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Short Answer Section (43 pts) - showing work helps! Substitution us. Elimination (12 pts). Predict all...
Short Answer Section (43 pts) – showing work helps! Substitution vs. Elimination (12 pts). Predict all...
Short Answer Section (43 pts) – showing work helps! Substitution
vs. Elimination (12 pts). Predict all major product(s) of each of
the following reactions and indicate the predominant mechanistic
pathways (Sn1, Sn2, E1, E2). Remember to consider rearrangements.
Mechanism #1 (10 pts). Draw a stepwise mechanism to account for the
following transformation. Br mechanism(s)? NaOH Cl mechanism(s)?
NaOEt OTs for this reaction, circle the major product mechanism(s)?
O K Cl for this reaction, circle the major product mechanism(s)?
NaOCH3 H2O...
23. Please answer the questions regarding to the following reactions. (12 pts) (a) CI + T...
23. Please answer the questions regarding to the following reactions. (12 pts) (a) CI + T (1) Is this a substitution or elimination reaction? (2) Do you think the reaction mechanism is Snl or Sx2? (3) Please provide mechanisms by using curved arrow pushing (step by step) that account for the product CL V ai + H2O (1) Is this a substitution or elimination reaction? (2) Do you think the reaction mechanism is Snl or Sn2? (3) Please provide mechanisms...
"Complete the reactions showing all Major Products, both substitution and elimination, that can form based on...
"Complete the reactions showing all Major Products, both
substitution and elimination, that can form based on the reaction
conditions. Be sure to show stereochemistry where
appropriate. Fill in each table with reaction conditions."
w upiete the following reactions showing all products, both substitution and elimination, that can form, then circle the MAJOR Foduct(s). Under each reaction, draw the step by step mechanism showing how each porduct is formed. Show or indicate stereochemistry where appropriate. Fill in each table with reaction...
Substitution and Elimination practice problems Analyze the reactant(s) and reaction conditions, then predict the st...
Substitution and Elimination practice problems Analyze the reactant(s) and reaction conditions, then predict the structure of the major organic product and indicate the predominant mechanism (Syl, SN2, El. or E2) of each reaction. къс(Снь. CH CH CH CH Br (сн),сон, 82с масн, CH3CH2CH2CH Br CHOH, Pc Всньсн, DMF,0°C сны + NaNO3 5°C CH, Сн,-с-отз НО 22°C CH CHOH 22°C кос(CH))). (CH)))соң, бес CHI + CHISH 43°C - месн,CH, CH,CHAOH, 78° с Н,0 22° C AB NACH CH,OH, O°C
Substitution and Elimination practice problems Analyze the reactant(s) and reaction conditions, then predict the structure of...
Substitution and Elimination practice problems Analyze the reactant(s) and reaction conditions, then predict the structure of the major organic product and indicate the predominant mechanism (S1, S2, E1, or E2) of each reaction KOC(CH) CH:CH-CH:CH BY (CH3),COH, 82°C 9 CH CH CH CH Br Na SCH CH,OH,0°C Nå SCH.CH DMF, 0°C 4 CHI - NaNO, sc CH CH3-Cors HO 22°C CH CH CH,OH 22°C K®SC(CH3) (CH3),COH, 82°C CHẠI • CH,SH 43°C масH,CH, CH,CHOH, 78°C CH H20 22°C Nясн, CH,OH, 0°C
-OH 5. For the reactions below: a. (10 pts) Predict all products and circle the major product if more than product...
-OH 5. For the reactions below: a. (10 pts) Predict all products and circle the major product if more than product can be made. Remember to indicate correct stereochemistry of your products for full credit: NaCN CH3CH,CH OH b. (3 pts) In any of your elimination products for the reactions above label whether they are Zaitsev or Hoffman
4. [12 pts] Propose mechanisms for the formation of all 3 products shown in the reaction...
4. [12 pts] Propose mechanisms for the formation of all 3 products shown in the reaction below: (draw curved arrows, intermediates, and resonance structures if necessary. NO NEED FOR TRANSITION STATES! CH CH CH CH Br Heat CH,CH,OH OCH.CH Mechanism.14 points) Mechanism 2 points) Mechanism.3 14 points) 5. [14 pts] Provide the major products of reacting the alkene shown in the middle of the scheme below with all the reagents independently. Draw the products' structures in the corresponding table below...
Thank you so much! (2 pts) Draw the major elimination products and Identify the mechanism responsible...
Thank you so much!
(2 pts) Draw the major elimination products and Identify the mechanism responsible (E1 or E2). If both E and Z isomers form, only draw the E alkene. If only one isomer forms, label the alkene "E,""Z," or neither 1. NaOCH3 а. Br НОСHЗ b. НОСНЗ C. CI NaOCH3 d. (6 pts) Draw the substitution and/or elimination product(s) for the following reactions and identify 2. the mechanism responsible (SN1, SN2, E1, or E2) for each product drawn....
Organic chemistry mechanisms i need help with systheses questions 6,7,8,9 2-hydroxybenzoic (3 pts) 5. Provide an...
Organic chemistry mechanisms
i need help with systheses questions 6,7,8,9
2-hydroxybenzoic (3 pts) 5. Provide an appropriate structure for: 3,3-dimethylcyclobutanecarbonitrile. (4 pts each, unless otherwise noted, 12 pts total) 6-8. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or reaction sequences) below. As appropriate, pay attention to regiospecificity (new bond formation and location in the product formed) and stereochemistry (direction in space of new bond(s) formed). Indicate ALL likely products: where one product does...
Can you please answer all of them? Section B: Free Response (you must show your work...
Can you please answer all of them?
Section B: Free Response (you must show your work for full credit) 1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp2 hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect...
Short Answer Section (43 pts) – showing work helps! Substitution
vs. Elimination (12 pts). Predict all major product(s) of each of
the following reactions and indicate the predominant mechanistic
pathways (Sn1, Sn2, E1, E2). Remember to consider rearrangements.
Mechanism #1 (10 pts). Draw a stepwise mechanism to account for the
following transformation. Br mechanism(s)? NaOH Cl mechanism(s)?
NaOEt OTs for this reaction, circle the major product mechanism(s)?
O K Cl for this reaction, circle the major product mechanism(s)?
NaOCH3 H2O...
23. Please answer the questions regarding to the following reactions. (12 pts) (a) CI + T (1) Is this a substitution or elimination reaction? (2) Do you think the reaction mechanism is Snl or Sx2? (3) Please provide mechanisms by using curved arrow pushing (step by step) that account for the product CL V ai + H2O (1) Is this a substitution or elimination reaction? (2) Do you think the reaction mechanism is Snl or Sn2? (3) Please provide mechanisms...
"Complete the reactions showing all Major Products, both
substitution and elimination, that can form based on the reaction
conditions. Be sure to show stereochemistry where
appropriate. Fill in each table with reaction conditions."
w upiete the following reactions showing all products, both substitution and elimination, that can form, then circle the MAJOR Foduct(s). Under each reaction, draw the step by step mechanism showing how each porduct is formed. Show or indicate stereochemistry where appropriate. Fill in each table with reaction...
Substitution and Elimination practice problems Analyze the reactant(s) and reaction conditions, then predict the structure of the major organic product and indicate the predominant mechanism (Syl, SN2, El. or E2) of each reaction. къс(Снь. CH CH CH CH Br (сн),сон, 82с масн, CH3CH2CH2CH Br CHOH, Pc Всньсн, DMF,0°C сны + NaNO3 5°C CH, Сн,-с-отз НО 22°C CH CHOH 22°C кос(CH))). (CH)))соң, бес CHI + CHISH 43°C - месн,CH, CH,CHAOH, 78° с Н,0 22° C AB NACH CH,OH, O°C
Substitution and Elimination practice problems Analyze the reactant(s) and reaction conditions, then predict the structure of the major organic product and indicate the predominant mechanism (S1, S2, E1, or E2) of each reaction KOC(CH) CH:CH-CH:CH BY (CH3),COH, 82°C 9 CH CH CH CH Br Na SCH CH,OH,0°C Nå SCH.CH DMF, 0°C 4 CHI - NaNO, sc CH CH3-Cors HO 22°C CH CH CH,OH 22°C K®SC(CH3) (CH3),COH, 82°C CHẠI • CH,SH 43°C масH,CH, CH,CHOH, 78°C CH H20 22°C Nясн, CH,OH, 0°C
-OH 5. For the reactions below: a. (10 pts) Predict all products and circle the major product if more than product can be made. Remember to indicate correct stereochemistry of your products for full credit: NaCN CH3CH,CH OH b. (3 pts) In any of your elimination products for the reactions above label whether they are Zaitsev or Hoffman
4. [12 pts] Propose mechanisms for the formation of all 3 products shown in the reaction below: (draw curved arrows, intermediates, and resonance structures if necessary. NO NEED FOR TRANSITION STATES! CH CH CH CH Br Heat CH,CH,OH OCH.CH Mechanism.14 points) Mechanism 2 points) Mechanism.3 14 points) 5. [14 pts] Provide the major products of reacting the alkene shown in the middle of the scheme below with all the reagents independently. Draw the products' structures in the corresponding table below...
Thank you so much!
(2 pts) Draw the major elimination products and Identify the mechanism responsible (E1 or E2). If both E and Z isomers form, only draw the E alkene. If only one isomer forms, label the alkene "E,""Z," or neither 1. NaOCH3 а. Br НОСHЗ b. НОСНЗ C. CI NaOCH3 d. (6 pts) Draw the substitution and/or elimination product(s) for the following reactions and identify 2. the mechanism responsible (SN1, SN2, E1, or E2) for each product drawn....
Organic chemistry mechanisms
i need help with systheses questions 6,7,8,9
2-hydroxybenzoic (3 pts) 5. Provide an appropriate structure for: 3,3-dimethylcyclobutanecarbonitrile. (4 pts each, unless otherwise noted, 12 pts total) 6-8. Syntheses: draw / provide the likely organic product(s) generated in each of the reactions (or reaction sequences) below. As appropriate, pay attention to regiospecificity (new bond formation and location in the product formed) and stereochemistry (direction in space of new bond(s) formed). Indicate ALL likely products: where one product does...
Can you please answer all of them?
Section B: Free Response (you must show your work for full credit) 1. Draw Frost circle diagrams for each compound shown. Assume that all atoms in the ring are sp2 hybridized. Populate the pi electrons in the corresponding MO's. Identify the compound as aromatic or antiaromatic. (5 pts) 2. What is the Hückel number of pi electrons for the molecule shown below? How many pi electron pairs does it have? Would you expect...
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