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8) A reaction occurs via the following sequence of elementary steps. What is the rate law...
Use the generic elementary steps shown to below to answer the following questions. A + BC...
Use the generic elementary steps shown to below to answer the following questions. A + BC + D Elementary Step 1 (slow) A + DC + E Elementary Step 2 (fast) a. Based on the provided elementary steps, but is the net reaction? Select] [Select] 2A+B+D -> 2C+D+E 2A+B --> 2C+E termediates in this reaction? [Select] 2A +B+D -> 2C+E 2A + B --> 2C+D+E C. If step 115 the slow step, what should be the rate law for this...
A reaction mechanism is defined as the sequence of reaction steps that define the pathway from...
A reaction mechanism is defined as the sequence of reaction steps that define the pathway from reactants to products. Each step in a mechanism is an elementary reaction, which describes a single molecular event of usually one or two molecules interacting. The rate law for an overall reaction is the rate law for the slowest step in the mechanism, which is directly related to the stoichiometric coefficients of the reactants. The exception to this rule occurs when the slowest step...
Which statement is false concerning elementary steps in a reaction mechanism? the rate law can be...
Which statement is false concerning elementary steps in a reaction mechanism? the rate law can be deduced from the stoichiometry of reactants for an elementary step the overall molecularity for an elementary step is the sum of the stoichiometric coefficients for all reactants in that step the rate law for an elementary step must be determined experimentally the rate law for the overall reaction is always the same as the rate law for the slowest elementary step both (c) and...
To understand how elementary steps make up a mechanism and how the rate law for an...
To understand how elementary steps make up a mechanism and how the rate law for an elementary step can be determined. Very often, a reaction does not tell us the whole story. For instance, the reaction NO2(g)+CO(g)→NO(g)+CO2(g)NO2(g)+CO(g)→NO(g)+CO2(g) does not involve a collision between an NO2NO2 molecule and a COCO molecule. Based on experimental data at moderate temperatures, this reaction is thought to occur in the following two steps: NO2(g)+NO2(g)→NO3(g)+NO(g)NO2(g)+NO2(g)→NO3(g)+NO(g) NO3(g)+CO(g)→CO2(g)+NO2(g)NO3(g)+CO(g)→CO2(g)+NO2(g) Each individual step is called an elementary step. Together, these...
Consider the overall reaction.... A+B--C+D which has an observed rate law of Rate=k[A12 Which of the...
Consider the overall reaction.... A+B--C+D which has an observed rate law of Rate=k[A12 Which of the following choices would be a sensible 2-step mechanism, given this observed rate law? O A+A-->E slow E+B-->C+D fast A+B--> 2 E --> C+D fast slow A+A-->E E+B-->C+D fast slow A+B-->E 2 E -->C+D slow fast
For the chemical reaction: A + B 3 C observed to have a rate law...
For the chemical reaction: A + B 3 C observed to have a rate law of Rate = k [B]2, the following reaction mechanism has been proposed. 2 B D (slow) D + A 3 C + B In your evaluation of the reaction mechanism you would conclude the mechanism is: A) a plausible representation of the reaction B) an implausible representation as the predicted rate law does not match the observed rate law C) an implausible...
Sketch a reaction coordinate energy diagram for the following elementary steps, which describe an endothermic reaction....
Sketch a reaction coordinate energy diagram for the following elementary steps, which describe an endothermic reaction. Write the overall rate law for this process. What is the reaction order? A+B=3C. fastest C+2D= . Slow E=F. Fast
5. An elementary reaction has the form 2A → B. The rate law is Rate A)...
5. An elementary reaction has the form 2A → B. The rate law is Rate A) k[A] B) 2 k[A] C) k? [A] D) k[A] 6. For some reaction, when concentration of reactant "A" doubles, the rate of the reaction doubles. The reaction is order in reactant A. B) 1" A oth C) 2nd D) 3rd 7. Tetrahydrofuran (commonly referred to as THF) is an organic solvent with a density of 0.889 g/mL. A solution is prepared by dissolving 11.8...
At 300 K, the following reaction is found to obey the rate law of Rate =...
At 300 K, the following reaction is found to obey the rate law of Rate = k[NOCl]^2: 2 NOCl(g) 2 NO(g) + Cl2(g) The following reaction mechanism has been proposed for the reaction above: Proposed Mechanism: NOCl(g) ->NO(g) + Cl(g) slow Cl(g) + NOCl(g) -> NOCl(g) fast NOCl2(g) -> NO(g) + Cl2(g) fast 21. The suggested rate law in the mechanism is Rate = k[NOCl]. (T) 22. The reaction mechanism is plausible. (F) 23. NOCl2 is a catalyst in...
39) What are the units of k in the following rate law? Rate = K[X][Y]1/2 40)...
39) What are the units of k in the following rate law? Rate = K[X][Y]1/2 40) What are the units of k in the following rate law? Rate = k[X]2 41) What is the overall order of the following reaction, given the rate law? X + 2Y → 42 Rate = k[X][Y] A) 3rd order B) 5th order C) 2nd order D) 1st order E) 6th order 42) What is the overall order of the following reaction, given the rate...
Use the generic elementary steps shown to below to answer the following questions. A + BC + D Elementary Step 1 (slow) A + DC + E Elementary Step 2 (fast) a. Based on the provided elementary steps, but is the net reaction? Select] [Select] 2A+B+D -> 2C+D+E 2A+B --> 2C+E termediates in this reaction? [Select] 2A +B+D -> 2C+E 2A + B --> 2C+D+E C. If step 115 the slow step, what should be the rate law for this...
Consider the overall reaction.... A+B--C+D which has an observed rate law of Rate=k[A12 Which of the following choices would be a sensible 2-step mechanism, given this observed rate law? O A+A-->E slow E+B-->C+D fast A+B--> 2 E --> C+D fast slow A+A-->E E+B-->C+D fast slow A+B-->E 2 E -->C+D slow fast
5. An elementary reaction has the form 2A → B. The rate law is Rate A) k[A] B) 2 k[A] C) k? [A] D) k[A] 6. For some reaction, when concentration of reactant "A" doubles, the rate of the reaction doubles. The reaction is order in reactant A. B) 1" A oth C) 2nd D) 3rd 7. Tetrahydrofuran (commonly referred to as THF) is an organic solvent with a density of 0.889 g/mL. A solution is prepared by dissolving 11.8...
39) What are the units of k in the following rate law? Rate = K[X][Y]1/2 40) What are the units of k in the following rate law? Rate = k[X]2 41) What is the overall order of the following reaction, given the rate law? X + 2Y → 42 Rate = k[X][Y] A) 3rd order B) 5th order C) 2nd order D) 1st order E) 6th order 42) What is the overall order of the following reaction, given the rate...
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