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First, clearly draw and label the starting compound given by name below (3,4-dimethyl-1-hexanol). Next, predict the...
please help in all sections asap!! Predict the product for the following reaction sequence: MgBr PCO...
please help in all sections asap!!
Predict the product for the following reaction sequence: MgBr PCO CHCE etler Predict the product for the following reaction, Predict the product for the following reaction. excess CH3OH H2SO4 H3CO OCHз Но осна ОСН3 Which one of the following compounds will yield 1-hexanol when treated with butylmagnesium bromide followed by acid workup? 1-hexanol formaldehyde acetaldehyde odrane hexanal Provide the reagents necessary to carry out the following conversion. 1. H20/ H2SO4 2. PCC/CH2Cl2 PCC/ CH2Cl2...
4. Propose a synthesis to create 3,4-dimethyl-3-hexanol from 1-butene. You only need to show individual steps an...
4. Propose a synthesis to create 3,4-dimethyl-3-hexanol from 1-butene. You only need to show individual steps and reagents, you do not need to show mechanisms. You must use 1-butene as your ONLY source of carbon atoms. The convergent processes have been outlined for you. for STEP 1: Show how to synthesize butyl magnesium bromide from 1-butene (5 points): BrMg STEP 2: Show how to synthesize 2-butanone from 1-butene (5 points): STEP 3: What intermediate forms below and what reagent(s) will...
Draw each product out based on given: 1.03 2.DMS 3. Na2Cr2O /HsSO /H20 PB13 2-methyl-1-propanol Mg/ether...
Draw each product out based on given:
1.03 2.DMS 3. Na2Cr2O /HsSO /H20 PB13 2-methyl-1-propanol Mg/ether 1. CO2 2. H,09 1. KMnO,/NaOH/H,0 2. H30 SOCI pyridine (CHz) CHCH OH pyridine V Mg/ether 1.CO2 2. H₂O* 1. LiAlH. 2. H2O
1) Predict the product(s) and draw the mechanism for when the compound below are treated with...
1) Predict the product(s) and draw the mechanism for when the compound below are treated with chloroethane and AICI3. (1.5 points) 2) Use Frost's circle to construct orbital energy diagram for cyclopentadienyl anion. Clearly draw the orbital energies diagram with the correct the number of electron in each level, label it as aromatic or antiaromatic according to Huckel's rule." (1.5 points) OH
Your answer is partially correct. Try again. Using the reagents below, list in order (by letter,...
Your answer is partially correct. Try again. Using the reagents below, list in order (by letter, no period) those necessary to provide this synthesis. Note: Not all spaces provided may be needed. Hints: First receive a Grignard reagent in steps 1 and 2. Use propanol in step 5. In step 9 a product from step 4 reacts with a product from step 8. a. NH3 b. Mg/ether C. SOCI2 d. 1. CO2 2. H30+ e. Na2Cr207/H2SO4/H20 f. product from step...
Name 1. With the following starting materials (at left), arra each correct order of reagents/reactants to...
Name 1. With the following starting materials (at left), arra each correct order of reagents/reactants to the final product (at right) (5 steps, 20 points, üer transformation to get linear, synthesis . A: Mg/diethyl ether B: Benzonitrile/H3O . D: 1) PhaP, 2) n-butylithium (Hint: used for Witig with an alkyl halide) E: Ag2O/THF/H20 Product Starting materials Cl Br
Please complete. Will rate 25. Predict the major organic product(s) for each reaction below. Note: some...
Please complete. Will rate
25. Predict the major organic product(s) for each reaction below. Note: some questions have multiple steps associated with them. (2 points each) a. O 1.Ph Culi CI 2. H20 1. CH3Li 2. H30* b. O NaBH4 OCHs CH3OH C. 1. PBr3 OH 2. NaCN 1. DIBAL-H 78 C H2SO4 OEt 2. H20 Pd(PPh3) Br FeBr3 B(OR)2
CHEM 241 Assignment 6 2. Provide the structure of the major products A, B, and C...
CHEM 241 Assignment 6
2. Provide the structure of the major products A, B, and C formed in each of the synthesis routes below. OH EINH Croz, H2SO A Hicat. B H, (-H20) 2) H30* В B ~ Br. 1 с LE A H30C b) H O V 2EOH cat (H20) 1) Hg(OAC). THE 2) NBH OAC - OCCH c) 1) POCI Me DMF - 2) NaHCO, (aq) Ph, P=CHCOMe - A Pdic. H C No Mg в с но...
s) Predict the principal organic product(s) in each of the following reactions. Draw the correct stereoisom...
s) Predict the principal organic product(s) in each of the following reactions. Draw the correct stereoisom wherever applicable (Structures with incomplete/wrong stereochemistry will not be accepted!!). CH₃ Clz Br2 Н,0 CCIA 1) BH3. THE 2) H2Oz/NaOH 1) O₃ 2) (CH3)2S МСРВА MCPECIES CH2Cl2 OsO4 NMO 1) МСРВА 2) H2O/H30* Hoy for Hos 1) Brz/H20 2) NaOH 1) Hg(OAC)2, H2O/THF 2) NaBHA = 1) O₃ 2) H20 340 H2SO4 HgSO4 2 Brz CCIA 2 HCI 26. pts) Listed below is information...
22. Starting with 1-hexene, which synthetic pathway below gives 2-cyanohexane? CN ? (a) HSO. (cat), H20;...
22. Starting with 1-hexene, which synthetic pathway below gives 2-cyanohexane? CN ? (a) HSO. (cat), H20; then NaCN (b) HBr/peroxide; then NaCN (c) HBr; then NaCN (d) Bry/H_O; then NaCN 23. [9 pts) Write out a complete mechanism for the following transformation: Br CH,CH,OH You 24. (20 pts] Draw the major expected organic product(s) for each of the following reactions. Be sure to indicate stereochemistry when needed. 1) TSCI, Pyr 2) NaB Br HS 1) SOCI. pyridine 2) NaSH OH...
please help in all sections asap!!
Predict the product for the following reaction sequence: MgBr PCO CHCE etler Predict the product for the following reaction, Predict the product for the following reaction. excess CH3OH H2SO4 H3CO OCHз Но осна ОСН3 Which one of the following compounds will yield 1-hexanol when treated with butylmagnesium bromide followed by acid workup? 1-hexanol formaldehyde acetaldehyde odrane hexanal Provide the reagents necessary to carry out the following conversion. 1. H20/ H2SO4 2. PCC/CH2Cl2 PCC/ CH2Cl2...
4. Propose a synthesis to create 3,4-dimethyl-3-hexanol from 1-butene. You only need to show individual steps and reagents, you do not need to show mechanisms. You must use 1-butene as your ONLY source of carbon atoms. The convergent processes have been outlined for you. for STEP 1: Show how to synthesize butyl magnesium bromide from 1-butene (5 points): BrMg STEP 2: Show how to synthesize 2-butanone from 1-butene (5 points): STEP 3: What intermediate forms below and what reagent(s) will...
Draw each product out based on given:
1.03 2.DMS 3. Na2Cr2O /HsSO /H20 PB13 2-methyl-1-propanol Mg/ether 1. CO2 2. H,09 1. KMnO,/NaOH/H,0 2. H30 SOCI pyridine (CHz) CHCH OH pyridine V Mg/ether 1.CO2 2. H₂O* 1. LiAlH. 2. H2O
1) Predict the product(s) and draw the mechanism for when the compound below are treated with chloroethane and AICI3. (1.5 points) 2) Use Frost's circle to construct orbital energy diagram for cyclopentadienyl anion. Clearly draw the orbital energies diagram with the correct the number of electron in each level, label it as aromatic or antiaromatic according to Huckel's rule." (1.5 points) OH
Your answer is partially correct. Try again. Using the reagents below, list in order (by letter, no period) those necessary to provide this synthesis. Note: Not all spaces provided may be needed. Hints: First receive a Grignard reagent in steps 1 and 2. Use propanol in step 5. In step 9 a product from step 4 reacts with a product from step 8. a. NH3 b. Mg/ether C. SOCI2 d. 1. CO2 2. H30+ e. Na2Cr207/H2SO4/H20 f. product from step...
Name 1. With the following starting materials (at left), arra each correct order of reagents/reactants to the final product (at right) (5 steps, 20 points, üer transformation to get linear, synthesis . A: Mg/diethyl ether B: Benzonitrile/H3O . D: 1) PhaP, 2) n-butylithium (Hint: used for Witig with an alkyl halide) E: Ag2O/THF/H20 Product Starting materials Cl Br
Please complete. Will rate
25. Predict the major organic product(s) for each reaction below. Note: some questions have multiple steps associated with them. (2 points each) a. O 1.Ph Culi CI 2. H20 1. CH3Li 2. H30* b. O NaBH4 OCHs CH3OH C. 1. PBr3 OH 2. NaCN 1. DIBAL-H 78 C H2SO4 OEt 2. H20 Pd(PPh3) Br FeBr3 B(OR)2
CHEM 241 Assignment 6
2. Provide the structure of the major products A, B, and C formed in each of the synthesis routes below. OH EINH Croz, H2SO A Hicat. B H, (-H20) 2) H30* В B ~ Br. 1 с LE A H30C b) H O V 2EOH cat (H20) 1) Hg(OAC). THE 2) NBH OAC - OCCH c) 1) POCI Me DMF - 2) NaHCO, (aq) Ph, P=CHCOMe - A Pdic. H C No Mg в с но...
s) Predict the principal organic product(s) in each of the following reactions. Draw the correct stereoisom wherever applicable (Structures with incomplete/wrong stereochemistry will not be accepted!!). CH₃ Clz Br2 Н,0 CCIA 1) BH3. THE 2) H2Oz/NaOH 1) O₃ 2) (CH3)2S МСРВА MCPECIES CH2Cl2 OsO4 NMO 1) МСРВА 2) H2O/H30* Hoy for Hos 1) Brz/H20 2) NaOH 1) Hg(OAC)2, H2O/THF 2) NaBHA = 1) O₃ 2) H20 340 H2SO4 HgSO4 2 Brz CCIA 2 HCI 26. pts) Listed below is information...
22. Starting with 1-hexene, which synthetic pathway below gives 2-cyanohexane? CN ? (a) HSO. (cat), H20; then NaCN (b) HBr/peroxide; then NaCN (c) HBr; then NaCN (d) Bry/H_O; then NaCN 23. [9 pts) Write out a complete mechanism for the following transformation: Br CH,CH,OH You 24. (20 pts] Draw the major expected organic product(s) for each of the following reactions. Be sure to indicate stereochemistry when needed. 1) TSCI, Pyr 2) NaB Br HS 1) SOCI. pyridine 2) NaSH OH...
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