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A student has a basic buffer solution of equimolar ammonia and ammonium nitrate. What would be...

A student has a basic buffer solution of equimolar ammonia and ammonium nitrate. What would be the effect on the concentrations of ammonia, ammonium ion, and hydroxide ion if a small amount of the following solutions were added to the buffer?

HCl

NH4Cl

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Answer #1

When Hcl is added to the solution it provides H+ ions, which reacts with NH3 , ammonia to produce ammonium ion. Hence concentration of ammonia will decrease whereas the concentration of ammonium ion will increase. It will not greatly affect the concentration of OH- ion though.

Whereas upon addition of NH4Cl , we'll get extra amount of ammonium ion , which will shift the dissociation process of ammonia in reverse direction, hence concentration of ammonia will increase, concentration of NH4+ will decrease and concentration of OH- will decrease.

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