all three statement are wrong.
option A none is right.
1). e-Ea/RT is the fraction of molecule having energy more than activation enrgy.
2). the probability of correctly oriented collision in complex molecule is less than simple molecule.
3). For elementry reaction (reaction having single step) concentration dependence of rate can be determined by stoichiometric coefficients.
Which of the following statements is/are correct? 1) The term e-Ea/RT in the Arrhenius equation is...
Which of the following are correct? 1. The fraction of collisions with energy greater than or equal to the activation energy always doubles as the temperature, on the Kelvin scale, is doubled. 2. The probability of correct relative orientation in collisions is smaller for reactants with complicated shape than for reactants with simple shape. 3. The rate determining step in a reaction mechanism must be an elementary process. 4. The rate determining step in a reaction mechanism cannot be the...
Question 2 of 10 Which of the following statements concerning the collision theory of reaction rates is correct? 1. The activation energy is the difference between the EAHf° (products) and EAHf° (reactants). 2. The activation energy for the forward reaction is the negative of the activation energy for the reverse reaction. 3. The pre-exponential or frequency factor in the Arrhenius equation is a measure of the fraction of reactant molecules having sufficient energy to react. 4. The activation energy of...
O KINETICS AND EQUILIBRIUM Using the Arrhenius equation to calculate Ea from k versus T data The rate constant k for a certain reaction is measured at two different temperatures: temperature k 3.4x 101 172.0 C 1.1 x 1012 242.0 °C Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy E, for this reaction. Round your answer to 2 significant digits. kJ E= mol
O KINETICS AND EQUILIBRIUM Using the Arrhenius equation to calculate Ea from k versus T data The rate constant k for a certain reaction is measured at two different temperatures: temperature 148.0°C 89.0 °C k 5.7 x 10° 3.3 * 10° Assuming the rate constant obeys the Arrhenius equation, calculate the activation energy E, for this reaction Round your answer to 2 significant digits.
Which of the following statements about an elementary process or step is/are correct? 1) Intermediates in a reaction cannot be involved in the rate determining step ii) In the rate equation for the forward reaction of an elementary step, the overall reaction order is equal to the number of reactant molecules in the step iii) To be the rate determining step in a mechanism, an elementary step must be exothermic O A. ii and ill only B. i and iii...
Which of the following statements about an elementary process or step is/are correct? 1) Intermediates in a reaction cannot be involved in the rate determining step ii) In the rate equation for the forward reaction of an elementary step, the overall reaction order is equal to the number of reactant molecules in the step iii) To be the rate determining step in a mechanism, an elementary step must be exothermic O A. ii and ill only B. i and iii...
Section A. Decide whether the following statements are true or false. 1. The order n is always a positive integer. 2. If the reaction rate doubles as the concentration of [A] doubles, the reaction is first order with respect to A. 3. If the reaction rate is constant as the concentration of [A] doubles, the reaction is zero order with respect to A. 4. The rate law is an equation that shows the dependence of the reaction rate on the...
the extra credit problem Helpful Stuff Gas Arrhenius Equation: k = Ae-Ea/RT Constant: R= 8.314 J/mol K Integrated Rate Laws and Half-Lives: Zero order: [A] = -kt + [A]. t1/2 =[A]/2k • First order: In[A] = -kt + In[A]. t1/2 = 0.693/k • Second order: 1/[A] = kt + 1/[A] t1/2 = 1/k[A] • Pseudo first order: Use first order integrated rate law for the pseudo-first order reactant; other reactant concentrations remain constant, but are still present in overall rate...
extra credit Helpful Stuff Gas Arrhenius Equation: k = Ae-Ea/RT Constant: R= 8.314 J/mol K Integrated Rate Laws and Half-Lives: Zero order: [A] = -kt + [A]. t1/2 =[A]/2k • First order: In[A] = -kt + In[A]. t1/2 = 0.693/k • Second order: 1/[A] = kt + 1/[A] t1/2 = 1/k[A] • Pseudo first order: Use first order integrated rate law for the pseudo-first order reactant; other reactant concentrations remain constant, but are still present in overall rate law 1....
Helpful Stuff Gas Arrhenius Equation: k = Ae-Ea/RT Constant: R= 8.314 J/mol K Integrated Rate Laws and Half-Lives: Zero order: [A] = -kt + [A]. t1/2 =[A]/2k • First order: In[A] = -kt + In[A]. t1/2 = 0.693/k • Second order: 1/[A] = kt + 1/[A] t1/2 = 1/k[A] • Pseudo first order: Use first order integrated rate law for the pseudo-first order reactant; other reactant concentrations remain constant, but are still present in overall rate law 1. You study...