Show how the reaction of MeCOOMe with CO under conditions of the Monsanto ethanoic acid process can lead to ethanoic anhydride.
Show how the reaction of MeCOOMe with CO under conditions of the Monsanto ethanoic acid process...
For each complex in the Monsanto Acetic Acid Process, indicate the following: 1. Name of step 2. oxidation state of the metal 3. d electron count 4. total electron count 5. turnover number 6. turnover frequency 7. geometry 8. coordination number CO Rh CO H3C-I H20 CO Rh H3C CO h CH3 CO Нас-он HI CO CO CO Rh CO H3C-I H20 CO Rh H3C CO h CH3 CO Нас-он HI CO CO
draw the product of the reaction of ethanoic acid, LAH and hydronium workup
If you were performing a reaction under acidic conditions (where 1.1 equivalents of the acid are used) and you had 6.5 g of your carboxylic acid, how much alcohol would you need to bring the reaction to completion? (Show your calculations, this is for a Fischer esterification reaction producing octyl butyrate).
determine the heat of the combustion reaction between CO and oxygen by combustion under normal conditions and in stoichiometric quantities 1 mol of CO with oxygen. For this, knowing that the system is in normal conditions, it should investigate in the literature the values of the standard enthalpies of formation of the chemical substances involved in that process.
1. Answer with octyl ethanoate as the esterfication reaction (alcohol: 1-octanol, 3.25ml and carboxylic acid: ethanoic acid, 1.25ml) (a) Write a complete chemical equation for the esterfication reaction, use structural formulas and write the name of each compound under the formula. (b) define if the esther is polar or non-polar (c) determine the molar ratio of the two reactants, alcohol and carboxylic acid using the balanced chemical reaction (d) calculate the molar mass of the alcohol and carboxylic acid (e)...
Draw a mechanism for an esterification reaction between phthalic anhydride and ethylene glycol under acidic conditions. (I need help seeing how this reaction would occur with a molecule such as phthalic anhydride, thanks!)
In detail, write out the Monsanto acetic acid catalytic cycle using (RhL;(CO)2] as the precatalyst Label all steps in the cycle and give the oxidation state of the metal in each intermediate. Identify the rate-determining step of the catalytic cycle Alkyl ligands are typically very strong anionic 6-donors with no T-acceptor ability One of the most common reactions of alkyls is the B-hydride elimination reaction Describe the B-hydride elimination reaction in general terms. Illustrate your answer with relevant drawings using...
5. Answer the follwing questions about two isomers, methyl methanoate and ethanoic acid. The molecular formula of the compounds is CH402 (a) Complete the Lewis electron-dot diagram of methyl methanoate in the box below. Show all valence electrons. A student puts 0.020 mol of methyl methanoate into a previously evacuated rigid 1.0L vessel at 450 K. The pressure is measured to be 0.74 atm. When the experiment is repeated using 0.020 mol of ethanoic acid instead of methyl methanoate, the...
pppppplllleeeaaassseee help 1. a. Compound 1 reacts with A under acid conditions to form an imine. What could Z be in this reaction? b. Compound 2 reacts with A (same A as previous reaction) under acid conditions to form an amide. What is Z in this reaction? Draw the structure of A Use curved arrows to show how Compound 2 forms the amide. c. Both reactions involve a leaving group. What is the leaving group in each reaction? O A...
Under the conditions shown below for the following reaction. Fe2O3(s) + 3 CO(g) - 2 Fe(s) + 3 CO2(g) AG° = -28.0 kJ P(CO) - 3.1 atm, P(CO2) - 1.7 atm Calculate Arxn at 298 K, and indicate if the reaction is more or less spontaneous under these conditions than under standard conditions? -4.5 kJ, more spontaneous than under standard conditions None of these -4.5 kJ, less spontaneous than under standard conditions -23.5 kJ, more spontaneous than under standard conditions...