2- For the reaction 2NO(g) + O2(g)2NO2(g) H° = -114.2 kJ and S° = -146.5 J/K The equilibrium constant for this reaction at 289.0 K is ---------- . Assume that H° and S° are independent of temperature.
ΔHo = -114.2 KJ/mol
ΔSo = -146.5 J/mol.K
= -0.1465 KJ/mol.K
T = 289 K
use:
ΔGo = ΔHo - T*ΔSo
ΔGo = -114.2 - 289.0 * -0.1465
ΔGo = -71.8615 KJ/mol
T = 289 K
ΔGo = -71.8615 KJ/mol
ΔGo = -71861.5 J/mol
use:
ΔGo = -R*T*ln Kc
-71861.5 = - 8.314*289.0* ln(Kc)
ln Kc = 29.9081
Kc = 9.748*10^12
Answer: 9.75*10^12
2- For the reaction 2NO(g) + O2(g)2NO2(g) H° = -114.2 kJ and S° = -146.5 J/K...
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