1. The same reaction takes place in two different vessels, which are initially at atmospheric pressure (1 atm). The first vessel is rigid and does not expand with change in pressure; the second vessel will expand to maintain a pressure of 1 atm inside. Over the course of a reaction, the second vessel expands by 1 liter.
a) What is the amount of PV work done by the reaction for each of the vessels?
b) Which vessel’s content has a higher enthalpy?
c) Based on the answer to part b, which vessel would you expect to have a higher temperature?
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2. The same reaction takes place in two different vessels, which are initially at atmospheric pressure (1 atm). The first vessel is rigid and does not expand with change in pressure; the second vessel will expand to maintain a pressure of 1 atm inside. Ov