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The chemical shift of Ha in the molecule below was recorded at 3.85 ppm downfield from...

The chemical shift of Ha in the molecule below was recorded at 3.85 ppm downfield from TMS on a 500 MHz spectrometer. What is this chemical shift, in Hz, on a 250 MHz NMR? Other hydrogen’s are omitted for clarity. ppm = (chemical shift in Hz)/(spectrometer frequency in MHz)

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Answer #1

relative chemical shift (ppm) = (absolute chemical shift in Hz)/(spectrometer frequency in MHz)

chemical shift, in Hz when recorded at 250  MHz

absolute chemical shift in Hz = 3.85 * 250 = 962.5 Hz

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