Which type of substrate will undergo substitution and elimination by bimolecular mechanism under all reaction conditions?...
Which type of substrate will undergo substitution and elimination by bimolecular mechanism under all reaction conditions?
a)Methyl
b)Primary
c)Secondary
d)Tertiary
please explain your reasoning.
Homework Answers
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Which type of substrate will undergo substitution and
elimination by bimolecular mechanism under all reaction
conditions?...
2. Predict the product(s) of each of the reaction conditions below. Specify the substrate type (primary,...
2. Predict the product(s) of each of the reaction conditions
below. Specify the substrate type (primary, secondary, or tertiary
alkyl halide), nucleophile (strong or poor), and the solvent type
(protic or aptrotic). Specify the type of reaction mechanism (SN1
or SN2), show the curved arrow mechanism and draw the products as
3D structures to illustrate stereochemistry.
Predict the product(s) of each of the reaction conditions below. Specify the substrate type (1º, 2º, or 3 alkyl halide). mucleophile (strong or poor),...
"Complete the reactions showing all Major Products, both substitution and elimination, that can form based on...
"Complete the reactions showing all Major Products, both
substitution and elimination, that can form based on the reaction
conditions. Be sure to show stereochemistry where
appropriate. Fill in each table with reaction conditions."
w upiete the following reactions showing all products, both substitution and elimination, that can form, then circle the MAJOR Foduct(s). Under each reaction, draw the step by step mechanism showing how each porduct is formed. Show or indicate stereochemistry where appropriate. Fill in each table with reaction...
Part A: Indicate which substrate in each pair is more reactive by an SN2 mechanism and...
Part A: Indicate which substrate in each pair is more reactive by an SN2 mechanism and explain why in terms of leaving group ability or substrate degree (primary, secondary, tertiary): 2-chlorobutane and 2-bromobutane 2-chlorobutane and 1-bromobutane 1-chlorobutane and 1-bromobutane 2-bromobutane and 1-bromobutane 2-chloro-2-methylpropane and 2-chlorobutane Part B: Indicate which substrate in each pair (same ones in part a) is more reactive by an SN1 mechanism and explain why in terms of leaving group ability or substrate degree (primary, secondary, tertiary).
organic chemistry Introduction to Sul and 52 Reactions Alkyl Halides, RX, can undergo substitution reaction. These...
organic chemistry
Introduction to Sul and 52 Reactions Alkyl Halides, RX, can undergo substitution reaction. These reactions are described as a reaction between an electrophile and a nucleophile. The generk equation for these reactions Nu + R-X - - R-Nu + X 2. Merent rate laws and mechanisms describe There are two types of substitution reactions, Seland them. 5.1 Unimolecular substitution reaction ratek [RXI 52 Bimolecular Substitution reaction ratek TRXIN] Mechanisms L Complete the 5.2 reaction by adding the curved...
Below is a reaction from an old second exam of this course. This reaction underwent Sn...
Below is a reaction from an old second exam of this course. This reaction underwent Sn 1. Reflect upon how you would have answered this predict the product question prior to exam II; how would you answer the question differently knowing what you learned from this reading? i.e. where would you find the new substituent, methoxy? **1111ll CHZOH 10 °C "CH3 A. For the reactions of alcohols, which reactions (i.e. substitution via PBr3, etc.) undergo bimolecular mechanisms of substitution and...
1. Which of the compounds below is expected to undergo Sg2 reaction to the highest degree?...
1. Which of the compounds below is expected to undergo Sg2 reaction to the highest degree? ~ a 2! The following substrate was subjected to a series of nucleophilic reactions. Which of the reagents below would be expected to progress climination reaction to the highest degree? elimination a) H.O b) Toso c) CH,COO d) HO el I Which of the following solvents should be correctly called aprotic solvent? M. a) aqua b) DMHA c) DMA d) MAC c) McОН The...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions is: HZC Br CH3 A. 1 B. | F—CH,BH C. CH3-C-CH-CH, CHz CH3 D. CH3 CH3-C-CH2CH2-Br CH3 E. A Br 2. Your task is to convert 2-chloropentane into 1-pentene. Which reagents would you choose? a) NaOH/H20 b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH e) (CH3)3COK/(CH3)3COH 3. Circle the reaction below which is faster in polar protic solvents. OH,H,O A. CH,CH,CH,Br- CH,CH,CH,OH + Br or SH.RSH...
For each of the following reactions, determine which ELIMINATION mechanism (E1 or E2) will occur. Alkyl...
For each of the following reactions, determine which ELIMINATION mechanism (E1 or E2) will occur. Alkyl Halide Substitution: Methyl 1° 2° 3° Base Strength: Strong Weak Mechanism Type: E1 E2 Draw the mechanism that leads to ALL products for the reaction. Finally, underline the major product of the elimination reaction: H3C OH H2C H2C1 Br CHE
Experiment F. Nucleophilic Substitution Reactions. Pre -Lab Report 2. SPECIAL INSTRUCTIONS: a. Work in groups of 2-...
Experiment F. Nucleophilic Substitution Reactions. Pre -Lab Report
2. SPECIAL INSTRUCTIONS: a. Work in groups of 2-3 students. Each group will complete and turn in one report for grade. You will not complete the lab report in your lab notebook using the usual format. Instead, the entire report is provided in the procedures section of these lab materials. You will complete the report by providing the missing information. Report is due at the end of the lab period. b. While...
Workshop Quiz 10-Substitution and elimination 1. Choose the reaction that is least likely to undergo an...
Workshop Quiz 10-Substitution and elimination 1. Choose the reaction that is least likely to undergo an SN2 reaction pathway. CH.он A NaNg CH3CN NaCN Hас— CN HyC C DMF NaSCH3 D OTs acetone Nal OMs acetone Choose the reaction that is least likely to undergo an E2 reaction pathwa 2. NAOCH3 CH-оH
2. Predict the product(s) of each of the reaction conditions
below. Specify the substrate type (primary, secondary, or tertiary
alkyl halide), nucleophile (strong or poor), and the solvent type
(protic or aptrotic). Specify the type of reaction mechanism (SN1
or SN2), show the curved arrow mechanism and draw the products as
3D structures to illustrate stereochemistry.
Predict the product(s) of each of the reaction conditions below. Specify the substrate type (1º, 2º, or 3 alkyl halide). mucleophile (strong or poor),...
"Complete the reactions showing all Major Products, both
substitution and elimination, that can form based on the reaction
conditions. Be sure to show stereochemistry where
appropriate. Fill in each table with reaction conditions."
w upiete the following reactions showing all products, both substitution and elimination, that can form, then circle the MAJOR Foduct(s). Under each reaction, draw the step by step mechanism showing how each porduct is formed. Show or indicate stereochemistry where appropriate. Fill in each table with reaction...
organic chemistry
Introduction to Sul and 52 Reactions Alkyl Halides, RX, can undergo substitution reaction. These reactions are described as a reaction between an electrophile and a nucleophile. The generk equation for these reactions Nu + R-X - - R-Nu + X 2. Merent rate laws and mechanisms describe There are two types of substitution reactions, Seland them. 5.1 Unimolecular substitution reaction ratek [RXI 52 Bimolecular Substitution reaction ratek TRXIN] Mechanisms L Complete the 5.2 reaction by adding the curved...
Below is a reaction from an old second exam of this course. This reaction underwent Sn 1. Reflect upon how you would have answered this predict the product question prior to exam II; how would you answer the question differently knowing what you learned from this reading? i.e. where would you find the new substituent, methoxy? **1111ll CHZOH 10 °C "CH3 A. For the reactions of alcohols, which reactions (i.e. substitution via PBr3, etc.) undergo bimolecular mechanisms of substitution and...
1. Which of the compounds below is expected to undergo Sg2 reaction to the highest degree? ~ a 2! The following substrate was subjected to a series of nucleophilic reactions. Which of the reagents below would be expected to progress climination reaction to the highest degree? elimination a) H.O b) Toso c) CH,COO d) HO el I Which of the following solvents should be correctly called aprotic solvent? M. a) aqua b) DMHA c) DMA d) MAC c) McОН The...
_1. An alkyl halide which might be expected to undergo rearrangement under Snl or E1 conditions is: HZC Br CH3 A. 1 B. | F—CH,BH C. CH3-C-CH-CH, CHz CH3 D. CH3 CH3-C-CH2CH2-Br CH3 E. A Br 2. Your task is to convert 2-chloropentane into 1-pentene. Which reagents would you choose? a) NaOH/H20 b) KOH/CH3OH c) CH3ONa/CH3OH d) CH3CH2ONa/CH3CH2OH e) (CH3)3COK/(CH3)3COH 3. Circle the reaction below which is faster in polar protic solvents. OH,H,O A. CH,CH,CH,Br- CH,CH,CH,OH + Br or SH.RSH...
For each of the following reactions, determine which ELIMINATION mechanism (E1 or E2) will occur. Alkyl Halide Substitution: Methyl 1° 2° 3° Base Strength: Strong Weak Mechanism Type: E1 E2 Draw the mechanism that leads to ALL products for the reaction. Finally, underline the major product of the elimination reaction: H3C OH H2C H2C1 Br CHE
Experiment F. Nucleophilic Substitution Reactions. Pre -Lab Report
2. SPECIAL INSTRUCTIONS: a. Work in groups of 2-3 students. Each group will complete and turn in one report for grade. You will not complete the lab report in your lab notebook using the usual format. Instead, the entire report is provided in the procedures section of these lab materials. You will complete the report by providing the missing information. Report is due at the end of the lab period. b. While...
Workshop Quiz 10-Substitution and elimination 1. Choose the reaction that is least likely to undergo an SN2 reaction pathway. CH.он A NaNg CH3CN NaCN Hас— CN HyC C DMF NaSCH3 D OTs acetone Nal OMs acetone Choose the reaction that is least likely to undergo an E2 reaction pathwa 2. NAOCH3 CH-оH
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