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iPad 7:01 AM moodle bergen.edu 2 of 2 lcocul (aq, blue) 6H20 Co(Hroy (aq. Pink) Predict color Add water Add NaCl Three (30 Points Titration of unknown acid. concentration of NaOH, Determine the Molarity of the NaoH. Use correct significant figures. pH vs mL NaOH pH vs mL NaOH 5 10 15 20 25 30 35 40 45 50 55 60 65 70 75 80 b. (10 Points) From the above chart predict the pKa of the unknown acid. 91%
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Answer #1

1) [CoCl4]-2  + 6H2O <------------> [ Co(H2O)6]+2   + 4Cl-

blue pink

When water is added , the equilibrium shifts right side , so the pink color is observed.

When NaCl is added , the equilibrium shifts left side , so the blue color is observed.

2)AT equivalence

mmoles of acid = mmoles of base

0.254g/ 204.22 = 95.01 x M x10-3

Thus molarity of NaOH = 0.01309 M

3) From the graph, the pKa is the area where the pH curve is flat and is half the equivalence volume.

Such point is pH = PKa = 5.0 at V= 30 mL and equivalenc evolume = 60mL

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