THF, then 2. OH-, H2O2 E.) 1. Hg (OAc)2, H2O; then 2. NaBH4 F.) H2, Ni G.) Br2 H.) Br2, H2O
Select the best reagents for each of the following transformations. You should only use each set of reagents once. You can record your answers on this worksheet, or type/write on another sheet of paper. You only need to submit the question number and the letter corresponding to the set of reagents from the table below. H2(g), Pd/C HBr HO" 1) Hg(OAc)2, H2O 1) BH; THF 2) NaBH4 2) H202, NaOH(aq) CH,OH, H+ Br2, CH2Cl2 Br2, H20 MCPBA 1) 03, -78°C...
9.44 (•) Determine whether the following reactions are redox reactions. If they are, identify whether the molecule has been oxidized or reduced. (a) (b) ý modo de volg Br2, heat + HO og sm. .- Br + H-Br (c) H2SO4 t o H2SO4 , .- CH3 NaBHA CH2OH OH OH - OH .PY OH + BH3 o-Na 9.45 (•) Predict the product(s) that would result when the alkenes are allowed to react under the following conditions: i) Bra; ii) Cl2;...
Provide the major product(s) for the following reactions: Show
Stereochemistry when necessary
HBr Br2 CH2Cl2 HBr Br2 ROOR H20 H2O СН,ОН H30* 1) BH3, THE 2) H2O2, NaOH, H2O 1) Hg(O2CCF3)2 CH3OH 2) NaBH4, NaOH 1) Hg(OAc)2, H20, THF 2) NaBH4, NaOH H2 Pd/C