please answer the following
there is part a and b. thanks.
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please answer the following
there is part a and b. thanks.
1. The following represents the...
please answer both. 1. The following represents the structure of the various transition metal complexes accurately...
please answer both.
1. The following represents the structure of the various transition metal complexes accurately drawn with necessary geometry. In the spaces provided a. Show the electron counting b. Oxidation state of the metal center and ligand charges if present (You don't have to draw out phenyl rings on ligands (e.g., for PPh3)) c) [ReCI(H2C=CH2) (dppe)21+ (dppe = Ph PCH CH PPhy) Pha Pha Pl . Re Ph2 cl Ph2 d. [trans-Aul Ph2] - (Ph=C6H5) Ph-Au-Ph.
3026 Inorganic Chemistry 1. Propose an 18e-structure for the following metal/ligand combinations. Use at least one...
3026 Inorganic Chemistry 1. Propose an 18e-structure for the following metal/ligand combinations. Use at least one of each metal and ligand listed. Complexes must be neutral. Don't use more than 2 metal centers. Clearly show your electron counting. Ligands are shown without charges, please indicate the proper ligand charge in your electron counting. Draw a reasonable structure showing the geometry about the metal center(s). a. Ir, Cp, CENME
Please give a detailed explanation. 18.15 The Wilkinson catalyst chlorotris(triphenylphosphine)rhodium(I), CIRh(PPha), brings about the catalytic hydrogenation...
Please give a detailed explanation.
18.15 The Wilkinson catalyst chlorotris(triphenylphosphine)rhodium(I), CIRh(PPha), brings about the catalytic hydrogenation of an alkene in homogeneous solution: R R CIRh(PPh3)3 C=C + H - RCH CHR (18.41) HH (a) Using the following mechanistic steps as your guide, draw structures of the transition-metal complexes involved in each step. Give the electron count and the metal oxidation state at each step. 1. oxidative addition of H, to the catalyst 2. ligand substitution of one PPhz by the...
UESTION 1 Consider the following five transition metal complexes A - E: PPhz CO CO Cl...
UESTION 1 Consider the following five transition metal complexes A - E: PPhz CO CO Cl В PPh3 CO Cl/ CH CH CH 2 Ph2P 2 143 CO CO CH a) Assign electron count and formal oxidation states to each of the five complexes b) Which of the complexes (if any) are likely to undergo the following types of reaction? In each case, give the main product expected (i)Oxidative addition (ii)1,2 insertion ("alkene" insertion) (iii) Reductive elimination
1. For each of the following complexes, give the electron configurations of the d-type M Os,...
1. For each of the following complexes, give the electron configurations of the d-type M Os, for tetrahedral complexes. Also ie ) (e) for octahedral complexes and (e( ch complex in units of the Bohr , Fe(CN) 3, CoCl , Ni(CO)4, Ti(H2O) +, magnet n f.в Co ( NH3) 3+, Co(FLO)r", Fe(CN) V Fa". Cu(H2O) г., CuCl? , V(CO), Cr(CO) each octahedral complex is high-spi the ligand field theory notes). ust use your judgment as to whether n or low-spin...
Please answer all of the following: a) Give the correct IUPAC name and sketch the structure...
Please answer all of the following: a) Give the correct IUPAC name and sketch the structure of the transition metal complex for each of the following compounds. If multiple stereoisomers are possible, give both names and structures: 1) [Pt(NH3)2Cl2] 2) [Cr(NMe3)4Br2]PF6 3) K[Co(edta)], where H4(edta) = ethylenediaminetetraacetic acid 4) [Ir(CO)Cl(PPh3)2] 5) Hg[Co(NCO)4] 6) [Fe(acac)3], where H(acac) = acetylacetone 7) [Co(NH3)6]3+[Cr(CN)6]3- 8) [{Co(NH3)5}2(μ-OH)]Cl5 9) [TiCl3(thf)3], where thf = tetrahydrofuran 10) [Ru(bpy)2Cl2], where bpy = 2,2’-bipyridine 11) V(O)(acac)2, where H(acac) = acetylacetone...
just part f please 1. For the following complexes: i) give the formal oxidation state of...
just part f please
1. For the following complexes: i) give the formal oxidation state of the metal ii) the d count for the metal ions (e.g. Fe → d) iii) sketch the compound iv) give its point group v) provide a qualitative o-only d-orbital splitting diagram indicating the correct symbols for the point group (i.e. a1g) vi) Indicate if you would predict a Jahn-Teller distortion (no need to distort to splitting diagram) vii) Calculate the spin-only value of off,...
just part d please 1. For the following complexes: i) give the formal oxidation state of...
just part d please
1. For the following complexes: i) give the formal oxidation state of the metal ii) the d count for the metal ions (e.g. Fe → d). iii) sketch the compound iv) give its point group v) provide a qualitative o-only d-orbital splitting diagram indicating the correct symbols for the point group (i.e. a10) vi) Indicate if you would predict a Jahn-Teller distortion (no need to distort to splitting diagram) vii) Calculate the spin-only value of Weft,...
2. For each of the following compounds, 1) write the formal oxidation state of the transition...
2. For each of the following compounds, 1) write the formal oxidation state of the transition metal and 2) the corresponding number of d electrons. 3) State whether or not each one is likely to be stable enough to be characterized. (a) [Re(CO)5] (b) [Cr(η6 -C6H6)2] (c) [Mo(CO)3(PPh3)3] (d) [Fe(η2 -C2H4)(CO)4] (e) [Zr(η5 -C5H5)Cl(OH)] (f) [Co(η5 -C5H5)2] 3. Identify the first-row transition metal (M) that follows the 18-electron rule for each of the following compounds (show how you arrived at...
2. For each of the following compounds, 1) write the formal oxidation state of the transition met...
2. For each of the following compounds, 1) write the formal oxidation state of the transition metal and 2) the corresponding number of d electrons. 3) State whether or not each one is likely to be stable enough to be characterized. (a) [Re(CO)5] (b) [Cr(η6 -C6H6)2] (c) [Mo(CO)3(PPh3)3] (d) [Fe(η2 -C2H4)(CO)4] (e) [Zr(η5 -C5H5)Cl(OH)] (f) [Co(η5 -C5H5)2] 3. Identify the first-row transition metal (M) that follows the 18-electron rule for each of the following compounds (show how you arrived at...
please answer both.
1. The following represents the structure of the various transition metal complexes accurately drawn with necessary geometry. In the spaces provided a. Show the electron counting b. Oxidation state of the metal center and ligand charges if present (You don't have to draw out phenyl rings on ligands (e.g., for PPh3)) c) [ReCI(H2C=CH2) (dppe)21+ (dppe = Ph PCH CH PPhy) Pha Pha Pl . Re Ph2 cl Ph2 d. [trans-Aul Ph2] - (Ph=C6H5) Ph-Au-Ph.
3026 Inorganic Chemistry 1. Propose an 18e-structure for the following metal/ligand combinations. Use at least one of each metal and ligand listed. Complexes must be neutral. Don't use more than 2 metal centers. Clearly show your electron counting. Ligands are shown without charges, please indicate the proper ligand charge in your electron counting. Draw a reasonable structure showing the geometry about the metal center(s). a. Ir, Cp, CENME
Please give a detailed explanation.
18.15 The Wilkinson catalyst chlorotris(triphenylphosphine)rhodium(I), CIRh(PPha), brings about the catalytic hydrogenation of an alkene in homogeneous solution: R R CIRh(PPh3)3 C=C + H - RCH CHR (18.41) HH (a) Using the following mechanistic steps as your guide, draw structures of the transition-metal complexes involved in each step. Give the electron count and the metal oxidation state at each step. 1. oxidative addition of H, to the catalyst 2. ligand substitution of one PPhz by the...
UESTION 1 Consider the following five transition metal complexes A - E: PPhz CO CO Cl В PPh3 CO Cl/ CH CH CH 2 Ph2P 2 143 CO CO CH a) Assign electron count and formal oxidation states to each of the five complexes b) Which of the complexes (if any) are likely to undergo the following types of reaction? In each case, give the main product expected (i)Oxidative addition (ii)1,2 insertion ("alkene" insertion) (iii) Reductive elimination
1. For each of the following complexes, give the electron configurations of the d-type M Os, for tetrahedral complexes. Also ie ) (e) for octahedral complexes and (e( ch complex in units of the Bohr , Fe(CN) 3, CoCl , Ni(CO)4, Ti(H2O) +, magnet n f.в Co ( NH3) 3+, Co(FLO)r", Fe(CN) V Fa". Cu(H2O) г., CuCl? , V(CO), Cr(CO) each octahedral complex is high-spi the ligand field theory notes). ust use your judgment as to whether n or low-spin...
just part f please
1. For the following complexes: i) give the formal oxidation state of the metal ii) the d count for the metal ions (e.g. Fe → d) iii) sketch the compound iv) give its point group v) provide a qualitative o-only d-orbital splitting diagram indicating the correct symbols for the point group (i.e. a1g) vi) Indicate if you would predict a Jahn-Teller distortion (no need to distort to splitting diagram) vii) Calculate the spin-only value of off,...
just part d please
1. For the following complexes: i) give the formal oxidation state of the metal ii) the d count for the metal ions (e.g. Fe → d). iii) sketch the compound iv) give its point group v) provide a qualitative o-only d-orbital splitting diagram indicating the correct symbols for the point group (i.e. a10) vi) Indicate if you would predict a Jahn-Teller distortion (no need to distort to splitting diagram) vii) Calculate the spin-only value of Weft,...
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