5b. The hydrolysis of 1-chloro-Imethylheptane in 80% ethanol follows first order kinetics. The values of the...
5b. The hydrolysis of 1-chloro-1methylheptane in 80% ethanol follows first order kinetics. The values of the rate constant with temperature is listed below: T(°C) k(sec) 1.06 x 10-5 3.19 x 10-4 35 9.86 x 104 45 2.92 x 103 Calculate the activation energy for the reaction an the value of the rate at infinitely high temperature..
The following gas-phase reaction follows first-order kinetics. CIO2F======> CIOF+O The activation energy of this reaction is 186 kJ/mol. The value of k at 322°C is 6.76 x 10-4 S-1 . a. What would be the value of k for this reaction at room temperature, 25°C? k = _____ S-1 b. At what temperature would this reaction have a k value of 9.50 x 10-2 S-1 ? Temperature = ______ oC
1) 2) 3) The decomposition of dinitrogen tetroxide to nitrogen dioxide at 400°C follows first-order kinetics with a rate constant of 3.84 X10-3-1. Starting with pure N204, how many minutes will it take for 38.0% to decompose? Suppose the surface-catalyzed hydrogenation reaction of an unsaturated hydrocarbon has a rate constant of 0.374 M/min. The reaction is observed to follow zero-order kinetics. If the initial concentration of the hydrocarbon is 2.90 M, what is the half-life of the reaction in seconds?...
The temperature dependence of the acid-catalysed hydrolysis of penicillin is investigated. This is a first order reaction that only depends on the concentration of the penicillin. The dependence of the rate constant, k, as a function of temperature is given in the following table: Data Temperature Irek (51) - (K) 285 1.42e – 4 316 0.00138 Determine the activation energy of this reaction. Express your answer in kJ mol-' to the first decimal place (XX.X). 55.0 Your last answer was...
O KINETICS AND EQUILIBRIUM Using a second order integrated rato low to find concentration '. At a certain temperature this reaction follows second-order kinetics with a rate constant of 13.1 M 250,() 250,()+0,6) Suppose a vessel contains so, at a concentration of 0.130 M. Calculate the concentration of SO, in the vessel 9.20 seconds later. You may assume no other reaction is important Round your answer to 2 significant digits. O KINETICS AND EQUILIRIUM Using the Arrhenius equation to calculate...
At a certain temperature this reaction follows first-order kinetics with a rate constant of Suppose a vessel contains at a concentration of . Calculate how long it takes for the concentration of to decrease to . You may assume no other reaction is important. Round your answer to significant digits. At a certain temperature this reaction follows first-order kinetics with a rate constant of 0.0366 s ": 250z (g) 2502(g) +0,(g) Suppose a vessel contains SO, at a concentration of...
The temperature dependence of the acid-catalysed hydrolysis of penicillin is investigated. This is a first order reaction that only depends on the concentration of the penicillin. The dependence of the rate constant, k, as a function of temperature is given in the following table: Temperature (K) k(s-1) 290 2.9e-5 320 2.61e-4 Determine the activation energy of this reaction. Express your answer in kJ mol-1 to the first decimal place (XX.X). Determine the Arrhenius pre-factor, A for this reaction. Express your...
The isomerization of methyl isocyanide, CH3NC - CH3CN, follows first-order kinetics. The half-lives were found to be 161 min at 199°C and 12.5 min at 230°C. Calculate the activation energy for this reaction. (R-8.314 J/mol K) 124 kJ/mol 6.17 x 10-3kJ/mol 78.2 kJ/mol 163 kJ/mol 31.4 kJ/mo
The decomposition of phosphine, PH3, follows first-order kinetics: 4 PH3(g) → P4(g) + 6 H2(g) Calculate the activation energy, Eq, in kJ/mol for the reaction, given that the rate constant k (at 25 °C) = 0.00852 s 1 and k (at 50 °C) = 0.756 s 1. 231 kJ/mol 144 kJ/mol O 56.5 kJ/mol О 99.3 kJ/mol O 111 kJ/mol
The isomerization of cyclopropane follows first order kinetics. The rate constant at 700 K is 6.20 × 10–4 min–1. A.) What is the half-life for this reaction in minutes? B.) If a sealed flask originally contains 0.150 M cyclopropane, what is the concentration remaining after one hour?