whats STABILITY OF CARBOCATION INTERMEDIATES and how it works in sn1?
compare the STABILITY OF CARBOCATION INTERMEDIATES what makes a carbon more stable ?
why raking the way ?
The answer is in images
whats STABILITY OF CARBOCATION INTERMEDIATES and how it works in sn1? compare the STABILITY OF CARBOCATION...
In this example, how can you tell that the carbocation is 2 or 3
prime?
Step [3] Rearrangement of the carbocation by a 1,2-CH3 shift KEY STEP CH3 H CH3 H 1,2-shift CH3-C-C-CH2 CH3-C-C-CHE Shift one CHg group. - CH CHE • 1,2-Shift of a CH3 group from one carbon to the adjacent carbon converts the 2° carbocation to a more stable 3° carbocation. 2° carbocation less stable 3° carbocation more stable
What is hyperconjugation and how does this contribute to carbocation stability? Provide drawings to help explain your answer.
1. These questions consider carbocation formation in SN1 reactions. a. Which should be more reactive in an Sn1 reaction, a primary alkyl halide or a secondary alkyl halide? b. Which reactions that you performed today compare ONLY the reactivity of primary and secondary alkyl halides and not any other effect? c. What were the reaction times for these reactions? d. Do the results of these reactions match what you would expect theoretically? e. In one or two sentences, summarize the...
can somebody explain this. how we get the product
plzz
311 7.11 CARBOCATION STABILITY PRACTICE PROBLEM 7.18 When the compound called isoborneol is heated with 9 M sulfuric acid, the product of the reaction is the compound called camphene and not bornylene, as one might expect. Using models to assist you, write a step-by-step mechanism showing how camphene is formed. HO H,O+ not heat Bornylene Camphene Isoborneol 7.11B Rearrangement After Dehydration of a Primary Alcohol Rearrangements also accompany the dehydration...
2. List the trend of relative reactivity of compounds in: SN2 & SN1. Indicate which favors 1°, 2° or 3° carbon. 3. What makes a good leaving group, or poor leaving group in a substitution reaction? List examples. 4. What makes a good nucleophile or poor nucleophile group in a substitution reaction? List examples. Be able to identify the nucleophile in a reaction. 5. What makes a good solvent for an SN2 reaction? List examples. Assign R & S to...
Name_ 08 (4 pts total) Explain why the formation of the carbocation that leads to the way product of this reaction is both thermodynamically and kinetically favorable con the formation of the other possible carbocation. (Hint: there are some key terms that I am looking for and none of them are "Marko Rule" -I am asking you to explain why/how Markovnikov's Rule works) нас H.SO H30 C H, H,0 Q8a (2 pts) It is thermodynamically favorable because... Q8b (2 pts)...
How do you think the stability of cyclohexane will be compared to that of cyclopropane? What should be the most stable conformation of cyclohexane and why? Which conformer of cis-13-dichloroccohexane will be the most stable and why?
BED S a. What is the relationship between compounds A and B? D b. What is the relationship between compounds C and D? D c. What is the relationship between compounds A and D? D E E E 4. In steam distillation of limonene, the boiling point of the distilling liquid is lower than limonene or water, can you explain? 2 pts 5. Bioynthesis of terpenes may proceed by way of the carbocation intermediate shown. a. Follow the arrows to...
I need help with problems with 5 and 6. I'm not sure how to do them. Thanks! 5. the stability of carbocations is generally explained by a concept known as hyperconjugation. Use this concept to explain why a primary (1°) carbocation is more stable than a methyl (CH3+) carbocation. You must use a simple and concise drawing to show your point. 6. Using frontier orbital theory, explain why an E2 reaction must have the beta-hydrogen and the leaving group anti-periplanar...
1 - Discuss correctly why each substituent favors the
observed major product. (e.g. stability of the carbocation
intermediate resonance hybrid, steric hindrance at reaction
location) How does the stability of the intermediates (from the
handout done during the lab) rationalize the observed products
formed? Do more stable intermediate lead to more products or
less
2- Create a general rule that correctly correlates
EDG/EWG behavior of a substituent and the preferred regiochemistry
of the reaction. Where do EDGs tend to substitute?...