A solution contains 0.100 mM of Ni2+ and Zn2+. Hydroxyl ions are slowly added to this solution to precipitate either Ni(OH)2 or Zn(OH)2. Determine which ion precipitates first at the pH range from 0-14 and the range of OH- concentrations that will allow a clean separation of the two ions. Ksp for Ni(OH)2=6x10^-16 and for Zn(OH)2 Ksp=3x10^-16
A solution contains 0.100 mM of Ni2+ and Zn2+. Hydroxyl ions are slowly added to this...
A solution contains .04 M Ca+, .04 M Zn2+, and .04 M Ni2+ ions. A) If you separate them using (NH4)2C2O2, which ion will precipitate first as an oxalate? Consider Ksp Values for CaC2O4, ZnC2O4, and NiC2O4. CaC2O4 Ksp = 1.3 x 10^-9 ZnC2O4 Ksp = 1.5 x 10^-9 NiC2O4 Ksp = 4.0 x 10^-10 B) Calculate the concentration of the oxalate ion when the first cation (Ca2+, Zn2+, or Ni2+ begins to precipitate. C) Explain why ZnC2O4 and NiC2O4...
Consider the voltaic cell and reduction half potentials: Zn(s) | Zn 2+(aq) (0.100 M) || Ni2+(aq) (1.50 M) | Ni(s) Zn 2+ (aq)/Zn (s) E o = - 0.760 V Ni2+ (aq)/Ni (s) E o = - 0.230 V a) Sketch the voltaic cell represented with the above line notation. Label the anode and cathode and indicate the half-reactions occurring at each electrode and the species present in each solution. Also indicate the direction of electron flow (3 marks). b)...
Fe3+ ions are to be separated from Hg2+ ions from an aqueous solution in which their concentrations are both 0.05500 M . The criterion for "complete" separation is that the Fe3+ ion concentration must be 10,000 times larger or 10,000 times smaller that the Hg2+ ion concentration. Answer the questions below. At what pH will Fe(OH)3 precipitate from a 0.05500 M Fe3+ solution? Ksp = 2.800×10-39 At what pH will Hg(OH)2 precipitate from a Hg M Hg2+ solution? Ksp = 3.100×10-26...
A solution contains 0.10 M concentrations of Ba2+, Ca2+, and Sr2+. Na2CO3 is slowly added to the solution. In what order will the ions begin to precipitate? What is the concentration of the first ion when the 2nd begins to precipitate? Ksp for BaCO3 = 2.58 x 10-9, for CaCO3 = 3.36 x 10-9, and for SrCO3 = 5.60 x 10-10.
The solubility of solid nickel hydroxide, Ni(OH)2, is governed by its Ksp= 6x10^-16. a) Write the equation for this dissolution reaction, and the equilibrium expression. b) Nickel ions undergo three complexations with hydroxide in basic solutions. Assume OH concentration to be 0.0010 M and pH to be 11, calculate the concentrations of Ni2+, NiOH+, Ni(OH)2, and Ni(OH)3-. logK1= 4.1 logK2= 3.9 logK3= 3
Question 12 7 pts Given the following Ksp values, if a solution contains 0.100 M each of Cu2+, Cd2+ and Sc3+, which ion would be present in a precipitate last if NaOH is slowly added to the solution? Ksp Cu(OH)2 = 2.2 x 10-20 Ksp Ca(OH)2 = 7.2 x 10-15 Ksp Sc(OH)3 = 8.0 x 10-25 Cd2+ All three precipitate out at the same time None of them would precipitate O Scat O Cu²
Question 10 1 pts A solution contains Pb2+, Cu2+ and Zn2+ ions. An aqueous solution of Na2CO3 is added slowly, one drop at a time. Which statement(s) is/are true? Select all. Kso PbCO3 7.4 x 10-14 CUCo3 3 x 10-12 ZnCO3 1.0 x 10-10 O All of the metal carbonates will precipitate at the same time. The precipitates will form in this order: ZnCO, then Cuco, then PbCO The precipitates will form in this order:PbCo, then Cuco, then Znco, The...
Question 10 1 pts A solution contains Pb?, Cu2+ and Zn2+ ions. An aqueous solution of Na,Co, is added slowly, one drop at a time. Which statement(s) is/are true? Select all. Kop POCO3 7.4 x 10-14 CuCoz 3x 10-12 ZnCO3 1.0 x 10-10 All of the metal carbonates will precipitate at the same time. The precipitates will form in this order: ZnCO3, then Cucos, then Pbco, The precipitates will form in this order: Pbco, then Cucos, then Znco, The precipitates...
Given the Ksp of Zn(OH)2 is 3.0x10-1, determine the Zn2 ion concentration when the pH of the solution is buffered to pH=12.00 (so that the hydroxide ion concentration is 0.010 M). 1. Zn(OH)2(s) A. [Zn2] 3.0x10-12 M B. [Zn2 3.7x10- M C. [Zn23.0x10-10 M D. [Zn2] 9.1x10-3 M E. [Zn2] 1.5x10-13 M Zn2 (aq) + 20H (aq) Ksp 3.0x10-16 2. When silver carbonate, Ag,COs, is mixed with water, it dissolves to some extent to form a saturated solution where the...
An acidic solution is 2 mM in each of the following metal ions: Zn2+, Cu2+, Co2+, Ca2+. a) Which of the metals would precipitate as their hydroxides at pH = 6.00? (Select all that apply. See theappendix.) -zinc -copper -cobalt -calcium b) Which of the metals would precipitate as their hydroxides at pH = 8.00? -zinc -copper -cobalt -calcium c) At what pH do the metal hydroxides begin to participate? Zn(OH)2 ____ Cu(OH)2 ____ Co(OH)2 ____ Ca(OH)2 ____ Substance Ksp...