Question

The virtual lab stockroom contains NaOH, water and an unknown solid weak acid. Perform experiments to identify the pka and mo
Distilled H20 Distilled Water 3.0L 100 mL H20 Distilled Water 0.1 L 1.00 M NaOH 1M Sodium Hydroxide 0.1 L Phenolphthalein Phe
Please enter your answer in the form below. The unknown solid acid has a molar mass of: and a pka of: grams/mole Your molar m

Data i got:
1g of solid acid=0.51706 ml
50 ml of water used to dissolve
0.5 ml of indicator added to acid solution

8.52 ml of 1M NaOH titrated from burrete into acid solution.


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Answer #1

Assuming, the given unknown acid is a monobasic HA.
The neutralization reaction would be:
NaOH(aq) \, +\, HA(aq)\, \rightarrow \, NaA\, +\, H_{2}O
Number of moles of NaOH added = Molarity x Vol. in L = 1 x 0.00852 L = 0.00852
Looking at the balanced equation, number of moles of HA added = 0.00852
Let molar mass of HA = M
Using, given mass/Molar mass = number of moles
1/M = 0.00852
M = 1/0.00852 = 117.37 g/mol
The salt formed (NaA) will be a basic salt and the pH of this salt can be calculated by the formula:
pH\, =\, 7\, +\, \frac{1}{2}\times [pk_{a}\, +\, logc]
c(concentration of the salt) or [NaA] = (number of moles/vol. of solution) x 1000
Number of moles of the salt formed = 0.00852
PS: It is not clear why vol of the solid acid taken is provided.
vol. of solution =  50 mL of water + 8.52 mL of NaOH + 0.5 mL of indicator = 59.02 mL
(Although the indicator volume is negligible, but since it is provided we can add it)
[NaA] = (0.00852/59.02) x1000 = 0.144
If pH at the end point is known, pKa can be callculated.


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