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5. Which mechanism would be appropriate for a reaction that had the rate law: Rate =k[A]??...
Consider the overall reaction.... A+B--C+D which has an observed rate law of Rate=k[A12 Which of the following choices would be a sensible 2-step mechanism, given this observed rate law? O A+A-->E slow E+B-->C+D fast A+B--> 2 E --> C+D fast slow A+A-->E E+B-->C+D fast slow A+B-->E 2 E -->C+D slow fast
4. For the reaction A+B → C+D we find that the rate law is v=k[A]”[B]° Which of the following mechanisms is consistent with the rate law? Explain in detail. a) A+B → C+D b) A+A ~ A2 (fast step) A2 +B → C+D (slow step) c) A+A → A2 (slow step) A2+B → C+D (fast step) d) A+A → A2 (fast equilibrium) A2+B → C+D (slow step)
The rate law for the reaction 2NO2 + O3 → N2O5 + O2 is rate = k[NO2][O3]. Which one of the following mechanisms is consistent with this rate law? A) NO2 + NO2 → N2O4 (fast) N2O4 + O3 → N2O5 + O2 (slow) B) NO2 + O3 → NO5 (fast) NO5 + NO5 → N2O5 + 5/2O2 (slow) C) NO2 + O3 → NO3 + O2 (slow) NO3 + NO2 → N2O5 (fast) D) NO2 + NO2 → N2O2...
A reaction mechanism is defined as the sequence of reaction steps that define the pathway from reactants to products. Each step in a mechanism is an elementary reaction, which describes a single molecular event of usually one or two molecules interacting. The rate law for an overall reaction is the rate law for the slowest step in the mechanism, which is directly related to the stoichiometric coefficients of the reactants. The exception to this rule occurs when the slowest step...
Part A Given the following proposed mechanism, predict the rate law for the overall reaction. 2 NO2 + Cl2 → 2 NO2Cl (overall reaction) Mechanism NO2 + Cl2 → NO2Cl + Cl slow NO2 + Cl → NO2Cl fast Given the following proposed mechanism, predict the rate law for the overall reaction. 2 NO2 + Cl2 → 2 NO2Cl (overall reaction) Mechanism NO2 + Cl2 → NO2Cl + Cl slow NO2 + Cl → NO2Cl fast Answer Choices: Rate =...
At 300 K, the following reaction is found to obey the rate law of Rate = k[NOCl]^2: 2 NOCl(g) 2 NO(g) + Cl2(g) The following reaction mechanism has been proposed for the reaction above: Proposed Mechanism: NOCl(g) ->NO(g) + Cl(g) slow Cl(g) + NOCl(g) -> NOCl(g) fast NOCl2(g) -> NO(g) + Cl2(g) fast 21. The suggested rate law in the mechanism is Rate = k[NOCl]. (T) 22. The reaction mechanism is plausible. (F) 23. NOCl2 is a catalyst in...
Consider the overall reaction and proposed mechanism. What step is rate determining (slow) if the rate law of overall reaction is Rate = k[A][BC] step 1: A + BC --> AB + C step 2: AB + D --> AD + B step 3: B + C --> BC overall reaction: A + D --> AD
The rate law for the reaction 2NO2 + O3 ? N2O5 + O2 is rate = k[NO2][O3]. Which one of the following mechanisms is consistent with this rate law? A) NO2 + NO2 ? N2O4 (fast) N2O4 + O3 ? N2O5 + O2 (slow) B) NO2 + O3 ? NO5 (fast) NO5 + NO5 ? N2O5 + 5/2O2 (slow) C) NO2 + O3 ? NO3 + O2 (slow) NO3 + NO2 ? N2O5 (fast) D) NO2 + NO2 ? N2O2...
8) A reaction occurs via the following sequence of elementary steps. What is the rate law based on this reaction mechanism? very fast slow fast 1st step: A B 2nd step: B+C D 3rd step: D - 2E A) rate = k[E]2 B) rate = k[A] [C] C) rate = k[B][C] D) rate = k[D] E) rate = k[A] [B]
The proposed mechanism for a reaction is Cl2 => Cl+ + Cl- Slow Cl- + H2S => HCl + HS- Fast Cl+ + HS- => HCl + S Fast Which of the following would be a rate law for the reaction? A. rate = k[Cl2] B. rate = k[Cl2][H2S] C. rate = k[Cl2]1/2[H2S] D. rate = k[Cl-][H2S] E. rate = [Cl+][Cl-]