Q 4(a) [12.5 Marks]
A sample consisting of 2 moles He is expanded isothermally at 0
Celsius from 5.0 dm3
to 20.0 dm3. Calculate w, q and U for each of the following
situations:
(i) A reversible expansion of the sample;
(ii) An irreversible expansion of the sample against a constant
external
pressure equal to the final pressure of the gas;
(iii) A free expansion (against zero external pressure, i.e., in a
vacuum) of
the sample.
Q 4(a) [12.5 Marks] A sample consisting of 2 moles He is expanded isothermally at 0...
Q 4(a) [12.5 Marks] A sample consisting of 2 moles He is expanded isothermally at 0oC from 5.0 dm3 to 20.0 dm3. Calculate w, q and U for each of the following situations: (i) A reversible expansion of the sample; (ii) An irreversible expansion of the sample against a constant external pressure equal to the final pressure of the gas; (iii) A free expansion (against zero external pressure, i.e., in a vacuum) of the sample.
study o OT-O expanded isothermally at 25°C from 24 2 dm3 to 48 4 dm according to the three processes described below For (b) A sample consisting of 1 00 mol of the molecules in air is 2each of the three processes calculate w q. AU, and AH Reversibly, () (5) (n) Against a constant external pressure (irreversibly) equal to the final pressure of the gas, and (m) Freely (against zero external pressure) (6) (1) study o OT-O expanded isothermally...
5 moles of an ideal gas expand isothermally at T-27°C from an initial volume of 20 dm3 to a final volume of 60 dm3. Calculate the work for this process for a) expansion against constant external pressure of 105 Pa and b) reversible expansion. 2.
A sample of 1.00 mol of N2 gas is expanded adiabatically from a volume of 10.00 dm3 and a temperature of 400 K to a volume of 20.00 - 3 -dm3. Assume that nitrogen is ideal, with Cv,m = 5R/2. (i) Find the final temperature if the expansion is carried out reversibly. (ii) Calculate the final temperature if the expansion is carried out with a constant external pressure of 1.00 atm. (iii) Find the final temperature if the gas expands...
7) A 1.20 mole sample of an ideal gas at 28.0°C expands isothermally from an initial volume of 24 dm to a final volume of 75 dm3. Calculate w for the following processes: (a) an expansion against an external pressure of 0.5x 105 Pa (b) a reversible expansion. Please give these quantities in joules. This may involve unit conversion(s).
3.1 moles of ideal gas undergo an expansion from V1 = 1.2 m3 to V2 = 1.7 m3 during an isothermal process taking place at T = 25 degree C. Calculate Delta U, Delta H, Q, W when The expansion takes place in The following conditions: A reversible expansion. A rapid non-reversible expansion against a constant surrounding pressure equal to The final pressure of The gas. A free expansion where The gas expands in vacuum against zero external pressure.
2. One mole of an ideal gas at an initial state of 300 K, 2.4618 atm and 10.0 L is isothermally expanded to 20.0 L against a constant external pressure of 1.2309 atm. Calculate AU, W, q, and AS for the process. Show that the Clausius inequality is satisfied.
2. One mole of an ideal gas at an initial state of 300 K, 2.4618 atm and 10.0 L is isothermally expanded to 20.0 L against a constant external pressure of 1.2309 atm. Calculate AU, W, q, and AS for the process. Show that the Clausius inequality is satisfied.