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HIO4 OsO4 t-BOOH t-BuOH, өОН K2Cr207 H2504, H20 "нн HCI heat O = 0 Na SME...
Predict the products. 16. K2Cr207 (excess) H2SO4, H2O HO 1. Phli, Et20 2. HCI, H20 3....
Predict the products.
16. K2Cr207 (excess) H2SO4, H2O HO 1. Phli, Et20 2. HCI, H20 3. SOCI2, Etz 4. NaOAC 1. Mg (1 eq), Et O Br 2. (1 eq) | C-CHO 3. HCI, H20 1. NaBH, MeOH, 0°C 2. PBrz. THE 3. LiAIDA, THE 4. HCI, H20 1. SOCI, NEtz, THE CHO 2. 2 eq Li, hexane 3. HCI, H20 hint: multiple steps 1. LiAlH4, THE 2. HCI, H2O 3. PBr3, THE 1. PCC, DCM OH 2. Mg, Eto...
9 just identify the type of reactiom a) 9) Complete the following: (Stereochemistry and regiochemistry may...
9
just identify the type of reactiom
a) 9) Complete the following: (Stereochemistry and regiochemistry may be important). (20 points) HgSO4/H2SO4 H20 OsO4. Me,NO f) HO/THF type type Br too ko Na/NH3 (0) b) t-BuOH type type a) NaOH(aq) c) h) heat type type OH a) NaNO3, H3O* b) H,O, 100 °C OCH HCI, ether d) i) OH type type KOBU, CHCI tBuOH/THF a) O3, CH2Cl2 -78 °C b) Mezs j) type type
6x. Fill in the missing items. 1.) CH3 Na BHз 2. HCI 1.)OH, H20 2.) H30®, heat * B. . .. 1.) NaOH, H20 2. NaOH, heat Na...
6x. Fill in the missing items. 1.) CH3 Na BHз 2. HCI 1.)OH, H20 2.) H30®, heat * B. . .. 1.) NaOH, H20 2. NaOH, heat NaCN CH3OH R но он Н,00 1.)LIAIH 4 , THE S 2. H,00
KMn04 cis-2-butene reflux SOC reflux t-butylbenzene AIC Zn(Hg) HCI Br2 (Imol) heat OH H20 KMn04 reflux...
KMn04 cis-2-butene reflux SOC reflux t-butylbenzene AIC Zn(Hg) HCI Br2 (Imol) heat OH H20 KMn04 reflux Sn 2. Brz 10 HNO3 H SO4 HCl Fe
a. HCI O C Br2 0°C Δ OH NaOH, heat NaOH он X. 1. LDA O...
a. HCI O C Br2 0°C Δ OH NaOH, heat NaOH он X. 1. LDA O 2 3. H2O
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH,...
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH, CH,CH2CH Predict the major products of the following reactions, including stereochemistry where appropriate. (a) (R)-2-butanol + TsCl in pyridine c) cyclooctanol + CrO3/H2SO4 (e) cyclopentylmethanol + Na2Cr 01/H2SO4 (g) n-butanol + HBr (i) potassium t-butoxide + methyl iodide (k) cyclopentanol + H2SO4/heat (m) sodium ethoxide +1-bromobutane (b) (S)-2-butyl tosylate +NaBr (d) cyclopentylmethanol + CrOs pyridine HC cyclopentanol + HCI/ZnCl2 (h) cyclooctylmethanol + CH3CH2MgBr (G)...
Question 39 What is the major product of the following reaction sequence? HCN HCI Н,0 heat...
Question 39 What is the major product of the following reaction sequence? HCN HCI Н,0 heat он он он -CN NH CN он II III IV І он соон V СА. ІІ СВ. Т C. IV D. II СЕ. V Question 40 What is the final product, Z, of the following synthesis? SOC12 1. LiAlH(O-t-Bu)3 ether, -78 °C 2. H20 1. KMnO4, OH, heat 2. H307 -CH3 Y Z O Lovebula o locha a odoli odor Ι II III IV...
1 2 H₂O (1) + 2 Na, ou a 2 Nallt cag) + Na 't le...
1 2 H₂O (1) + 2 Na, ou a 2 Nallt cag) + Na 't le H₂SO4 cag) H- H-OH U - O- hot Superific of water Calorimetry - In a coffee cup calorimeter 100.0 mL of 1. 0 M NaOH and 100.00 mL of 1.0 M H ₂ SO are mixed. The initial temperature of each solution was 25.6°C. After the reaction, the temperature of the solution was 31.3°C Calculate how much heat does the reaction generate ? Q...
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он H2SO4 H20, A heat 1) PhMgBr 1) NaOH, Br2 2) 5% HCI 2)H3O+, Δ OEt 1) PPh3 3...
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он H2SO4 H20, A heat 1) PhMgBr 1) NaOH, Br2 2) 5% HCI 2)H3O+, Δ OEt 1) PPh3 3) KOtBu 2) O 1) NaOH on. Br 2) O o
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он...
calorimetry 1 2 NaOlt (aq) + Na 't H₂SO4 (aq) - 2 H-O-8-0-H H₂O (1) +...
calorimetry
1 2 NaOlt (aq) + Na 't H₂SO4 (aq) - 2 H-O-8-0-H H₂O (1) + 1 Na, sou da H-O-H SO50 Calorimetry - In a coffee cup calorimeter, 100.0 mL of 1.0 M. NaOH and 100.0 ml of 1.0M H₂SO are mixed. The initial temperature of each solution was 25.6°C. After the reaction, the temperature of the solution was 31.3°C Calculate how much heat does the reaction generate?
Predict the products.
16. K2Cr207 (excess) H2SO4, H2O HO 1. Phli, Et20 2. HCI, H20 3. SOCI2, Etz 4. NaOAC 1. Mg (1 eq), Et O Br 2. (1 eq) | C-CHO 3. HCI, H20 1. NaBH, MeOH, 0°C 2. PBrz. THE 3. LiAIDA, THE 4. HCI, H20 1. SOCI, NEtz, THE CHO 2. 2 eq Li, hexane 3. HCI, H20 hint: multiple steps 1. LiAlH4, THE 2. HCI, H2O 3. PBr3, THE 1. PCC, DCM OH 2. Mg, Eto...
9
just identify the type of reactiom
a) 9) Complete the following: (Stereochemistry and regiochemistry may be important). (20 points) HgSO4/H2SO4 H20 OsO4. Me,NO f) HO/THF type type Br too ko Na/NH3 (0) b) t-BuOH type type a) NaOH(aq) c) h) heat type type OH a) NaNO3, H3O* b) H,O, 100 °C OCH HCI, ether d) i) OH type type KOBU, CHCI tBuOH/THF a) O3, CH2Cl2 -78 °C b) Mezs j) type type
6x. Fill in the missing items. 1.) CH3 Na BHз 2. HCI 1.)OH, H20 2.) H30®, heat * B. . .. 1.) NaOH, H20 2. NaOH, heat NaCN CH3OH R но он Н,00 1.)LIAIH 4 , THE S 2. H,00
KMn04 cis-2-butene reflux SOC reflux t-butylbenzene AIC Zn(Hg) HCI Br2 (Imol) heat OH H20 KMn04 reflux Sn 2. Brz 10 HNO3 H SO4 HCl Fe
a. HCI O C Br2 0°C Δ OH NaOH, heat NaOH он X. 1. LDA O 2 3. H2O
(2) NaBH4 (2) H202 OH cold, dilute KMnO4 "ОН H,C H,C HCO,H H,O с-с CH CH2CH, CH,CH2CH Predict the major products of the following reactions, including stereochemistry where appropriate. (a) (R)-2-butanol + TsCl in pyridine c) cyclooctanol + CrO3/H2SO4 (e) cyclopentylmethanol + Na2Cr 01/H2SO4 (g) n-butanol + HBr (i) potassium t-butoxide + methyl iodide (k) cyclopentanol + H2SO4/heat (m) sodium ethoxide +1-bromobutane (b) (S)-2-butyl tosylate +NaBr (d) cyclopentylmethanol + CrOs pyridine HC cyclopentanol + HCI/ZnCl2 (h) cyclooctylmethanol + CH3CH2MgBr (G)...
Question 39 What is the major product of the following reaction sequence? HCN HCI Н,0 heat он он он -CN NH CN он II III IV І он соон V СА. ІІ СВ. Т C. IV D. II СЕ. V Question 40 What is the final product, Z, of the following synthesis? SOC12 1. LiAlH(O-t-Bu)3 ether, -78 °C 2. H20 1. KMnO4, OH, heat 2. H307 -CH3 Y Z O Lovebula o locha a odoli odor Ι II III IV...
1 2 H₂O (1) + 2 Na, ou a 2 Nallt cag) + Na 't le H₂SO4 cag) H- H-OH U - O- hot Superific of water Calorimetry - In a coffee cup calorimeter 100.0 mL of 1. 0 M NaOH and 100.00 mL of 1.0 M H ₂ SO are mixed. The initial temperature of each solution was 25.6°C. After the reaction, the temperature of the solution was 31.3°C Calculate how much heat does the reaction generate ? Q...
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он H2SO4 H20, A heat 1) PhMgBr 1) NaOH, Br2 2) 5% HCI 2)H3O+, Δ OEt 1) PPh3 3) KOtBu 2) O 1) NaOH on. Br 2) O o
1. Predict the major product for the reactions shown below; pick any 5: HO xs CHal Ag20 NaOEt EtOH, Δ -H2O HO но он 0 он...
calorimetry
1 2 NaOlt (aq) + Na 't H₂SO4 (aq) - 2 H-O-8-0-H H₂O (1) + 1 Na, sou da H-O-H SO50 Calorimetry - In a coffee cup calorimeter, 100.0 mL of 1.0 M. NaOH and 100.0 ml of 1.0M H₂SO are mixed. The initial temperature of each solution was 25.6°C. After the reaction, the temperature of the solution was 31.3°C Calculate how much heat does the reaction generate?
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