please don't use any
abbreviations! like I don't know how to draw anything like oet or
an R group like please just draw out the whole thing!
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please don't use any
abbreviations! like I don't know how to draw anything like oet or...
please don't use any abbreviations! like I don't know how to draw anything like oet or...
please don't use any abbreviations! like I
don't know how to draw anything like oet or an R group like please
just draw out the whole thing!
CH3 CO2Et Hagemann's ester The compound known as Hagemann's ester is prepared by treatment of a mixture of formaldehyde and ethyl acetoacetate with base, followed by acid-catalyzed decarboxylation. The reaction involves the following steps: 1. Deprotonation of ethyl acetoacetate to form enolate ion 1; 2. Reaction of the enolate ion with formaldehyde to...
Homework marked this wrong. Not sure what I did wrong Nat -OET ethanol This reaction involves...
Homework marked this wrong. Not sure what I did wrong
Nat -OET ethanol This reaction involves two successive Michael reactions, and has the following steps: 1. Deprotonation forms enolate ion 1; 2. The first Michael reaction forms enolate ion 2; 3. The second Michael reaction forms enolate ion 3; 4. Protonation leads to the final product. Write the mechanism out on a sheet of paper, and then draw the structure of enolate ion 2. • You do not have to...
please don't use any abbreviations! The following structure represents an intermediate formed by addition of an...
please don't use any
abbreviations!
The following structure represents an intermediate formed by addition of an ester enolate ion to a second ester molecule. Draw the reactant. ball & stick labels • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading.
СО cat. H + NH2CH3 + H2CO2C CO2CH3 CO CHE Cocaine has been prepared by a...
СО cat. H + NH2CH3 + H2CO2C CO2CH3 CO CHE Cocaine has been prepared by a sequence beginning with a Mannich reaction between dimethyl acetonedicarboxylate, methylamine, and butanedial. The mechanism involves the following steps: 1. Following initial protonation of the carbonyl oxygen, nucleophilic attack by the amine forms carbinolamine 1; 2. Proton transfer and elimination of water forms iminium ion 2; he enol form of the dicarboxylate ester attacks the iminium ion to form adduct 3; 4. Adduct 3 tautomerizes...
tivities Electron pairs :0: :0: 9 H:03 :0—H I- Erase H-CC-HH-CC-H I- H-OH Write the first...
tivities Electron pairs :0: :0: 9 H:03 :0—H I- Erase H-CC-HH-CC-H I- H-OH Write the first step of this aldol reaction using curved arrows to show electron reorganization. H OHH dilute ag NaOH H-CC-C 0- 0-0-1 АН HH ethana "aldor Recheckt (2017) Nat Et Ethanol pe 1 pt The double cyclization (above) proceeds by formation of an enolate followed by two successive intramolecular Michael reactions 1 pt Write a detailed mechanism for this reaction on paper, then draw structural formulas...
Problem 19.41a Write a detailed mechanism for the following reaction. EtoY OE orbollowed OEt + EtoNa...
Problem 19.41a Write a detailed mechanism for the following reaction. EtoY OE orbollowed OEt + EtoNa Eto OEt OE Get help answering Molecular Drawing questions. X Incorrect. Draw step one of the mechanism which forms the initial carbanion. Draw only the carbanion form of the reaction, NOT the enolate. Include lone pairs and formal charges in the mechanism. Draw out explicitly only the ONE hydrogen that is removed in this mechanistic step. DO NOT USE ABBREVIATIONS SUCH AS OEt for...
The double cyclization (above) proceeds by formation of an enolate followed by two successive intramolecular Michael...
The double cyclization (above) proceeds by formation of an enolate followed by two successive intramolecular Michael reactions. Write a detailed mechanism for this reaction on paper, then draw structural formulas for the reactant enolate and adduct enolate of the first Michael reaction in the window below. You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. Do not include lone pairs in your answer. They will not be considered in the grading. Draw enolates...
If the Favorskii R of 2-chlorocyclohexanone is carried out using sodium ethoxide in ethanol, the product...
If the Favorskii R of 2-chlorocyclohexanone is carried out using sodium ethoxide in ethanol, the product is ethyl cyclopentanecarboxylate, shown below. CI CH,CH2O Na The reaction procceds via a 5-step mechanism and can be formulated as follows. Step 1: Formation of an enolate ion 1 and ethanol. Step 2: An intramolecular alkylation reaction, with enolate ion I as the nucleophile, to yield a fused ring intermediate 2 and Cr. Step 3: Formation of a tetrahedral carbonyl addition intermediate 3 Step...
[Review Topics) [References Draw the structure of the major organic product of the following reaction. Predict...
[Review Topics) [References Draw the structure of the major organic product of the following reaction. Predict whether the product will be an aldol or an enone. dilute aqueous NaOH CH3 0-5° • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. . Do not include lone pairs in your answer. They will not be considered in the grading. • If no reaction occurs, draw the organic starting material. C-@- - 0 Write...
draw the mechanism as well please! with lone pairs Question 8 When the following ketone is...
draw the mechanism as well please! with lone pairs
Question 8 When the following ketone is treated with aqueous sodium hydroxide, the aldol product is obtained in poor yields. In these cases, special distillation techniques are used to increase the yield of aldol product. Predict the aldol addition product that is obtained, and propose a mechanism for its formation. For the mechanism, draw the curved arrows as needed. Include lone pairs and charges in your answer. Do not draw out...
please don't use any abbreviations! like I
don't know how to draw anything like oet or an R group like please
just draw out the whole thing!
CH3 CO2Et Hagemann's ester The compound known as Hagemann's ester is prepared by treatment of a mixture of formaldehyde and ethyl acetoacetate with base, followed by acid-catalyzed decarboxylation. The reaction involves the following steps: 1. Deprotonation of ethyl acetoacetate to form enolate ion 1; 2. Reaction of the enolate ion with formaldehyde to...
Homework marked this wrong. Not sure what I did wrong
Nat -OET ethanol This reaction involves two successive Michael reactions, and has the following steps: 1. Deprotonation forms enolate ion 1; 2. The first Michael reaction forms enolate ion 2; 3. The second Michael reaction forms enolate ion 3; 4. Protonation leads to the final product. Write the mechanism out on a sheet of paper, and then draw the structure of enolate ion 2. • You do not have to...
please don't use any
abbreviations!
The following structure represents an intermediate formed by addition of an ester enolate ion to a second ester molecule. Draw the reactant. ball & stick labels • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. • Do not include lone pairs in your answer. They will not be considered in the grading.
СО cat. H + NH2CH3 + H2CO2C CO2CH3 CO CHE Cocaine has been prepared by a sequence beginning with a Mannich reaction between dimethyl acetonedicarboxylate, methylamine, and butanedial. The mechanism involves the following steps: 1. Following initial protonation of the carbonyl oxygen, nucleophilic attack by the amine forms carbinolamine 1; 2. Proton transfer and elimination of water forms iminium ion 2; he enol form of the dicarboxylate ester attacks the iminium ion to form adduct 3; 4. Adduct 3 tautomerizes...
tivities Electron pairs :0: :0: 9 H:03 :0—H I- Erase H-CC-HH-CC-H I- H-OH Write the first step of this aldol reaction using curved arrows to show electron reorganization. H OHH dilute ag NaOH H-CC-C 0- 0-0-1 АН HH ethana "aldor Recheckt (2017) Nat Et Ethanol pe 1 pt The double cyclization (above) proceeds by formation of an enolate followed by two successive intramolecular Michael reactions 1 pt Write a detailed mechanism for this reaction on paper, then draw structural formulas...
Problem 19.41a Write a detailed mechanism for the following reaction. EtoY OE orbollowed OEt + EtoNa Eto OEt OE Get help answering Molecular Drawing questions. X Incorrect. Draw step one of the mechanism which forms the initial carbanion. Draw only the carbanion form of the reaction, NOT the enolate. Include lone pairs and formal charges in the mechanism. Draw out explicitly only the ONE hydrogen that is removed in this mechanistic step. DO NOT USE ABBREVIATIONS SUCH AS OEt for...
The double cyclization (above) proceeds by formation of an enolate followed by two successive intramolecular Michael reactions. Write a detailed mechanism for this reaction on paper, then draw structural formulas for the reactant enolate and adduct enolate of the first Michael reaction in the window below. You do not have to consider stereochemistry. You do not have to explicitly draw H atoms. Do not include lone pairs in your answer. They will not be considered in the grading. Draw enolates...
If the Favorskii R of 2-chlorocyclohexanone is carried out using sodium ethoxide in ethanol, the product is ethyl cyclopentanecarboxylate, shown below. CI CH,CH2O Na The reaction procceds via a 5-step mechanism and can be formulated as follows. Step 1: Formation of an enolate ion 1 and ethanol. Step 2: An intramolecular alkylation reaction, with enolate ion I as the nucleophile, to yield a fused ring intermediate 2 and Cr. Step 3: Formation of a tetrahedral carbonyl addition intermediate 3 Step...
[Review Topics) [References Draw the structure of the major organic product of the following reaction. Predict whether the product will be an aldol or an enone. dilute aqueous NaOH CH3 0-5° • You do not have to consider stereochemistry. • You do not have to explicitly draw H atoms. . Do not include lone pairs in your answer. They will not be considered in the grading. • If no reaction occurs, draw the organic starting material. C-@- - 0 Write...
draw the mechanism as well please! with lone pairs
Question 8 When the following ketone is treated with aqueous sodium hydroxide, the aldol product is obtained in poor yields. In these cases, special distillation techniques are used to increase the yield of aldol product. Predict the aldol addition product that is obtained, and propose a mechanism for its formation. For the mechanism, draw the curved arrows as needed. Include lone pairs and charges in your answer. Do not draw out...
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