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The solubility of acetanilide is 12.8 g in 100 mL of ethanol at 0 ∘C, and...

The solubility of acetanilide is 12.8 g in 100 mL of ethanol at 0 ∘C, and 46.4 g in 100 mL of ethanol at 60 ∘C. What is the maximum percent recovery that can be achieved for the recrystallization of acetanilide from ethanol?

A student was given a sample of crude acetanilide to recrystallize. The initial mass of the the crude acetanilide was 171 mg.The mass after recrystallization was 125 mg.

Calculate the percent recovery from recrystallization.

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Answer #1

The solubility of acetanilide in ethanol increase as temperature is increased. When the solution cools down , it becomes supersaturated and acetanilide starts to crystalize.

At 0 degree C , only 12.8 g can stay dissolved in the solution. The rest of the acetanilide precipitated out from the solution and can be separated by filtration.

Assuming there is no loss during filtration, the maximum percent recovery that can be achieved

2nd part

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