1) Which of the following oxidation-reduction reactions will be spontaneous in the direction written? Select all that apply.
Mg2+ (aq) + Be (s) → Mg (s) + Be2+ (aq)
Cu2+ (aq) + Zn (s) → Cu (s) + Zn2+ (aq)
Hg2+ (aq) + Cu (s) → Hg (l) + Cu2+ (aq)
Pb2+ (aq) + Cu (s) → Pb (s) + Cu2+ (aq)
Fe2+ (aq) + Pb (s) → Fe (s) + Pb2+ (aq)
2) What is the value (in V) of Eocell for the following reaction?
Sn2+ (aq) + Hg (l) → Sn (s) + Hg2+ (aq)
3) What values of K (the equilibrium constant) and ΔG are expected for a large positive Eocell ?
K less than 1; ΔG negative
K less than 1; ΔG positive
K greater than 1; ΔG negative
These values are not consistently related.
K greater than 1; ΔG positive
4) What is Eocell (in V) for a redox reaction where one electron is transferred with an equilibrium constant (K) of 9.88 x 1012?
5) What is ΔGo (in kJ/mol) for a redox reaction where two electrons are transferred with Eocell = -0.338 V?
1) Which of the following oxidation-reduction reactions will be spontaneous in the direction written? Select all...
1. What is the value (in V) of Eocell for the following reaction? Co2+ (aq) + Be (s) → Co (s) + Be2+ (aq) 2.What is Eocell (in V) for a redox reaction where one electron is transferred with an equilibrium constant (K) of 1.44 x 10-14? 3.Consider the following reaction: Cu2+ (aq) + Pb (s) → Cu (s) + Pb2+ (aq) What will be Ecell for this reaction (in V) when [Cu2+] = 0.500 M and [Pb2+] = 0.0350...
1a) Use the standard reduction potentials to calculate the standard free energy change in kJ for the reaction: Hg2+(aq) + Pb(s)---------->Hg(l) + Pb2+(aq) Answer: _______ kJ K for this reaction would be _________(greater/less) than one. 1b) calculate the standard free energy change in kJ for the reaction: Zn2+(aq) + Hg(l)--------->Zn(s) + Hg2+(aq) Answer: ______ kJ K for this reaction would be _________(greater/less) than one. K for this reaction would be _________(greater/less) than one.
30) Use the tabulated half-cell potentials below to calculate the equilibrium constant (K) for the following balanced redox reaction at 25°C. Pb2+(aq) + Cu(s) → Pb(s) + Cu2+(aq) Pb2+(aq) + 2e → Pb(s) Cu2+ (aq) +2e → Cu(s) E° = -0.13 V E = 0.34 V C) 7.9 x 1015 A) 7.9 x 10-8 D) 1.3 x 10-16 B) 8.9 x 107 E) 1.1 x 10-8
1- Consider the following redox reaction: Fe(s) + Cu2+(aq) --> Fe2+(aq) + Cu(s) EoCell = 0.78 V If [Cu2+] = 0.3 M, what [Fe2+] is needed so that Ecell = 0.76 V 2- Calculate the Eocell for the following redox reaction: Cu(s) + 2Ag+(aq) --> Cu2+(aq) + 2Ag(s)
- Zn2+ Choose... Choose... (1pts) Identify the complete redox reaction for a ZnZn2+1|Cu2+1Cu cell. A. Zn(s) + Cu?+ (aq) (aq) + Cu(s) B. Zn(s) + Cu(s) → Zn2+ (aq) + Cu2+ (aq) C. Zn2+ (aq) + Cu(s) Zn(s) + Cu2+ (aq) D. Zn (s) + 2 Cu(s) — Zn2+ (aq) + 2 Cu2+ (aq) (1pts) Identify the complete redox reaction for a Zn/Zn2+||Pb2+1Pb cell. A. Zn (s) + Pb(s) Zn2+ (aq) + Pb2+ (aq) B. Zn2+ (aq) + Pb(s) Zn(s)...
1. Which of the following conditions defines a non-spontaneous oxidation-reduction reaction? E° + ΔG° - Keq <1 E° - ΔG° - Keq <1 E° + ΔG°+ Keq >1 E° + ΔG°- Keq >1 E° - ΔG° + Keq <1 2. What information can be obtained from the Figure below? The equivalence point occurs at pH = 7.0 but the pKa is not known from the graph. Both the pOH and the...
Question 1) What is the value of the equilibrium constant at 25 oC for the reaction between the pair: Pb(s) and Sn2+(aq) to give Sn(s) and Pb2+(aq) Use the reduction potential values for Sn2+(aq) of -0.14 V and for Pb2+(aq) of -0.13 V Question 2) What is the value of ΔGo in kJ at 25 oC for the reaction between the pair: Cr(s) and Cu2+(aq) to give Cu(s) and Cr3+(aq) Use the reduction potentials for Cr3+(aq) is -0.74 V and...
Using the standard reduction potentials given below, choose the reaction than can only be achieved through electrolysis. Cu2+(aq) + 2e → Cu(s) E° = 0.34 V Pb2+(aq) + 2e + Pb(s) E° = -0.13 V Fe2+(aq) + 2e Fe(s) E° = -0.44 V Zn2+(aq) + 2e + Zn(s) E° = -0.77 V Zn2+(aq) + Pb(s) → Zn(s) + Pb2+(aq) o Fe2+(aq) + Zn(s) → Fe(s) + Zn2+(aq) Pb2+(aq) + Fe(s) → Pb(s) + Fe2+(aq) Cu2+(aq) + Fe(s) → Cu(s) +...
Identify the oxidizing agent in the following redox reaction. Hg2+(aq) + Cu(s) --- ---->> Cu2+(aq) + Hg(1)
question 1 - Use standard reduction potentials to calculate the equilibrium constant for the reaction: Fe3+(aq) + Cu+(aq) Fe2+(aq) + Cu2+(aq) Carry at least 5 significant figures during intermediate calculations to avoid roundoff error when taking the antilogarithm. Equilibrium constant: ..... ? G° for this reaction would be greater or less than zero.? question 2 Use standard reduction potentials to calculate the equilibrium constant for the reaction: 2Cu2+(aq) + Hg(l)2Cu+(aq) + Hg2+(aq) Carry at least 5 significant figures during intermediate...