[Ag+]=[Cl-]= 1.00 x 10-4M
Consider the reaction for the dissolution of AgCl in water below at 25⁰C: AgCl(s) DAg+(aq) + Cl-(aq)...
Consider the Gibbs energies at 25 ∘C. SubstanceSubstance ΔG∘f (kJ⋅mol−1)ΔGf∘ (kJ·mol−1) Ag+(aq)Ag+(aq) 77.177.1 Cl−(aq)Cl−(aq) −131.2−131.2 AgCl(s)AgCl(s) −109.8−109.8 Br−(aq)Br−(aq) −104.0−104.0 AgBr(s)AgBr(s) −96.9−96.9 (a) Calculate ΔG∘rxn for the dissolution of AgCl(s)AgCl(s). kJ⋅mol−1 (b) Calculate the solubility-product constant of AgCl. K= (c) Calculate ΔG∘rxnΔGrxn∘ for the dissolution of AgBr(s)AgBr(s). kJ⋅mol−1kJ⋅mol−1 (d) Calculate the solubility-product constant of AgBr. K=K=
To decide whether AgCl should dissolve in water ( spontaneous reaction ) at 25 degrees celcius, the delta H and T delta S must be used in the Gibbs Free Energy equation to calculate delta G AgCl (s) + H2O (I) -> Ag+ + Cl- + H2O Standard Enthalpies of formation and standard entropies of common compounds substance state AgCl s -127010 96.20 Cl- aq -167080. 56.50 Ag+ aq. 105790. 72.70
AgCl (s) + --> <-- Ag + (aq) + Cl- (aq) Shown above is information about the dissolution of AgCl in water at 298 K. In a chemistry lab a student wants to determine the value of s, the molar solubility of AgCl, by measuring [Ag+] in a saturated solution prepared by mixing excess AgCl and distilled water. How would the results of the experiment be altered if the student mixed excess AgCl with tap water (in which [Cl-] =...
For the dissolution of thenardite shown below, calculate the following (at STP, 25 °C and 1 atm):Na2SO4 (s) ↔ 2Na+(aq) + SO42-(aq) (a) standard??° enthalpy of reaction (∆????°), ??° (b) standard Gibbs free energy of reaction (∆?? ) using standard Gibbs free energy of formation values (∆?? ), and (c) equilibrium constant (K). (d) Is this a spontaneous reaction [i.e., the dissolution reaction (left to right)]? Explain.
When solutions containing silver ions and chloride ions are mixed, silver chloride precipitates: Ag+(aq)+Cl−(aq)→AgCl(s)ΔH=−65.5kJ A.) Calculate ΔH for formation of 0.100 mol of AgCl by this reaction. I got A ΔH=-6.55 kJ B.) Calculate ΔH for the formation of 2.80 g of AgCl. C.) Calculate ΔH when 0.110 mmol of AgCl dissolves in water. Need help with B and C.
When solutions containing silver ions and chloride ions are mixed, silver chloride precipitates: Ag+(aq)+Cl−(aq)→AgCl(s)ΔH=−65.5kJ Calculate ΔH for formation of 0.490 mol of AgCl by this reaction. Calculate ΔH for the formation of 7.50 g of AgCl. Calculate ΔH when 9.23×10−4 mol of AgCl dissolves in water.
Question 8 (1 point) The standard potential of the cell Sn(s) Sn2(aq) || Cl(aq)| AgCl(s) | Ag(s) is +0,36 V at 25°C. If the standard reduction potential of the AgCl|Ag Cl-couple is 0.22 V, calculate the standard reduction potential of the Sn? Isn couple. 0 -0.14 V +0.36 V -0.07 V +0.14 V +0.58 V
Consider the following Gibbs energies at 25 "C Substance Ag (aq) Cr(aq) AgCI(s) Br(aq) AgBr(s) 77.1 - 131.2 - 109.8 - 104.0 -96.9 (a) Calculate AG rn for the dissolution of AgCl(s). (b) Calculate the solubility-product constant of AgCl Number Number kJ mol (c) Calculate Δ3rxn for the dissolution of AgBr(s). (d) Calculate the solubility-product constant of AgBr Number Number kJ mol
< Question 13 of 18 > Consider the Gibbs energies at 25 °C. Substance AG (kJ. mol-!) Ag+ (aq) 77.1 Cl(aq) -131.2 AgCl(s) -109.8 Br" (aq) -104.0 AgBr(s) -96.9 (a) Calculate AGran for the dissolution of AgCl(s). kJ. mol- (b) Calculate the solubility-product constant of AgCl. kJ. mol- (b) Calculate the solubility product constant of AgCl. K = Enter numeric value (c) Calculate AGtx for the dissolution of AgBr(s). kl. mol-? (d) Calculate the solubility-product constant of AgBr. K=
2. (20%) The standard potential of the AgCl/Ag, Cr couple fits the expression FO 0.23659-4.8564x10 0-3.4205x106 +5.869x10 8 Unit: E (V; 0 °c) Where: [4G"(H) = 0]; [4,Ge(Ag) = 0]; [4H.(H): 0]; [4m(Ag) = 0] (a) Evaluate the standard reaction Gibbs energy (G enthalpy (4,He) and entropy (4,Se ) at 298K (b) Calculate the standard Gibbs energy (ApG"(cr)and enthalpy(A4"(cr)of formation of Cl (aq) 2. (20%) The standard potential of the AgCl/Ag, Cr couple fits the expression FO 0.23659-4.8564x10 0-3.4205x106 +5.869x10...